scholarly journals Locomotion of the C60-based nanomachines on graphene surfaces

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Seyedeh Mahsa Mofidi ◽  
Hossein Nejat Pishkenari ◽  
Mohammad Reza Ejtehadi ◽  
Alexey V. Akimov

AbstractWe provide a comprehensive computational characterization of surface motion of two types of nanomachines with four C60 “wheels”: a flexible chassis Nanocar and a rigid chassis Nanotruck. We study the nanocars’ lateral and rotational diffusion as well as the wheels’ rolling motion on two kinds of graphene substrates—flexible single-layer graphene which may form surface ripples and an ideally flat graphene monolayer. We find that the graphene surface ripples facilitate the translational diffusion of Nanocar and Nanotruck, but have little effect on their surface rotation or the rolling of their wheels. The latter two types of motion are strongly affected by the structure of the nanomachines instead. Surface diffusion of both nanomachines occurs preferentially via a sliding mechanism whereas the rolling of the “wheels” contributes little. The axial rotation of all “wheels” is uncorrelated.

2021 ◽  
Vol 22 (16) ◽  
pp. 8396
Author(s):  
Miriam Izzo ◽  
Margot Jacquet ◽  
Takayuki Fujiwara ◽  
Ersan Harputlu ◽  
Radosław Mazur ◽  
...  

Here, we report the development of a novel photoactive biomolecular nanoarchitecture based on the genetically engineered extremophilic photosystem I (PSI) biophotocatalyst interfaced with a single layer graphene via pyrene-nitrilotriacetic acid self-assembled monolayer (SAM). For the oriented and stable immobilization of the PSI biophotocatalyst, an His6-tag was genetically engineered at the N-terminus of the stromal PsaD subunit of PSI, allowing for the preferential binding of this photoactive complex with its reducing side towards the graphene monolayer. This approach yielded a novel robust and ordered nanoarchitecture designed to generate an efficient direct electron transfer pathway between graphene, the metal redox center in the organic SAM and the photo-oxidized PSI biocatalyst. The nanosystem yielded an overall current output of 16.5 µA·cm−2 for the nickel- and 17.3 µA·cm−2 for the cobalt-based nanoassemblies, and was stable for at least 1 h of continuous standard illumination. The novel green nanosystem described in this work carries the high potential for future applications due to its robustness, highly ordered and simple architecture characterized by the high biophotocatalyst loading as well as simplicity of manufacturing.


Author(s):  
Nikolaos Mavredakis ◽  
Anibal Pacheco-Sanchez ◽  
Paulius Sakalas ◽  
Wei Wei ◽  
Emiliano Pallecchi ◽  
...  

2013 ◽  
Vol 52 (6R) ◽  
pp. 060203 ◽  
Author(s):  
Rai Kou ◽  
Shinichi Tanabe ◽  
Tai Tsuchizawa ◽  
Kaori Warabi ◽  
Satoru Suzuki ◽  
...  

Sign in / Sign up

Export Citation Format

Share Document