Rate-dependent phase transitions in Li2FeSiO4 cathode nanocrystals

AbstractThe paper extends the authors' recent model for one-dimensional rate-dependent magneto-mechanical behavior of NiMnGa single crystals to account for temperature-dependent effects including austenite/martensite and ferro-/paramagnetic phase transitions. The magneto-mechanical model is based on the Helmholtz free energy landscape constructed for a meso-scale lattice element with strain and magnetization as order parameters. This two-dimensional energy landscape includes three paraboloidal wells representing the two easy-axis and one hard-axis martensite variants relevant for the structurally one-dimensional case. Phase transformations resulting from applied stresses and magnetic fields follow from a system of evolution laws based on the Gibbs free energy equations and the theory of thermally activated processes, which in the low-thermal-activation limit appropriately reproduce the athermal transformation behavior observed in these materials. The phase fractions subsequently determine the macroscopic strain and magnetization of a sample of NiMnGa by means of a standard averaging procedure. To account for the first-order phase transitions to austenite, additional temperature-dependent wells representing the stable states of austenitic NiMnGa are introduced into the Helmholtz energy landscape. The transition from ferromagnetic to paramagnetic states is modeled as a second order transformation based on the gradual degeneration of the ferromagnetic wells with increasing temperature.

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Formation and phase transitions of methane hydrates under dynamic loadings: Compression rate dependent kinetics

The Journal of Chemical Physics ◽

10.1063/1.3695212 ◽

2012 ◽

Vol 136 (11) ◽

pp. 114513 ◽

Cited By ~ 12

Author(s):

Jing-Yin Chen ◽

Choong-Shik Yoo

Keyword(s):

Phase Transitions ◽

Methane Hydrates ◽

Compression Rate ◽

Rate Dependent ◽

Dynamic Loadings

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Evaluation of Freezing Methods by Low Temperature X-Ray Diffraction

Proceedings, annual meeting, Electron Microscopy Society of America ◽

10.1017/s0424820100079176 ◽

1977 ◽

Vol 35 ◽

pp. 330-333

Author(s):

T. Gulik-Krzywicki ◽

M.J. Costello

Keyword(s):

Biological Materials ◽

Molecular Organization ◽

X Ray Diffraction ◽

Glass Capillary ◽

X Ray ◽

Rate Dependent ◽

Before And After ◽

Freeze Etching ◽

Diffraction Patterns ◽

Set Up

Freeze-etching electron microscopy is currently one of the best methods for studying molecular organization of biological materials. Its application, however, is still limited by our imprecise knowledge about the perturbations of the original organization which may occur during quenching and fracturing of the samples and during the replication of fractured surfaces. Although it is well known that the preservation of the molecular organization of biological materials is critically dependent on the rate of freezing of the samples, little information is presently available concerning the nature and the extent of freezing-rate dependent perturbations of the original organizations. In order to obtain this information, we have developed a method based on the comparison of x-ray diffraction patterns of samples before and after freezing, prior to fracturing and replication.Our experimental set-up is shown in Fig. 1. The sample to be quenched is placed on its holder which is then mounted on a small metal holder (O) fixed on a glass capillary (p), whose position is controlled by a micromanipulator.

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Electron Microscopy of Graphite Intercalation Compounds

Proceedings, annual meeting, Electron Microscopy Society of America ◽

10.1017/s0424820100055564 ◽

1982 ◽

Vol 40 ◽

pp. 544-545

Author(s):

G. Timp ◽

L. Salamanca-Riba ◽

L.W. Hobbs ◽

G. Dresselhaus ◽

M.S. Dresselhaus

Keyword(s):

Electron Microscopy ◽

Phase Transitions ◽

Domain Wall ◽

Intercalation Compounds ◽

Lattice Plane ◽

Wall Model ◽

Graphite Intercalation Compounds ◽

Fundamental Symmetry ◽

Graphite Intercalation

Electron microscopy can be used to study structures and phase transitions occurring in graphite intercalations compounds. The fundamental symmetry in graphite intercalation compounds is the staging periodicity whereby each intercalate layer is separated by n graphite layers, n denoting the stage index. The currently accepted model for intercalation proposed by Herold and Daumas assumes that the sample contains equal amounts of intercalant between any two graphite layers and staged regions are confined to domains. Specifically, in a stage 2 compound, the Herold-Daumas domain wall model predicts a pleated lattice plane structure.

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Multiple phase transitions investigated by high-speed TEM

Proceedings, annual meeting, Electron Microscopy Society of America ◽

10.1017/s0424820100175880 ◽

1990 ◽

Vol 48 (4) ◽

pp. 550-551

Author(s):

Oleg Bostanjoglo ◽

Peter Thomsen-Schmidt

Keyword(s):

Phase Transitions ◽

High Speed ◽

Short Exposure ◽

Semiconductor Film ◽

Time Resolved ◽

Short Exposure Time ◽

Multiple Phase ◽

Model Substance ◽

History Of ◽

Electron Image

Thin GexTe1-x (x = 0.15-0.8) were studied as a model substance of a composite semiconductor film, in addition being of interest for optical storage material. Two complementary modes of time-resolved TEM were used to trace the phase transitions, induced by an attached Q-switched (50 ns FWHM) and frequency doubled (532 nm) Nd:YAG laser. The laser radiation was focused onto the specimen within the TEM to a 20 μm spot (FWHM). Discrete intermediate states were visualized by short-exposure time doubleframe imaging /1,2/. The full history of a transformation was gained by tracking the electron image intensity with photomultiplier and storage oscilloscopes (space/time resolution 100 nm/3 ns) /3/. In order to avoid radiation damage by the probing electron beam to detector and specimen, the beam is pulsed in this continuous mode of time-resolved TEM,too.Short events ( <2 μs) are followed by illuminating with an extended single electron pulse (fig. 1c)

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