Chapter 8. Self-Assembly of Starch Spherulites as Induced by Inclusion Complexation with Small Ligands

A pseudo-graft copolymer micelle was constructed from the self-assembly of (6-(2-aminoethyl)-amino-6-deoxy)-cyclodextrin (β-CDen)-modified poly(aspartic acid) (PASP-CD) with cholesterol-modified poly(d,l-lactide) (PLA-Chol) using host–guest inclusion complexation in water.

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ChemInform Abstract: Cyclodextrin-Based Inclusion Complexation Bridging Supramolecular Chemistry and Macromolecular Self-Assembly

ChemInform ◽

10.1002/chin.201139243 ◽

2011 ◽

Vol 42 (39) ◽

pp. no-no

Author(s):

Guosong Chen ◽

Ming Jiang

Keyword(s):

Supramolecular Chemistry ◽

Self Assembly ◽

Inclusion Complexation

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Self-Assembly of Amphiphilic Block Copolymer in Aqueous Solutions Tuned by Host-Guest Inclusion Complexation

Advanced Materials Research ◽

10.4028/www.scientific.net/amr.487.663 ◽

2012 ◽

Vol 487 ◽

pp. 663-667

Author(s):

Yu Long Shuai ◽

Mi Zhou ◽

Xin Qian

Keyword(s):

Block Copolymer ◽

Self Assembly ◽

Ring Opening ◽

Chain Transfer ◽

Gene Transfection ◽

Inclusion Complexation ◽

Ring Opening Polymerization ◽

Isopropyl Acrylamide ◽

Reversible Addition ◽

Copolymer Poly

The block copolymer poly (ε-caprolactone)-b-poly (N-isopropyl acrylamide) (PCL-b-PNIPAM) is synthesized via the combination of ring-opening polymerization (ROP) and reversible addition-fragmentation chain transfer (RAFT). PCL-b-PNIPAM can self-assemble into the micelles taking PCL as the cores and PNIPAM as the shells. Add α-CD into the micelles, because the inclusion complexation of α-CD to PCL chains and phenols is stronger than that to PCL, to regulate the hydrophilic and hydrophobic features of PCL chain. So PCL-b-PNIPAM block copolymers have potential application in drug delivery and gene transfection.

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Pseudo-graft polymer based on adamantyl-terminated poly(oligo(ethylene glycol) methacrylate) and homopolymer with cyclodextrin as pendant: its thermoresponsivity through polymeric self-assembly and host–guest inclusion complexation

RSC Advances ◽

10.1039/c3ra47861k ◽

2014 ◽

Vol 4 (34) ◽

pp. 17768-17779 ◽

Cited By ~ 12

Author(s):

Yinwen Li ◽

Huilong Guo ◽

Yunfei Zhang ◽

Jian Zheng ◽

Jianqun Gan ◽

...

Keyword(s):

Ethylene Glycol ◽

Self Assembly ◽

Inclusion Complexation ◽

Graft Polymer ◽

Glycol Methacrylate

Thermoresponsivity and self-assembly of a pseudo-graft polymer based on Ad-terminated poly(oligo(ethylene glycol) methacrylate) and homopolymer with CD pendants.

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Facile fabrication of narrowly-distributed polymeric micelles via host–guest inclusion complexation of hyperbranched polymers and cyclodextrin and its two-dimensional self-assembly

Physical Chemistry Chemical Physics ◽

10.1039/c002463e ◽

2010 ◽

Vol 12 (38) ◽

pp. 11948 ◽

Cited By ~ 11

Author(s):

Xiaoyi Sun ◽

Wei Huang ◽

Yongfeng Zhou ◽

Deyue Yan

Keyword(s):

Self Assembly ◽

Polymeric Micelles ◽

Inclusion Complexation ◽

Hyperbranched Polymers ◽

Two Dimensional ◽

Facile Fabrication

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β-Cyclodextrin-Based Inclusion Complexation Bridged Biodegradable Self-Assembly Macromolecular Micelle for the Delivery of Paclitaxel

PLoS ONE ◽

10.1371/journal.pone.0150877 ◽

2016 ◽

Vol 11 (3) ◽

pp. e0150877 ◽

Cited By ~ 12

Author(s):

Yanzuo Chen ◽

Yukun Huang ◽

Dongdong Qin ◽

Wenchao Liu ◽

Chao Song ◽

...

Keyword(s):

Self Assembly ◽

Inclusion Complexation

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A Binary Supramolecular Assembly with Intense Fluorescence Emission, High pH Stability, and Cation Selectivity: Supramolecular Assembly-Induced Emission Materials

Research ◽

10.34133/2019/1454562 ◽

2019 ◽

Vol 2019 ◽

pp. 1-10 ◽

Cited By ~ 5

Author(s):

Xu Wang ◽

Xin-Yue Lou ◽

Xiao-Yu Jin ◽

Feng Liang ◽

Ying-Wei Yang

Keyword(s):

Self Assembly ◽

Inclusion Complexation ◽

Fluorescence Emission ◽

Blue Emission ◽

Supramolecular Assembly ◽

Supramolecular System ◽

Cation Selectivity ◽

Ion Sensing ◽

Wide Range ◽

Ammonium Binding

We construct a fluorescent supramolecular system (TPE-Q4⊂ DSP5) of excellent tolerance to a wide range of pH by the facile self-assembly of a new pillar[5]arene bearing disulfonated arms (DSP5) with an AIE-active tetraphenylethene-based tetratopic guest bearing four quaternary ammonium binding sites (TPE-Q4), which exhibits strong blue emission even in dilute aqueous solutions along with much higher quantum yield and longer fluorescence lifetime than TPE-Q4 itself. This appreciable property can be attributed to the supramolecular assembly-induced emission (SAIE) mechanism endowed by the host-guest inclusion complexation based on synthetic macrocycles. Remarkably, the enhanced fluorescence of the supramolecular assembly is quenched efficiently and exclusively by ferric ions in water with a high Stern–Volmer formula constant of 1.3 × 105 mol-1, demonstrating the excellent cation selectivity and visualized responsiveness in ion sensing and detection.

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