The influence of oligo(ethylene glycol) side chains on the self-assembly of benzene-1,3,5-tricarboxamides in the solid state and in solution

2009 ◽  
Vol 19 (1) ◽  
pp. 124-130 ◽  
Author(s):  
Patrick J. M. Stals ◽  
Jan F. Haveman ◽  
Rafael Martín-Rapún ◽  
Carel F. C. Fitié ◽  
Anja R. A. Palmans ◽  
...  
Keyword(s):  
Solid State ◽  
Ethylene Glycol ◽  
Self Assembly ◽  
The Self ◽  
Side Chains

Self-assembly of chiral oligo(methylene-p-phenylene-ethynylene)s into vesicle-like particles independent of hydrophobicity/hydrophilicity of side chains and solvents

Soft Matter ◽  
2021 ◽  
Author(s):  
Zhiqiang Zhao ◽  
Zheng Bian ◽  
Yu Chen ◽  
Chuanqing Kang ◽  
Lianxun Gao ◽  
...  
Keyword(s):  
Self Assembly ◽  
Molecular Design ◽  
The Self ◽  
Side Chains ◽  
Phenylene Ethynylene

Chiral oligo(methylene-p-phenyleneethynylene)s can form vesicular assemblies no matter whether side chains and solvents are hydrophilic or hydrophobic. The self-assembly processes are highly independent of molecular design and chemical environments.

Cryogenic wormlike micelles

Soft Matter ◽  
2019 ◽  
Vol 15 (12) ◽  
pp. 2511-2516 ◽  
Author(s):  
Hongyao Yin ◽  
Yujun Feng ◽  
Peixun Li ◽  
James Doutch ◽  
Yixiu Han ◽  
...  
Keyword(s):  
Ethylene Glycol ◽  
Rheological Behavior ◽  
Self Assembly ◽  
Mixed Solvent ◽  
Freezing Point ◽  
The Self ◽  
Wormlike Micelles ◽  
Micellar Solutions ◽  
Zwitterionic Surfactant

Cryogenic wormlike micellar solutions with a freezing point far below 0 °C and unique rheological behavior are fabricated from the self-assembly of a C22-tailed zwitterionic surfactant in a mixed solvent of ethylene glycol and water. Such fluids could find applications in areas where viscoelasticity is highly desired at subfreezing temperatures.

NANOSTRUCTURES FROM DESIGNER PEPTIDES

COSMOS ◽  
2008 ◽  
Vol 04 (02) ◽  
pp. 173-183
Author(s):  
BOON TEE ONG ◽  
PARAYIL KUMARAN AJIKUMAR ◽  
SURESH VALIYAVEETTIL
Keyword(s):  
Atomic Force Microscopy ◽  
Solid State ◽  
Self Assembly ◽  
Size Range ◽  
The Self ◽  
Mica Surface ◽  
Force Microscopy ◽  
Solution Structures ◽  
Atomic Force

The present article reviews the self-assembly of oligopeptides to form nanostructures, both in solution and in solid state. The solution structures of the peptides were examined using circular dichroism and dynamic light scattering. The solid state assembly was examined by adsorbing the peptides onto a mica surface and analyzing it using atomic force microscopy. The role of pH and salt concentration on the peptide self-assembly was also examined. Nanostructures within a size range of 3–10 nm were obtained under different conditions.

Hydrolysis of Surface-Bound Phosphonate Esters for the Self-Assembly of Multilayer Films:  Use of Solid State Magic Angle Spinning31P NMR as a Probe of Reactions on Surfaces

Langmuir ◽  
1996 ◽  
Vol 12 (2) ◽  
pp. 238-242 ◽  
Author(s):  
Grace Ann Neff ◽  
Catherine J. Page ◽  
Ernesta Meintjes ◽  
T. Tsuda ◽  
W.-C. Pilgrim ◽  
...  
Keyword(s):  
Solid State ◽  
Self Assembly ◽  
Multilayer Films ◽  
The Self ◽  
Magic Angle ◽  
Phosphonate Esters ◽  
Hydrolysis Of

Factors driving the self-assembly of water-soluble calix[4]arene and gemini guests: a combined solution, computational and solid-state study

RSC Advances ◽  
2014 ◽  
Vol 4 (96) ◽  
pp. 53575-53587 ◽  
Author(s):  
Carmela Bonaccorso ◽  
Giovanna Brancatelli ◽  
Giuseppe Forte ◽  
Giuseppe Arena ◽  
Silvano Geremia ◽  
...  
Keyword(s):  
Solid State ◽  
Self Assembly ◽  
Water Soluble ◽  
The Self ◽  
State Study ◽  
Combined Solution

scholarly journals Supramolecular nanoparticles self-assembled from reduction-responsive cabazitaxel prodrugs for effective cancer therapy

2021 ◽  
Author(s):  
Jiahui Jin ◽  
Jianqin Wan ◽  
Xiaoxiao Hu ◽  
Tao Fang ◽  
Zhijian Ye ◽  
...  
Keyword(s):  
Cancer Therapy ◽  
Ethylene Glycol ◽  
Intravenous Administration ◽  
Self Assembly ◽  
Aqueous Media ◽  
The Self ◽  
Supramolecular Nanoparticles ◽  
Self Assembled ◽  
Effective Cancer Therapy

Short amphiphilic oligo(ethylene glycol)–oligolactide fragments were used to chemically modify a hydrophobic and toxic taxane drug, which induced the self-assembly of the resultant prodrug entities in aqueous media for intravenous administration.

scholarly journals {N 1-[2-(Butylselanyl)benzyl]-N 2,N 2-dimethylethane-1,2-diamine}dichloridomercury(II)

2018 ◽  
Vol 74 (8) ◽  
pp. 1151-1154
Author(s):  
Pushpendra Singh ◽  
Harkesh B. Singh ◽  
Ray J. Butcher
Keyword(s):  
Hydrogen Bonding ◽  
Solid State ◽  
Self Assembly ◽  
Title Compound ◽  
Supramolecular Assembly ◽  
Molecular Geometry ◽  
The Self ◽  
Intermolecular Hydrogen Bonding ◽  
Hydrogen Bonding Interactions ◽  
Donor Acceptor

In the title compound, [HgCl2(C16H28N2Se)], the primary geometry around the Se and Hg atoms is distorted trigonal–pyramidal and distorted square-pyramidal, respectively. The distortion of the molecular geometry in the complex is caused by the steric demands of the ligands attached to the Se atom. The Hg atom is coordinated through two chloride anions, an N atom and an Se atom, making up an unusual HgNSeCl2 coordination sphere with an additional long Hg...N interaction. Intermolecular C—H...Cl interactions are the only identified intermolecular hydrogen-bonding interactions that seem to be responsible for the self assembly. These relatively weak C—H...Cl hydrogen bonds possess the required linearity and donor–acceptor distances. They act as molecular associative forces that result in a supramolecular assembly along the b-axis direction in the solid state of the title compound.

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