From polyester grafting onto POSS nanocage by ring-opening polymerization to high performance polyester/POSS nanocomposites

2010 ◽  
Vol 20 (42) ◽  
pp. 9415 ◽  
Author(s):  
Anne-Lise Goffin ◽  
Emmanuel Duquesne ◽  
Jean-Marie Raquez ◽  
Hans E. Miltner ◽  
Xiaoxing Ke ◽  
...  
Keyword(s):  
Ring Opening ◽  
High Performance ◽  
Ring Opening Polymerization ◽  
Grafting Onto

A Recommender System for Inverse Design of Polycarbonates and Polyesters

2020 ◽  
Author(s):  
Nathaniel Park ◽  
Dmitry Yu. Zubarev ◽  
James L. Hedrick ◽  
Vivien Kiyek ◽  
Christiaan Corbet ◽  
...  
Keyword(s):  
Ring Opening ◽  
High Performance ◽  
Recommendation System ◽  
Polymeric Materials ◽  
Monomer Conversion ◽  
Design Strategy ◽  
Ring Opening Polymerization ◽  
Inverse Design ◽  
False Negatives ◽  
Accelerate Development

The convergence of artificial intelligence and machine learning with material science holds significant promise to rapidly accelerate development timelines of new high-performance polymeric materials. Within this context, we report an inverse design strategy for polycarbonate and polyester discovery based on a recommendation system that proposes polymerization experiments that are likely to produce materials with targeted properties. Following recommendations of the system driven by the historical ring-opening polymerization results, we carried out experiments targeting specific ranges of monomer conversion and dispersity of the polymers obtained from cyclic lactones and carbonates. The results of the experiments were in close agreement with the recommendation targets with few false negatives or positives obtained for each class.<br>

Propargylamine: An Attractive Amino Source for Designing High-Performance Benzoxazine Resins with Low Polymerization Temperatures

2021 ◽  
Author(s):  
Yu Liu ◽  
Weichen Sheng ◽  
Ren Yin ◽  
Kan Zhang
Keyword(s):  
Ring Opening ◽  
High Performance ◽  
Ring Opening Polymerization ◽  
Polymerization Temperature

Aniline is a very common amino source for benzoxazine synthesis, but generally resulting in relatively high ring-opening polymerization temperatures. The exploration of alternative amine sources to lower the polymerization temperature...

Ring-opening polymerization approach to ε -caprolactone grafting onto modified LDH biodegradable nanocomposites

2013 ◽  
Vol 172 (1) ◽  
pp. e132-e133 ◽  
Author(s):  
Lian Liu ◽  
Teng Yu ◽  
Guangshuo Wang ◽  
Pei Wang ◽  
Zhiyong Wei ◽  
...  
Keyword(s):  
Ring Opening ◽  
Ring Opening Polymerization ◽  
Biodegradable Nanocomposites ◽  
Grafting Onto

A novel high performance oxazine derivative: design of tetrafunctional monomer, step-wise ring-opening polymerization, improved thermal property and broadened processing window

RSC Advances ◽  
2015 ◽  
Vol 5 (42) ◽  
pp. 33623-33631 ◽  
Author(s):  
Tong Zhang ◽  
Jun Wang ◽  
Tiantian Feng ◽  
Hui Wang ◽  
Noureddine Ramdani ◽  
...  
Keyword(s):  
Thermal Property ◽  
Ring Opening ◽  
High Performance ◽  
Condensation Reaction ◽  
Ring Opening Polymerization ◽  
Processing Window ◽  
Mannich Condensation ◽  
Oxazine Derivative ◽  
First Time ◽  
Tetrafunctional Monomer

A novel tetrafunctional oxazine monomer containing benzoxazine and fluorene-oxazine was prepared for the first time using a Mannich condensation reaction of 2,7-dihydroxy-9,9-bis-(4-hydroxyphenyl)fluorene with paraformaldehyde and n-butylamine.

High performance benzoimidazolyl-based aminophenolate zinc complexes for isoselective polymerization of rac-lactide

2019 ◽  
Vol 55 (68) ◽  
pp. 10112-10115 ◽  
Author(s):  
Yanmei Gong ◽  
Haiyan Ma
Keyword(s):  
Ring Opening ◽  
High Performance ◽  
Ring Opening Polymerization ◽  
Zinc Complexes ◽  
Mild Conditions ◽  
Highly Active

A series of zinc complexes supported by achiral benzoimidazolyl-based aminophenolate ligands were employed as highly active initiators for the ring-opening polymerization of rac-lactide to afford highly isotactic polymers under mild conditions.

scholarly journals Original Macromolecular Architectures Based on poly(ε-caprolactone) and poly(ε-thiocaprolactone) Grafted onto Chitosan Backbone

2018 ◽  
Vol 19 (12) ◽  
pp. 3799 ◽  
Author(s):  
Cüneyt Ünlü ◽  
Eric Pollet ◽  
Luc Avérous
Keyword(s):  
Ring Opening ◽  
Ring Opening Polymerization ◽  
Hexamethylene Diisocyanate ◽  
Proton Nuclear Magnetic Resonance ◽  
High Yield ◽  
X Ray Diffraction ◽  
Scanning Calorimetry ◽  
X Ray ◽  
Molar Ratios ◽  
Grafting Onto

Polyester and/or polythioester grafted chitosan copolymers were synthesized. For that, poly(ε-caprolactone) (PCL), poly(ε-thiocaprolactone) (PTCL), and their copolymers were first synthesized by ring opening polymerization. Copolymers with caprolactone:thiocaprolactone (CL:TCL) molar ratios of 2:1, 1:1, 1:2 were synthesized. All of the synthesized macromolecular architectures were characterized using different spectral (Fourier transform infrared (FTIR), proton nuclear magnetic resonance (1H-NMR), X-Ray diffraction (XRD)) and thermal (Differential scanning calorimetry (DSC), Thermogravimetric analysis (TGA)) methods. Grafting was then performed according two distinct routes: (i) using a blend of both homopolymers (PCL and PTCL) or (ii) using pre-synthesized copolymers with controlled CL:TCL ratios. Hexamethylene diisocyanate was used as a grafting/coupling agent through urethane bonds with high yield. Grafting preferentially occurred at sulfur sites. The results indicated that PTCL is more reactive and favorable than PCL for grafting onto chitosan. With the homopolymers blend grafting route, the corresponding materials mostly had a higher PTCL portion than expected. To obtain polyester grafted chitosan with a determined CL:TCL ratio, the copolymer grafting route would yield better results.

scholarly journals A Recommender System for Inverse Design of Polycarbonates and Polyesters

2020 ◽  
Author(s):  
Nathaniel Park ◽  
Dmitry Yu. Zubarev ◽  
James L. Hedrick ◽  
Vivien Kiyek ◽  
Christiaan Corbet ◽  
...  
Keyword(s):  
Ring Opening ◽  
High Performance ◽  
Recommendation System ◽  
Polymeric Materials ◽  
Monomer Conversion ◽  
Design Strategy ◽  
Ring Opening Polymerization ◽  
Inverse Design ◽  
False Negatives ◽  
Accelerate Development

The convergence of artificial intelligence and machine learning with material science holds significant promise to rapidly accelerate development timelines of new high-performance polymeric materials. Within this context, we report an inverse design strategy for polycarbonate and polyester discovery based on a recommendation system that proposes polymerization experiments that are likely to produce materials with targeted properties. Following recommendations of the system driven by the historical ring-opening polymerization results, we carried out experiments targeting specific ranges of monomer conversion and dispersity of the polymers obtained from cyclic lactones and carbonates. The results of the experiments were in close agreement with the recommendation targets with few false negatives or positives obtained for each class.<br>

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