Influences of molecular packing on the charge mobility of organic semiconductors: from quantum charge transfer rate theory beyond the first-order perturbation

2011 ◽  
Vol 13 (20) ◽  
pp. 9736 ◽  
Author(s):  
Guangjun Nan ◽  
Qiang Shi ◽  
Zhigang Shuai ◽  
Zesheng Li
Keyword(s):  
Charge Transfer ◽  
Organic Semiconductors ◽  
Transfer Rate ◽  
Order Perturbation ◽  
Rate Theory ◽  
Charge Mobility ◽  
First Order ◽  
Charge Transfer Rate ◽  
First Order Perturbation ◽  
Quantum Charge

Note on Interference Effects in Two-Step Reaction Processes

1975 ◽  
Vol 53 (23) ◽  
pp. 2590-2592
Author(s):  
J. Cejpek ◽  
J. Dobeš
Keyword(s):  
Perturbation Theory ◽  
Point Of View ◽  
Order Perturbation ◽  
Interference Effects ◽  
Qualitative Explanation ◽  
First Order ◽  
One Step ◽  
Step Transition ◽  
Reaction Processes ◽  
First Order Perturbation

The reaction processes in which a one-step transition is forbidden are analyzed from the point of view of the first order perturbation theory. The interference between two competing two-step reaction paths is found to be always constructive. A qualitative explanation of the experimentally observed reaction intensities is presented.

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