Isolation and characterization of main group and late transition metal complexes using orthometallated imine ligands

2012 ◽  
Vol 41 (3) ◽  
pp. 860-870 ◽  
Author(s):  
John F. Beck ◽  
Joseph A. R. Schmidt
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Main Group ◽  
Late Transition Metal ◽  
Isolation And Characterization ◽  
Late Transition ◽  
Imine Ligands

Straightforward synthesis and catalytic applications of rigid N,O-type calixarene ligands

2015 ◽  
Vol 13 (46) ◽  
pp. 11189-11193 ◽  
Author(s):  
Varun Rawat ◽  
Konstantin Press ◽  
Israel Goldberg ◽  
Arkadi Vigalok
Keyword(s):  
Catalytic Activity ◽  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Main Group ◽  
Late Transition Metal ◽  
Organic Transformations ◽  
One Step ◽  
Catalytic Applications ◽  
Late Transition

Here, we report a simple one-step access to new rigid N,O-calixarene ligands which is based on copper-catalized amination at the lower rim. We also present their main group and late transition metal complexes which show superior catalytic activity, in several organic transformations, compared with known metal calixarene complexes.

Electron rich bidentate phosphinimine-imine ligands: Synthesis and reactivity of late transition metal complexes

2010 ◽  
Vol 39 (2) ◽  
pp. 541-547 ◽  
Author(s):  
Christopher J. Wallis ◽  
Ira L. Kraft ◽  
Brian O. Patrick ◽  
Parisa Mehrkhodavandi
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Late Transition Metal ◽  
Late Transition ◽  
Imine Ligands

Hydrosilylation as an efficient tool for polymer synthesis and modification with methacrylates

RSC Advances ◽  
2015 ◽  
Vol 5 (8) ◽  
pp. 5879-5885 ◽  
Author(s):  
Nuttapol Risangud ◽  
Zhijian Li ◽  
Athina Anastasaki ◽  
Paul Wilson ◽  
Kristian Kempe ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Polymer Synthesis ◽  
Late Transition Metal ◽  
Efficient Tool ◽  
Silicon Compounds ◽  
Late Transition

Hydrosilylation is a well-established reaction for the preparation of organo-silicon compounds, in which vinyl groups react with silanes (Si–H) usually catalysed by late transition metal complexes, most often Pt(ii) complexes.

Electron-density distributions in selected ferrocenyl-pyrazolyl late transition-metal complexes

2018 ◽  
Vol 20 (17) ◽  
pp. 11682-11691
Author(s):  
M. A. Peck ◽  
G. R. Hearne ◽  
C. Obuah ◽  
J. Darkwa
Keyword(s):  
Mössbauer Spectroscopy ◽  
Transition Metal ◽  
Metal Complexes ◽  
Electron Density ◽  
Transition Metal Complexes ◽  
Mossbauer Spectroscopy ◽  
Late Transition Metal ◽  
Density Distributions ◽  
Mößbauer Spectroscopy ◽  
Late Transition

57Fe Mössbauer spectroscopy has been used to study electronic dispersions in complexes of Fe, Co, Ni and Pd anchored onto 3-ferrocenyl-5-methylpyrazolylmethylenepyridine and 3-ferrocenylpyrazolylmethylenepyridine ligands.

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