Two dimensional directed π–π interactions in a linear shaped bi-1,3,4-oxadiazole derivative to achieve organic single crystal with highly polarized fluorescence and amplified spontaneous emissions

2012 ◽  
Vol 22 (47) ◽  
pp. 24605 ◽  
Author(s):  
Songnan Qu ◽  
Qipeng Lu ◽  
Shaohang Wu ◽  
Lijun Wang ◽  
Xingyuan Liu
2019 ◽  
Vol 75 (2) ◽  
pp. 196-199 ◽  
Author(s):  
Ning-Ning Chen ◽  
Jian-Ning Ni ◽  
Jun Wang ◽  
Jian-Qing Tao

A novel two-dimensional (2D) ZnII coordination framework, poly[[μ-1,3-bis(2-methyl-1H-imidazol-1-yl)benzene](μ-5-nitrobenzene-1,3-dicarboxylato)zinc(II)], [Zn(C8H3NO6)(C14H14N4)] n or [Zn(NO2-BDC)(1,3-BMIB)] n [1,3-BMIB is 1,3-bis(2-methyl-1H-imidazol-1-yl)benzene and NO2-H2BDC is 5-nitrobenzene-1,3-dicarboxylic acid], has been prepared and characterized by IR, elemental analysis, thermal analysis and single-crystal X-ray diffraction. Single-crystal X-ray diffraction analysis revealed that the compound is a new 2D polymer with a 63 topology parallel to the (10\overline{2}) crystal planes based on left-handed helices, right-handed helical NO2-BDC–Zn chains and [Zn2(1,3-BMIB)2] n clusters. In the crystal, adjacent layers are further connected by C—H...O hydrogen bonds, C—H...π interactions, C—O...π interactions and N—O...π interactions to form a three-dimensional structure in the solid state. In addition, the compound exhibits strong fluorescence emissions in the solid state at room temperature.


2008 ◽  
Author(s):  
Takafumi Uemura ◽  
Masakazu Yamagishi ◽  
Yukihiro Tominari ◽  
Jun Takeya

Author(s):  
Amr Elattar ◽  
Hiroo Suzuki ◽  
Ryuji Mishima ◽  
Kodai Nakao ◽  
Hiromi Ota ◽  
...  

Facile synthesis of single crystal of two-dimensional mixed-halide copper-based perovskites with tunable band gaps and their capability of exfoliation and reversible thermochromism.


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