Effect of thermal ageing on the structure and catalytic activity of Pd/CeO2 prepared using arc-plasma process

2014 ◽  
Vol 4 (9) ◽  
pp. 2990-2996 ◽  
Author(s):  
Satoshi Hinokuma ◽  
Hiroaki Fujii ◽  
Yasuo Katsuhara ◽  
Keita Ikeue ◽  
Masato Machida

High CO oxidation activity of Pd/CeO2 as prepared by using an arc-plasma process was lost by thermal ageing at 600 °C in air, whereas further ageing at 900 °C enhanced significantly the activity, exceeding that of the as-prepared catalyst.

2015 ◽  
Vol 5 (8) ◽  
pp. 3945-3952 ◽  
Author(s):  
Satoshi Hinokuma ◽  
Noriko Yamashita ◽  
Yasuo Katsuhara ◽  
Hayato Kogami ◽  
Masato Machida

Fe–Cu bimetal nanoparticles were prepared by the dual-mode arc-plasma process. The CO oxidation activity of Fe–Cu/CeO2 was enhanced by thermal aging at 900 °C. CO oxidation over aged Fe–Cu/CeO2 proceeded via the Mars–van Krevelen mechanism.


2015 ◽  
Vol 51 (87) ◽  
pp. 15823-15826 ◽  
Author(s):  
Junya Ohyama ◽  
Taiki Koketsu ◽  
Yuta Yamamoto ◽  
Shigeo Arai ◽  
Atsushi Satsuma

Au/TiO2 prepared by CO treatment showed high catalytic activity for CO oxidation due to twinned structure of Au nanoparticles.


2016 ◽  
Vol 18 (44) ◽  
pp. 30622-30629 ◽  
Author(s):  
L. S. R. Kumara ◽  
Osami Sakata ◽  
Shinji Kohara ◽  
Anli Yang ◽  
Chulho Song ◽  
...  

The 3D configuration models of novel fcc and conventional hcp ruthenium nanoparticles are studied to elucidate their CO oxidation activity.


RSC Advances ◽  
2018 ◽  
Vol 8 (39) ◽  
pp. 21699-21711
Author(s):  
Yu Huanhuan ◽  
Chen Fayun ◽  
Zhubaolin Zhubaolin ◽  
Huang Weiping ◽  
Zhang Shoumin

A CePO4–GdPO4 composite was prepared by a general ultrasound method and could be a good support for gold nanocatalysts. Au/CePO4–GdPO4 catalysts with a low content of gold showed good catalytic activity, high temperature resistance and stability for CO oxidation.


2012 ◽  
Vol 85 (1) ◽  
pp. 144-149 ◽  
Author(s):  
Satoshi Hinokuma ◽  
Madoka Okamoto ◽  
Eriko Ando ◽  
Keita Ikeue ◽  
Masato Machida

2012 ◽  
Vol 116 (45) ◽  
pp. 24054-24059 ◽  
Author(s):  
Kamran Qadir ◽  
Sang Hoon Kim ◽  
Sun Mi Kim ◽  
Heonphil Ha ◽  
Jeong Young Park

2013 ◽  
Vol 454 ◽  
pp. 53-58 ◽  
Author(s):  
Sang Hoon Kim ◽  
Chan-Ho Jung ◽  
Nruparaj Sahu ◽  
Dahee Park ◽  
Jung Yeul Yun ◽  
...  

RSC Advances ◽  
2016 ◽  
Vol 6 (70) ◽  
pp. 65950-65959 ◽  
Author(s):  
Pengfei Zhao ◽  
Pengfei Yu ◽  
Zijian Feng ◽  
Rong Chen ◽  
Liwei Jia ◽  
...  

CO conversion as a function of temperature for SMO and LCO is shown in the graphical abstract image. SMO reached 95% conversion at 150 °C and showed a better CO oxidation activity than LCO.


2014 ◽  
Vol 955-959 ◽  
pp. 51-55
Author(s):  
Ting Ting Hu ◽  
Lin Hua Zhu

Gold catalysts supported on Na-MMT and Al-PILM noted as Au/Na-MMT and Au/Al-PILM respectively were prepared using Au(en)2Cl3 as precursor, and the catalytic oxidation activity for CO oxidation was investigated. The influence of different carriers on the conversion of CO was discussed. The phase of catalysts, the actual gold loading and the morphology of gold nanoparticles were characterized by X-ray diffraction(XRD), X-ray fluorescence analysis(XRF) and Transmission electron microscopy(TEM). The results showed that Au/Al-PILM exhibited higher catalytic activity for the oxidation reaction of CO, and 100% conversion of CO was achieved at reaction temperature of 250°C when gold precursor was loaded on the Al-PILM carrier at 60°Cand calcined it at 450°C for 1h.


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