Controllable crystalline preferred orientation in Li–Co–Ni–Mn oxide cathode thin films for all-solid-state lithium batteries

Nanoscale ◽  
2014 ◽  
Vol 6 (18) ◽  
pp. 10611 ◽  
Author(s):  
Guoqiang Tan ◽  
Feng Wu ◽  
Jun Lu ◽  
Renjie Chen ◽  
Li Li ◽  
...  
Keyword(s):  
Thin Films ◽  
Solid State ◽  
Lithium Batteries ◽  
Preferred Orientation ◽  
Mn Oxide ◽  
Oxide Cathode

scholarly journals All ceramic cathode composite design and manufacturing towards low interfacial resistance for garnet-based solid-state lithium batteries

2020 ◽  
Vol 13 (12) ◽  
pp. 4930-4945 ◽  
Author(s):  
Kun Joong Kim ◽  
Jennifer L. M. Rupp
Keyword(s):  
Solid State ◽  
Lithium Batteries ◽  
Processing Temperature ◽  
Interfacial Resistance ◽  
Sintering Additives ◽  
Oxide Cathode ◽  
All Ceramic ◽  
Design And Manufacturing ◽  
Formation Method ◽  
Interfacial Impedance

Solution-assisted all-oxide-cathode formation method allows reduction of processing temperature without using sintering additives, demonstrating the lowest interfacial impedance in garnet-based solid-state lithium batteries.

High-rate and long-life Ni-rich oxide cathode under high mass loading for sulfide-based all-solid-state lithium batteries

2021 ◽  
pp. 138917
Author(s):  
Xuelei Li ◽  
Yiming Sun ◽  
Zhenyu Wang ◽  
Xiaoqing Wang ◽  
Hongzhou Zhang ◽  
...  
Keyword(s):  
Solid State ◽  
Lithium Batteries ◽  
High Rate ◽  
High Mass ◽  
Mass Loading ◽  
Oxide Cathode ◽  
Long Life

Application of LiCoO2Particles Coated with Lithium Ortho-Oxosalt Thin Films to Sulfide-Type All-Solid-State Lithium Batteries

2015 ◽  
Vol 162 (8) ◽  
pp. A1610-A1616 ◽  
Author(s):  
Yusuke Ito ◽  
Yuki Sakurai ◽  
So Yubuchi ◽  
Atsushi Sakuda ◽  
Akitoshi Hayashi ◽  
...  
Keyword(s):  
Thin Films ◽  
Solid State ◽  
Lithium Batteries

Low Interface Resistance in Solid-State Lithium Batteries Using Spinel LiNi0.5Mn1.5O4(111) Epitaxial Thin Films

2020 ◽  
Vol 3 (2) ◽  
pp. 1358-1363
Author(s):  
Hideyuki Kawasoko ◽  
Tetsuroh Shirasawa ◽  
Susumu Shiraki ◽  
Toru Suzuki ◽  
Shigeru Kobayashi ◽  
...  
Keyword(s):  
Thin Films ◽  
Solid State ◽  
Lithium Batteries ◽  
Epitaxial Thin Films ◽  
Interface Resistance

TEM studies of solid-state reactions in sputter-deposited Nb/Al multilayer thin films

1996 ◽  
Vol 54 ◽  
pp. 1020-1021
Author(s):  
F. Ma ◽  
S. Vivekanand ◽  
K. Barmak ◽  
C. Michaelsen
Keyword(s):  
Thin Films ◽  
Solid State ◽  
Stoichiometric Composition ◽  
Analytical Electron Microscopy ◽  
Grain Structure ◽  
Solid State Reactions ◽  
Multilayer Thin Films ◽  
X Ray Diffraction ◽  
X Ray ◽  
Sputter Deposited

Solid state reactions in sputter-deposited Nb/Al multilayer thin films have been studied by transmission and analytical electron microscopy (TEM/AEM), differential scanning calorimetry (DSC) and X-ray diffraction (XRD). The Nb/Al multilayer thin films for TEM studies were sputter-deposited on (1102)sapphire substrates. The periodicity of the films is in the range 10-500 nm. The overall composition of the films are 1/3, 2/1, and 3/1 Nb/Al, corresponding to the stoichiometric composition of the three intermetallic phases in this system.Figure 1 is a TEM micrograph of an as-deposited film with periodicity A = dA1 + dNb = 72 nm, where d's are layer thicknesses. The polycrystalline nature of the Al and Nb layers with their columnar grain structure is evident in the figure. Both Nb and Al layers exhibit crystallographic texture, with the electron diffraction pattern for this film showing stronger diffraction spots in the direction normal to the multilayer. The X-ray diffraction patterns of all films are dominated by the Al(l 11) and Nb(l 10) peaks and show a merging of these two peaks with decreasing periodicity.

Progress and perspectives on halide lithium conductors for all-solid-state lithium batteries

2020 ◽  
Vol 13 (5) ◽  
pp. 1429-1461 ◽  
Author(s):  
Xiaona Li ◽  
Jianwen Liang ◽  
Xiaofei Yang ◽  
Keegan R. Adair ◽  
Changhong Wang ◽  
...  
Keyword(s):  
Energy Storage ◽  
Solid State ◽  
Lithium Batteries ◽  
Electrochemical Stability ◽  
Superionic Conductors ◽  
Fundamental Understanding ◽  
Potential Applications ◽  
Synthesis Routes

This review focuses on fundamental understanding, various synthesis routes, chemical/electrochemical stability of halide-based lithium superionic conductors, and their potential applications in energy storage as well as related challenges.

Experimental and numerical analysis to identify the performance limiting mechanisms in solid-state lithium cells under pulse operating conditions

2019 ◽  
Vol 21 (41) ◽  
pp. 22740-22755 ◽  
Author(s):  
Mei-Chin Pang ◽  
Yucang Hao ◽  
Monica Marinescu ◽  
Huizhi Wang ◽  
Mu Chen ◽  
...  
Keyword(s):  
Solid State ◽  
Numerical Analysis ◽  
Energy Density ◽  
Lithium Ion Batteries ◽  
Lithium Batteries ◽  
Safety Concern ◽  
Lithium Ion ◽  
Thermal Runaway ◽  
Operating Conditions ◽  
Lithium Cells

Solid-state lithium batteries could reduce the safety concern due to thermal runaway while improving the gravimetric and volumetric energy density beyond the existing practical limits of lithium-ion batteries.

Phase transformation and preferred orientation in carboxylate derived ZrO2 thin films on silicon substates

1992 ◽  
Vol 7 (11) ◽  
pp. 3065-3071 ◽  
Author(s):  
Peir-Yung Chu ◽  
Isabelle Campion ◽  
Relva C. Buchanan
Keyword(s):  
Thin Films ◽  
Heat Treatment ◽  
Phase Transformation ◽  
Heating Rate ◽  
Tetragonal Phase ◽  
Monoclinic Phase ◽  
Preferred Orientation ◽  
Si Substrate ◽  
Interfacial Diffusion ◽  
Deposited Films

Phase transformation and preferred orientation in ZrO2 thin films, deposited on Si(111) and Si(100) substrates, and prepared by heat treatment from carboxylate solution precursors were investigated. The deposited films were amorphous below 450 °C, transforming gradually to the tetragonal and monoclinic phases on heating. The monoclinic phase developed from the tetragonal phase displacively, and exhibited a strong (111) preferred orientation at temperature as low as 550 °C. The degree of preferred orientation and the tetragonal-to-monoclinic phase transformation were controlled by heating rate, soak temperature, and time. Interfacial diffusion into the film from the Si substrate was negligible at 700 °C and became significant only at 900 °C, but for films thicker than 0.5 μm, overall preferred orientation exceeded 90%.

Designing Polymer‐in‐Salt Electrolyte and Fully Infiltrated 3D Electrode for Integrated Solid‐State Lithium Batteries

2021 ◽  
Author(s):  
Wenyi Liu ◽  
Chengjun Yi ◽  
Linpo Li ◽  
Shuailei Liu ◽  
Qiuyue Gui ◽  
...  
Keyword(s):  
Solid State ◽  
Lithium Batteries ◽  
3D Electrode
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