scholarly journals All ceramic cathode composite design and manufacturing towards low interfacial resistance for garnet-based solid-state lithium batteries

2020 ◽  
Vol 13 (12) ◽  
pp. 4930-4945 ◽  
Author(s):  
Kun Joong Kim ◽  
Jennifer L. M. Rupp
Keyword(s):  
Solid State ◽  
Lithium Batteries ◽  
Processing Temperature ◽  
Interfacial Resistance ◽  
Sintering Additives ◽  
Oxide Cathode ◽  
All Ceramic ◽  
Design And Manufacturing ◽  
Formation Method ◽  
Interfacial Impedance

Solution-assisted all-oxide-cathode formation method allows reduction of processing temperature without using sintering additives, demonstrating the lowest interfacial impedance in garnet-based solid-state lithium batteries.

High-rate and long-life Ni-rich oxide cathode under high mass loading for sulfide-based all-solid-state lithium batteries

2021 ◽  
pp. 138917
Author(s):  
Xuelei Li ◽  
Yiming Sun ◽  
Zhenyu Wang ◽  
Xiaoqing Wang ◽  
Hongzhou Zhang ◽  
...  
Keyword(s):  
Solid State ◽  
Lithium Batteries ◽  
High Rate ◽  
High Mass ◽  
Mass Loading ◽  
Oxide Cathode ◽  
Long Life

scholarly journals Effect of Liquid Electrolyte Soaking on the Interfacial Resistance of Li7La3Zr2O12 for All-Solid-State Lithium Batteries

2020 ◽  
Vol 12 (18) ◽  
pp. 20605-20612 ◽  
Author(s):  
Münir M. Besli ◽  
Camille Usubelli ◽  
Michael Metzger ◽  
Vikram Pande ◽  
Katherine Harry ◽  
...  
Keyword(s):  
Solid State ◽  
Lithium Batteries ◽  
Liquid Electrolyte ◽  
Interfacial Resistance

scholarly journals Solid-State Li-Ion Batteries Operating at Room Temperature Using New Borohydride Argyrodite Electrolytes

Materials ◽  
2020 ◽  
Vol 13 (18) ◽  
pp. 4028
Author(s):  
Anh Ha Dao ◽  
Pedro López-Aranguren ◽  
Junxian Zhang ◽  
Fermín Cuevas ◽  
Michel Latroche
Keyword(s):  
Solid State ◽  
Room Temperature ◽  
Electrochemical Impedance ◽  
Coulombic Efficiency ◽  
Active Material ◽  
Cathode Side ◽  
Oxide Material ◽  
Interfacial Resistance ◽  
Impedance Measurements ◽  
Oxide Cathode

Using a new class of (BH4)− substituted argyrodite Li6PS5Z0.83(BH4)0.17, (Z = Cl, I) solid electrolyte, Li-metal solid-state batteries operating at room temperature have been developed. The cells were made by combining the modified argyrodite with an In-Li anode and two types of cathode: an oxide, LixMO2 (M = ⅓ Ni, ⅓ Mn, ⅓ Co; so called NMC) and a titanium disulfide, TiS2. The performance of the cells was evaluated through galvanostatic cycling and Alternating Current AC electrochemical impedance measurements. Reversible capacities were observed for both cathodes for at least tens of cycles. However, the high-voltage oxide cathode cell shows lower reversible capacity and larger fading upon cycling than the sulfide one. The AC impedance measurements revealed an increasing interfacial resistance at the cathode side for the oxide cathode inducing the capacity fading. This resistance was attributed to the intrinsic poor conductivity of NMC and interfacial reactions between the oxide material and the argyrodite electrolyte. On the contrary, the low interfacial resistance of the TiS2 cell during cycling evidences a better chemical compatibility between this active material and substituted argyrodites, allowing full cycling of the cathode material, 240 mAhg−1, for at least 35 cycles with a coulombic efficiency above 97%.

Controllable crystalline preferred orientation in Li–Co–Ni–Mn oxide cathode thin films for all-solid-state lithium batteries

Nanoscale ◽  
2014 ◽  
Vol 6 (18) ◽  
pp. 10611 ◽  
Author(s):  
Guoqiang Tan ◽  
Feng Wu ◽  
Jun Lu ◽  
Renjie Chen ◽  
Li Li ◽  
...  
Keyword(s):  
Thin Films ◽  
Solid State ◽  
Lithium Batteries ◽  
Preferred Orientation ◽  
Mn Oxide ◽  
Oxide Cathode

Reducing the Interfacial Resistance in All‐Solid‐State Lithium Batteries Based on Oxide Ceramic Electrolytes

2019 ◽  
Vol 6 (12) ◽  
pp. 2970-2983 ◽  
Author(s):  
Zhouyang Jiang ◽  
Qingyue Han ◽  
Suqing Wang ◽  
Haihui Wang
Keyword(s):  
Solid State ◽  
Lithium Batteries ◽  
Oxide Ceramic ◽  
Interfacial Resistance ◽  
Ceramic Electrolytes

Interfacial Engineering Facilitating Robust Li6.35Ga0.15La3Zr1.8Nb0.2O12 for All-solid-state Lithium Batteries

2021 ◽  
Author(s):  
Hongyang Fan ◽  
Fuxin Wei ◽  
Jianchuan Luo ◽  
Shufen Wu ◽  
Xiying JIan ◽  
...  
Keyword(s):  
Solid State ◽  
Lithium Ion Batteries ◽  
Lithium Batteries ◽  
Organic Liquid ◽  
Lithium Ion ◽  
Liquid Electrolyte ◽  
Inherent Safety ◽  
Interfacial Resistance ◽  
Safety Issues ◽  
Interfacial Engineering

All-solid-state Lithium batteries are promising substitutes for traditional lithium ion batteries to solve the inherent safety issues of organic liquid electrolyte. However, the large interfacial resistance renders the batteries insufficient...

An advanced construction strategy of all-solid-state lithium batteries with excellent interfacial compatibility and ultralong cycle life

2017 ◽  
Vol 5 (32) ◽  
pp. 16984-16993 ◽  
Author(s):  
Zhihua Zhang ◽  
Yanran Zhao ◽  
Shaojie Chen ◽  
Dongjiu Xie ◽  
Xiayin Yao ◽  
...  
Keyword(s):  
Solid State ◽  
Lithium Batteries ◽  
Electronic Conductivity ◽  
Cycle Life ◽  
Cycle Performance ◽  
Interfacial Resistance ◽  
Interfacial Compatibility ◽  
Construction Strategy

The inferior cycle performance of All-solid-state lithium batteries (ASSLBs) resulting from the low mixed ionic and electronic conductivity in the electrodes, as well as the large interfacial resistance between the electrodes and the electrolyte have been optimized in this work.

Progress and perspectives on halide lithium conductors for all-solid-state lithium batteries

2020 ◽  
Vol 13 (5) ◽  
pp. 1429-1461 ◽  
Author(s):  
Xiaona Li ◽  
Jianwen Liang ◽  
Xiaofei Yang ◽  
Keegan R. Adair ◽  
Changhong Wang ◽  
...  
Keyword(s):  
Energy Storage ◽  
Solid State ◽  
Lithium Batteries ◽  
Electrochemical Stability ◽  
Superionic Conductors ◽  
Fundamental Understanding ◽  
Potential Applications ◽  
Synthesis Routes

This review focuses on fundamental understanding, various synthesis routes, chemical/electrochemical stability of halide-based lithium superionic conductors, and their potential applications in energy storage as well as related challenges.

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