Au–Pd alloy catalyst with high performance for hydrogen generation from formic acid-formate solution at nearly 0 °C

RSC Advances ◽  
2014 ◽  
Vol 4 (84) ◽  
pp. 44500-44503 ◽  
Author(s):  
Shuang Wu ◽  
Fan Yang ◽  
Pingchuan Sun ◽  
Tiehong Chen
Keyword(s):  
Carbon Black ◽  
Formic Acid ◽  
High Performance ◽  
Hydrogen Generation ◽  
Alloy Nanoparticles ◽  
Metal Precursors ◽  
Pd Alloy ◽  
Ice Water ◽  
Formate Solution ◽  
Alloy Catalyst

By reduction of mixed noble metal precursors in aqueous phase under ice-water bath conditions, well dispersed Au–Pd alloy nanoparticles supported on carbon black were facilely prepared and exhibited high activity for hydrogen generation from formic acid-formate solution even at nearly 0 °C.

Synthesis and Characterization of Highly Dispersed Au-Pd Alloy Nanoparticles Supported on ZrO2

2013 ◽  
Vol 716 ◽  
pp. 89-93 ◽  
Author(s):  
Wen Jing Cui ◽  
Wu Lan Ao ◽  
Yu Lin Zhang ◽  
Zhao Ri Ge Tu Bao
Keyword(s):  
Reduction Method ◽  
Preparation Method ◽  
Catalytic Properties ◽  
Alloy Nanoparticles ◽  
Highly Active ◽  
Highly Dispersed ◽  
Pd Alloy ◽  
Protection Agent ◽  
Alloy Catalyst

This paper investigated Au-Pd/ZrO2alloy catalyst prepared by solution reduction method using NaBH4as reducing agent and L-lysine as protection agent. TEM, EDX, XRD, UV-Vis and XPS were employed to investigate the morphology, composition, dispersity and catalytic properties of the catalyst. The results show that Au-Pd/ZrO2alloy catalyst is uniform and highly dispersed. Furthermore, this preparation method leads to highly active Au-Pd/ZrO2alloy catalyst for the selective oxidation of benzyl alcohol.

scholarly journals High-Performance Palladium-Based Catalyst Boosted by Thin-layered Carbon Nitride for Hydrogen Generation from Formic Acid

2020 ◽  
Vol 0 (0) ◽  
pp. 2003035-0
Author(s):  
Zhicong Sun ◽  
Ergui Luo ◽  
Qinglei Meng ◽  
Xian Wang ◽  
Junjie Ge ◽  
...  
Keyword(s):  
Formic Acid ◽  
High Performance ◽  
Carbon Nitride ◽  
Hydrogen Generation

Facile synthesis of AgAuPd/graphene with high performance for hydrogen generation from formic acid

2015 ◽  
Vol 3 (28) ◽  
pp. 14535-14538 ◽  
Author(s):  
Si-jia Li ◽  
Yun Ping ◽  
Jun-Min Yan ◽  
Hong-Li Wang ◽  
Ming Wu ◽  
...  
Keyword(s):  
Formic Acid ◽  
High Performance ◽  
Hydrogen Generation ◽  
Catalytic Performance ◽  
Acid Decomposition ◽  
Facile Synthesis ◽  
Formic Acid Decomposition ◽  
Excellent Catalytic Performance

A well dispersed and ultrafine AgAuPd nanoalloy supported on rGO shows excellent catalytic performance toward hydrogen generation from formic acid decomposition.

Three-dimensionally ordered mesoporous Co 3 O 4 -supported Au–Pd alloy nanoparticles: High-performance catalysts for methane combustion

2015 ◽  
Vol 332 ◽  
pp. 13-24 ◽  
Author(s):  
Zhixing Wu ◽  
Jiguang Deng ◽  
Yuxi Liu ◽  
Shaohua Xie ◽  
Yang Jiang ◽  
...  
Keyword(s):  
High Performance ◽  
Methane Combustion ◽  
Alloy Nanoparticles ◽  
Ordered Mesoporous ◽  
Pd Alloy

scholarly journals Formation of Pt-Based Alloy Nanoparticles Assisted by Molybdenum Hexacarbonyl

Nanomaterials ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 1825
Author(s):  
Gerard M. Leteba ◽  
David R. G. Mitchell ◽  
Pieter B. J. Levecque ◽  
Eric van Steen ◽  
Candace I. Lang
Keyword(s):  
High Performance ◽  
Morphological Evolution ◽  
High Index ◽  
Solution Phase ◽  
Alloy Nanoparticles ◽  
Molybdenum Hexacarbonyl ◽  
Metal Precursors ◽  
Synthetic Procedure ◽  
Selection Of

We report on an optimized, scalable solution-phase synthetic procedure for the fabrication of fine-tuned monodisperse nanostructures (Pt(NiCo), PtNi and PtCo). The influence of different solute metal precursors and surfactants on the morphological evolution of homogeneous alloy nanoparticles (NPs) has been investigated. Molybdenum hexacarbonyl (Mo(CO)6) was used as the reductant. We demonstrate that this solution-based strategy results in uniform-sized NPs, the morphology of which can be manipulated by appropriate selection of surfactants and solute metal precursors. Co-surfactants (oleylamine, OAm, and hexadecylamine, HDA) enabled the development of a variety of high-index faceted NP morphologies with varying degrees of curvatures while pure OAm selectively produced octahedral NP morphologies. This Mo(CO)6-based synthetic protocol offers new avenues for the fabrication of multi-structured alloy NPs as high-performance electrocatalysts.

scholarly journals Highly efficient hydrogen generation from formic acid using a reduced graphene oxide-supported AuPd nanoparticle catalyst

2016 ◽  
Vol 52 (22) ◽  
pp. 4171-4174 ◽  
Author(s):  
Xinchun Yang ◽  
Pradip Pachfule ◽  
Yao Chen ◽  
Nobuko Tsumori ◽  
Qiang Xu
Keyword(s):  
Graphene Oxide ◽  
Catalytic Activity ◽  
Formic Acid ◽  
Reduced Graphene Oxide ◽  
Noble Metal ◽  
Hydrogen Generation ◽  
Alloy Nanoparticles ◽  
Reduced Graphene ◽  
Highly Dispersed ◽  
Nanoparticle Catalyst

Highly dispersed AuPd alloy nanoparticles have been successfully immobilized on reduced graphene oxide using a facile non-noble metal sacrificial method, which exhibit the highest catalytic activity for dehydrogenation of formic acid at 323 K.

Amine-functionalized graphene nanosheet-supported PdAuNi alloy nanoparticles: efficient nanocatalyst for formic acid dehydrogenation

2018 ◽  
Vol 42 (19) ◽  
pp. 16103-16114 ◽  
Author(s):  
Ahmet Bulut ◽  
Mehmet Yurderi ◽  
Murat Kaya ◽  
Murat Aydemir ◽  
Akin Baysal ◽  
...  
Keyword(s):  
Formic Acid ◽  
Room Temperature ◽  
Hydrogen Generation ◽  
Alloy Nanoparticles ◽  
Functionalized Graphene ◽  
Graphene Nanosheet ◽  
Amine Functionalized ◽  
Free Hydrogen ◽  
Formic Acid Dehydrogenation

PdAuNi/f-GNS provides CO-free hydrogen generation from additive-free dehydrogenation of formic acid even at room temperature.

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