Green catalysis by nanoparticulate catalysts developed for flow processing? Case study of glucose hydrogenation

RSC Advances ◽  
2015 ◽  
Vol 5 (21) ◽  
pp. 15898-15908 ◽  
Author(s):  
Dörthe Gericke ◽  
Denise Ott ◽  
Valentina G. Matveeva ◽  
Esther Sulman ◽  
Atte Aho ◽  
...  

Heterogeneous catalysis, flow chemistry, continuous processing, green solvents, catalyst immobilization and recycling are some of the most relevant, emerging key technologies to achieve green synthesis.

Author(s):  
Matthew J. Harding ◽  
Bin Feng ◽  
Rafael Lopez-Rodriguez ◽  
Heather O'Connor ◽  
Denis Dowling ◽  
...  

A low-cost, modular, robust, and easily customisable continuous liquid–liquid phase separator has been developed that uses a tubular membrane and annular channels to allow high fluidic throughputs while maintaining rapid, surface wetting dominated, phase separation.


ACS Catalysis ◽  
2021 ◽  
pp. 5189-5201
Author(s):  
Max Schumann ◽  
Monia R. Nielsen ◽  
Thomas E. L. Smitshuysen ◽  
Thomas W. Hansen ◽  
Christian D. Damsgaard ◽  
...  

2018 ◽  
Vol 14 ◽  
pp. 1655-1659 ◽  
Author(s):  
Ugo Azzena ◽  
Massimo Carraro ◽  
Gloria Modugno ◽  
Luisa Pisano ◽  
Luigi Urtis

The application of heterogeneous catalysis and green solvents to the set up of widely employed reactions is a challenge in contemporary organic chemistry. We applied such an approach to the synthesis and further conversion of tetrahydropyranyl ethers, an important class of compounds widely employed in multistep syntheses. Several alcohols and phenols were almost quantitatively converted into the corresponding tetrahydropyranyl ethers in cyclopentyl methyl ether or 2-methyltetrahydrofuran employing NH4HSO4 supported on SiO2 as a recyclable acidic catalyst. Easy work up of the reaction mixtures and the versatility of the solvents allowed further conversion of the reaction products under one-pot reaction conditions.


2010 ◽  
Vol 139-141 ◽  
pp. 1455-1459 ◽  
Author(s):  
Qi Cheng Zhang ◽  
Lin Zhang ◽  
Yong Liang Luo ◽  
Bao Lu Wang

Experience accumulation and reuse are very important for manufacturing of complex product. However, there is no mechanism to support such function in the integrated manufacturing system based on semantic SOA which is generally accepted as an effective approach to raise productivity. Specific to this problem, we propose a solution by building a case-base in semantic SOA to improve the traditional framework, in which case-base can accumulates the experiences by case study and reuse them by case retrieve. In this paper, the new architecture and workflow of the semantic SOA with build-in case-base is designed, merging and maximizing the advantages of both case-base and SOA to make up the lack of experience accumulation and reuse mechanism. Then, combined with field characteristics of complex products’ manufacturing process, construction and implementation concerning key technologies and methods of case-base are comprehensively elaborated.


2007 ◽  
Vol 79 (11) ◽  
pp. v
Author(s):  
James R. Bull

IUPAC's initiatives and publications have been closely identified with green chemistry over the past several years. However, a significant milestone was reached in a project on Synthetic Pathways and Processes in Green Chemistry, chaired by Prof. Pietro Tundo (University of Venice), as a first IUPAC undertaking devoted exclusively to the theme of green chemistry. This culminated in publication of a Special Topic issue of Pure and Applied Chemistry [Pure Appl. Chem.72 (7), (2000); <http://www.iupac.org/publications/pac/2000/7207>], which attracted an exceptionally high level of readership interest and has hitherto accumulated a record number of nearly 900 citations. Indeed, one of the papers published in that collection, Ionic Liquids: Green Solvents of the Future, by M. J. Earle and K. R. Seddon (The Queen's University of Belfast) [Pure Appl. Chem.72 (7), 1391 (2000)], boasts no fewer than 349 citations (recorded on 30 April 2007)!Shortly thereafter, Prof. M. Kidwai and his colleagues at the University of Delhi launched an IUPAC-sponsored International Symposium on Green Chemistry in January 2001 [Pure Appl. Chem.73 (1), (2001); <http://www.iupac.org/publications/pac/2001/7301>], and have since organized a sequel in 2006 [Pure Appl. Chem.78 (11), (2006); <http://www.iupac.org/publications/pac/2006/7811>]. The record of that first event focused strongly on insights into green catalysis and methodology, and also has the distinction of heading the citation record for PAC event collections in 2001. Later in 2001, the Conference on Green Chemistry: Toward Environmentally Benign Processes and Products was held in Boulder, Colorado, under the guidance of Drs. D. L. Hjeresen and P. T. Anastas [Pure Appl. Chem.73 (8), (2001); <http://www.iupac.org/publications/pac/2001/7308>]. This was the 14th of the CHEMRAWN series, an acronym for CHEMistry Research Applied to World Needs, that is most aptly served by this important collection of works, dealing with a range of policy, educational, and research and development issues around the title topic.Although the foregoing publication projects are explicitly identified with green chemistry, the theme features repeatedly in numerous papers arising from other IUPAC-sponsored events in recent years, or underpins other disciplinary themes, for example, in the Special Topic collection devoted to Electrochemistry and Interfacial Chemistry for the Environment [Pure Appl. Chem.73 (12), (2001); <http://www.iupac.org/publications/pac/2001/7312>]. This trend is destined to continue, and is perhaps symptomatic of growing social responsibility in current research and development. Furthermore, it demonstrates that IUPAC has an ongoing role to play in fostering activities that fulfil its commitment to shaping and serving the chemical sciences in the interests of societal upliftment and progress.It is thus fitting that the Union should now take the initiative to regularize its role in promoting green chemistry, through a series of biennial conferences. It is equally appropriate to highlight the published record of the 1st International Conference on Green-Sustainable Chemistry as a Special Topic feature of PAC, in recognition of the topicality of this authoritative and representative collection of papers.James R. BullScientific Editor


2013 ◽  
Vol 760-762 ◽  
pp. 1762-1766
Author(s):  
Qin Yi Ma ◽  
Ming Wei Wang ◽  
Mao Jun Zhou ◽  
Hui Hui Wang

The interoperation of various applications will need a representation that goes beyond the traditional geometry-based one, which is inadequate for capturing semantic information. The semantic file is proposed to support a tighter integration of CAD and FEA. The main idea of the approach is presented and key technologies are elaborated, including the creation of the FEA solution template, and the matching algorithm between semantic markup file and FEA template file t. Finally, the feasibility and effectiveness of the approach is empirically validated by a case study.


2011 ◽  
Vol 279 ◽  
pp. 406-411
Author(s):  
Cong Lu ◽  
Jun Zha

This paper proposes a feature recognition approach from a boundary representation solid model with Fuzzy ART neural network. To recognize the feature efficiently, some key technologies in Fuzzy ART neural network are used. The influence of the vigilance parameter on feature recognition is studied, and two learning modes, fast learning and slow learning are adopted and compared in feature recognition. Finally, a case study is given to verify the proposed approach.


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