Enhanced CO2 transport properties of membranes by embedding nano-porous zeolite particles into Matrimid®5218 matrix

RSC Advances ◽  
2015 ◽  
Vol 5 (12) ◽  
pp. 8552-8565 ◽  
Author(s):  
Abtin Ebadi Amooghin ◽  
Mohammadreza Omidkhah ◽  
Ali Kargari
Keyword(s):  
Transport Properties ◽  
Zeolite Y ◽  
Mixed Matrix Membrane ◽  
Nay Zeolite ◽  
Mixed Matrix ◽  
Co2 Transport

A novel mixed matrix membrane (MMM) was fabricated by incorporating micro-sized nano-porous sodium zeolite-Y (NaY zeolite) into Matrimid®5218 matrix.

A novel Co2+ exchanged zeolite Y/cellulose acetate mixed matrix membrane for CO2/N2 separation

2016 ◽  
Vol 60 ◽  
pp. 403-413 ◽  
Author(s):  
Hamidreza Sanaeepur ◽  
Ali Kargari ◽  
Bahram Nasernejad ◽  
Abtin Ebadi Amooghin ◽  
Mohammadreza Omidkhah
Keyword(s):  
Cellulose Acetate ◽  
Zeolite Y ◽  
Mixed Matrix Membrane ◽  
Mixed Matrix

scholarly journals Ag-exchanged NaY zeolite introduced polyvinyl alcohol/polyacrylic acid mixed matrix membrane for pervaporation separation of water/isopropanol mixture

RSC Advances ◽  
2018 ◽  
Vol 8 (37) ◽  
pp. 20669-20678 ◽  
Author(s):  
YongSung Kwon ◽  
Shivshankar Chaudhari ◽  
ChaEun Kim ◽  
DaHae Son ◽  
JiHwan Park ◽  
...  
Keyword(s):  
Ion Exchange ◽  
Polyvinyl Alcohol ◽  
Polyacrylic Acid ◽  
Mixed Matrix Membrane ◽  
Nay Zeolite ◽  
Mixed Matrix ◽  
Aqueous Mixture ◽  
Pervaporation Separation

Ag-exchanged NaY zeolite (Ag-NaZ) particles were prepared by ion exchange and introduced to a polyvinyl alcohol (PVA) membrane cross-linked with polyacrylic acid (PAA) for the pervaporation dehydration of an isopropanol (IPA) aqueous mixture.

scholarly journals ENHANCED BIOGAS (CO2/CH4) SEPARATION PERFORMANCE OF HYBRID MIXED MATRIX MEMBRANE BY INCORPORATING NANOSILICA PARTICLES INTO POLYETHERSULFONE

2017 ◽  
Vol 79 (7-2) ◽  
Author(s):  
Tutuk Djoko Kusworo ◽  
Budiyono Budiyono ◽  
Qudratun Qudratun
Keyword(s):  
Transport Properties ◽  
Gas Transport ◽  
Quantitative Result ◽  
Mixed Matrix Membrane ◽  
Inversion Method ◽  
Separation Performance ◽  
Mixed Matrix ◽  
Gas Transport Properties ◽  
Biogas Purification ◽  
Nanosilica Particles

This paper studies the gas transport properties of PES-nanosilica hybrid mixed matrix membrane for biogas purification. Problem statement: The hybrid mixed matrix membrane was produced to improve the membrane separation performance for biogas purification. The membrane was produced via dry-wet phase inversion method, in which the nanosilica was incorporated into polyethersulfone membranes and the prepared membrane was performed on biogas separation experimental test. Quantitative result: The SEM images analysis confirmed that nanosilica surface had taken important role in gas transport properties. Moreover, the nano-gaps (voids) between polymer and nanosilica particles were disappeared in the polyethersulfone hybrid mixed matrix membrane. The results revealed that the good nano-silica dispersion leads to enhance the properties of gas permeation up to 200% and slighly increased the selectivity about 0.9% of the nanosilica concentration 8 wt-%. Conclusion: It can be concluded that incorporation of nanosilicas particles into the matrix of polyethersulfone polymer significantly enhanced the membrane structure and separation properties.

Aqueous One-Step Modulation for Synthesizing Monodispersed ZIF-8 Nanocrystals for Mixed-Matrix Membrane

2021 ◽  
Vol 13 (9) ◽  
pp. 11296-11305
Author(s):  
Xu Jiang ◽  
Shanshan He ◽  
Gang Han ◽  
Jun Long ◽  
Songwei Li ◽  
...  
Keyword(s):  
Mixed Matrix Membrane ◽  
Mixed Matrix ◽  
One Step

Kinetics studies on free radical scavenging property of ceria in polysulfone–ceria radiation resistant mixed-matrix membrane

2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Amita Bedar ◽  
Beena G. Singh ◽  
Pradip K. Tewari ◽  
Ramesh C. Bindal ◽  
Soumitra Kar
Keyword(s):  
Radical Scavenging ◽  
Radiation Environment ◽  
Mixed Matrix Membranes ◽  
Mixed Matrix Membrane ◽  
Ceria Nanoparticles ◽  
Ros Scavenging ◽  
Mixed Matrix ◽  
Stable States ◽  
Host Matrix ◽  
Γ Radiation

Abstract Cerium oxide (ceria) contains two stable states of cerium ions (Ce3+ and Ce4+). The presence of these two states and the ability to swap from one state to another (Ce3+ ↔ Ce4+) by scavenging the highly reactive oxygen species (ROS) generated from radiolysis of water, ensure the enhanced stability of polysulfone (Psf) membranes in the γ-radiation environment. In this study, the ROS scavenging ability of ceria was studied. Ceria nanoparticles were found to scavenge ROS like hydroxyl radicals and hydrogen peroxide (H2O2). The H2O2 scavenging is due to the peroxidase-like catalytic activity of ceria nanoparticles. The ROS scavenging is responsible for offering protection to the Psf host matrix and in turn the stability to the Psf-ceria mixed-matrix membranes (MMMs) in γ-radiation environment. Thus, presence of ceria nanoparticles provides an opportunity for utilizing Psf-ceria MMMs in ionizing radiation environment with increased life span, without compromise in the performance.

scholarly journals Multiple Amine-Contained POSS-Functionalized Organosilica Membranes for Gas Separation

Membranes ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 194
Author(s):  
Xiuxiu Ren ◽  
Masakoto Kanezashi ◽  
Meng Guo ◽  
Rong Xu ◽  
Jing Zhong ◽  
...  
Keyword(s):  
Gas Separation ◽  
Mixed Matrix Membranes ◽  
Mixed Matrix Membrane ◽  
Separation Performance ◽  
Hybrid Membranes ◽  
Mixed Matrix ◽  
Translation Model ◽  
Good Thermal Stability ◽  
Oligomeric Silsesquioxane

A new polyhedral oligomeric silsesquioxane (POSS) designed with eight –(CH2)3–NH–(CH2)2–NH2 groups (PNEN) at its apexes was used as nanocomposite uploading into 1,2-bis(triethoxysilyl)ethane (BTESE)-derived organosilica to prepare mixed matrix membranes (MMMs) for gas separation. The mixtures of BTESE-PNEN were uniform with particle size of around 31 nm, which is larger than that of pure BTESE sols. The characterization of thermogravimetric (TG) and gas permeance indicates good thermal stability. A similar amine-contained material of 3-aminopropyltriethoxysilane (APTES) was doped into BTESE to prepare hybrid membranes through a copolymerized strategy as comparison. The pore size of the BTESE-PNEN membrane evaluated through a modified gas-translation model was larger than that of the BTESE-APTES hybrid membrane at the same concentration of additions, which resulted in different separation performance. The low values of Ep(CO2)-Ep(N2) and Ep(N2) for the BTESE-PNEN membrane at a low concentration of PNEN were close to those of copolymerized BTESE-APTES-related hybrid membranes, which illustrates a potential CO2 separation performance by using a mixed matrix membrane strategy with multiple amine POSS as particles.

scholarly journals The Effect of the Temperature and Moisture to the Permeation Properties of PEO-Based Membranes for Carbon-Dioxide Separation

Polymers ◽  
2021 ◽  
Vol 13 (13) ◽  
pp. 2053
Author(s):  
Dragutin Nedeljkovic
Keyword(s):  
Carbon Dioxide ◽  
Partial Pressure ◽  
Carbon Dioxide Emission ◽  
Combustion Products ◽  
Mixed Matrix Membranes ◽  
Mixed Matrix Membrane ◽  
Mixed Matrix ◽  
Gas Treatment ◽  
Carbon Dioxide Separation ◽  
Different Temperatures

An increased demand for energy in recent decades has caused an increase in the emissions of combustion products, among which carbon-dioxide is the most harmful. As carbon-dioxide induces negative environmental effects, like global warming and the greenhouse effect, a decrease of the carbon-dioxide emission has emerged as one of the most urgent tasks in engineering. In this work, the possibility for the application of the polymer-based, dense, mixed matrix membranes for flue gas treatment was tested. The task was to test a potential decrease in the permeability and selectivity of a mixed-matrix membrane in the presence of moisture and at elevated temperature. Membranes are based on two different poly(ethylene oxide)-based polymers filled with two different zeolite powders (ITR and IWS). An additive of detergent type was added to improve the contact properties between the zeolite and polymer matrix. The measurements were performed at three different temperatures (30, 60, and 90 °C) under wet conditions, with partial pressure of the water equal to the vapor pressure of the water at the given temperature. The permeability of carbon-dioxide, hydrogen, nitrogen, and oxygen was measured, and the selectivity of the carbon-dioxide versus other gases was determined. Obtained results have shown that an increase of temperature and partial pressure of the vapor slightly increase both the selectivity and permeability of the synthesized membranes. It was also shown that the addition of the zeolite powder increases the permeability of carbon-dioxide while maintaining the selectivity, compared to hydrogen, oxygen, and nitrogen.

Preparation of Cu 3 ( BTC ) 2 / PVC mixed matrix membrane for pomegranate seed storage

2021 ◽  
Author(s):  
Yuanyue Wu ◽  
Zhen Wang ◽  
Liang Zhu ◽  
Kaijun Xiao ◽  
Yurong Yin ◽  
...  
Keyword(s):  
Seed Storage ◽  
Mixed Matrix Membrane ◽  
Mixed Matrix ◽  
Pomegranate Seed

Asymmetric mixed matrix membrane incorporating organically modified clay particle for gas separation

2014 ◽  
Vol 241 ◽  
pp. 495-503 ◽  
Author(s):  
A.K. Zulhairun ◽  
A.F. Ismail ◽  
T. Matsuura ◽  
M.S. Abdullah ◽  
A. Mustafa
Keyword(s):  
Gas Separation ◽  
Clay Particle ◽  
Mixed Matrix Membrane ◽  
Mixed Matrix ◽  
Modified Clay ◽  
Organically Modified

scholarly journals New mixed matrix membrane for the removal of urea from dialysate solution

2021 ◽  
pp. 119408
Author(s):  
Ilaria Geremia ◽  
Jacobus A. W. Jong ◽  
Cornelus F. van Nostrum ◽  
Wim E. Hennink ◽  
Karin G. F. Gerritsen ◽  
...  
Keyword(s):  
Mixed Matrix Membrane ◽  
Mixed Matrix ◽  
Dialysate Solution
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