Synthesis of nanocrystals of Zr-based metal–organic frameworks with csq-net: significant enhancement in the degradation of a nerve agent simulant

2015 ◽  
Vol 51 (54) ◽  
pp. 10925-10928 ◽  
Author(s):  
Peng Li ◽  
Rachel C. Klet ◽  
Su-Young Moon ◽  
Timothy C. Wang ◽  
Pravas Deria ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Nerve Agent ◽  
Significant Enhancement ◽  
Metal Organic

The synthesis of nano-sized particles of NU-1000 (length from 75 nm to 1200 nm) and PCN-222/MOF-545 (length from 350 nm to 900 nm) is reported.

Efficient MOF-based degradation of organophosphorus compounds in non-aqueous environments

2018 ◽  
Vol 6 (7) ◽  
pp. 3038-3045 ◽  
Author(s):  
Dorina F. Sava Gallis ◽  
Jacob A. Harvey ◽  
Charles J. Pearce ◽  
Morgan G. Hall ◽  
Jared B. DeCoste ◽  
...  
Keyword(s):  
Organophosphorus Compounds ◽  
Metal Organic Frameworks ◽  
Nerve Agent ◽  
Aqueous Environments ◽  
Metal Organic

Metal–organic frameworks are shown to degrade organophosphorus compounds in non-aqueous environments, highlighting appropriate simulants for the nerve agent sarin.

Salt nanoconfinement in zirconium-based metal–organic frameworks leads to pore-size and loading-dependent ionic conductivity enhancement

2020 ◽  
Vol 56 (53) ◽  
pp. 7245-7248
Author(s):  
Sorout Shalini ◽  
Thomas P. Vaid ◽  
Adam J. Matzger
Keyword(s):  
Ionic Conductivity ◽  
Pore Size ◽  
Metal Organic Frameworks ◽  
Significant Enhancement ◽  
Conductivity Enhancement ◽  
Metal Organic ◽  
Novel Method ◽  
Ion Conductors

Confinement of the salt [NEt4][TFSI] in metal–organic frameworks leads to a significant enhancement in ionic conductivity, pointing toward a novel method of creating solid ion conductors.

Cerium(IV) vs Zirconium(IV) Based Metal–Organic Frameworks for Detoxification of a Nerve Agent

2017 ◽  
Vol 29 (7) ◽  
pp. 2672-2675 ◽  
Author(s):  
Timur Islamoglu ◽  
Ahmet Atilgan ◽  
Su-Young Moon ◽  
Gregory W. Peterson ◽  
Jared B. DeCoste ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Nerve Agent ◽  
Metal Organic

Significant enhancement of gas uptake capacity and selectivity via the judicious increase of open metal sites and Lewis basic sites within two polyhedron-based metal–organic frameworks

2016 ◽  
Vol 52 (15) ◽  
pp. 3223-3226 ◽  
Author(s):  
Bing Liu ◽  
Shuo Yao ◽  
Chao Shi ◽  
Guanghua Li ◽  
Qisheng Huo ◽  
...  
Keyword(s):  
High Performance ◽  
Metal Organic Frameworks ◽  
High Density ◽  
Significant Enhancement ◽  
Uptake Capacity ◽  
Gas Uptake ◽  
Basic Sites ◽  
Open Metal Sites ◽  
Metal Organic

Two novel PMOFs with a high density of OMSs and LBSs were assembled using the SBB strategy and exhibited a high performance for CO2 capture and separation towards CO2, C2H6 and C3H8 over CH4.

Adsorptive removal of nerve-agent simulant with zirconium-based metal-organic frameworks modified by hydrophobic monocarboxylic acids

2019 ◽  
Vol 285 ◽  
pp. 61-69 ◽  
Author(s):  
Kyung Ho Cho ◽  
Sachin K. Chitale ◽  
Seung-Joo Kim ◽  
Ga-Young Cha ◽  
Do-Young Hong ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Nerve Agent ◽  
Monocarboxylic Acids ◽  
Adsorptive Removal ◽  
Metal Organic

Tuning the Lewis acidity of metal–organic frameworks for enhanced catalysis

2021 ◽  
Author(s):  
Venkata Swaroopa Datta Devulapalli ◽  
Mélissandre Richard ◽  
Tian-Yi Luo ◽  
Mattheus L. De Souza ◽  
Nathaniel L. Rosi ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Nerve Agent ◽  
Metal Salts ◽  
Lewis Acidity ◽  
Kinetics Of Hydrolysis ◽  
Nitrophenyl Phosphate ◽  
Transition Metal Salts ◽  
Metal Organic ◽  
Kinetics Of ◽  
Hydrolysis Of

The kinetics of hydrolysis of dimethyl nitrophenyl phosphate (DMNP), a simulant of the nerve agent Soman, was studied and revealed transition metal salts as catalysts.

Tailoring the Pore Size and Functionality of UiO-Type Metal–Organic Frameworks for Optimal Nerve Agent Destruction

2015 ◽  
Vol 54 (20) ◽  
pp. 9684-9686 ◽  
Author(s):  
Gregory W. Peterson ◽  
Su-Young Moon ◽  
George W. Wagner ◽  
Morgan G. Hall ◽  
Jared B. DeCoste ◽  
...  
Keyword(s):  
Pore Size ◽  
Metal Organic Frameworks ◽  
Nerve Agent ◽  
Metal Organic

scholarly journals Layer-by-Layer Integration of Zirconium Metal–Organic Frameworks onto Activated Carbon Spheres and Fabrics with Model Nerve Agent Detoxification Properties

2021 ◽  
Author(s):  
Rodrigo Gil-San-Millan ◽  
Pedro Delgado ◽  
Elena Lopez-Maya ◽  
Javier D. Martin-Romera ◽  
Elisa Barea ◽  
...  
Keyword(s):  
Activated Carbon ◽  
Metal Organic Frameworks ◽  
Nerve Agent ◽  
Layer By Layer ◽  
Carbon Spheres ◽  
Metal Organic ◽  
Activated Carbon Spheres ◽  
Zirconium Metal

Product Inhibition and the Catalytic Destruction of a Nerve Agent Simulant by Zirconium-Based Metal–Organic Frameworks

2021 ◽  
Author(s):  
Yijun Liao ◽  
Thomas Sheridan ◽  
Jian Liu ◽  
Omar Farha ◽  
Joseph Hupp
Keyword(s):  
Metal Organic Frameworks ◽  
Nerve Agent ◽  
Product Inhibition ◽  
Catalytic Destruction ◽  
Metal Organic
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