Product Inhibition and the Catalytic Destruction of a Nerve Agent Simulant by Zirconium-Based Metal–Organic Frameworks

2021 ◽  
Author(s):  
Yijun Liao ◽  
Thomas Sheridan ◽  
Jian Liu ◽  
Omar Farha ◽  
Joseph Hupp
Keyword(s):  
Metal Organic Frameworks ◽  
Nerve Agent ◽  
Product Inhibition ◽  
Catalytic Destruction ◽  
Metal Organic

Efficient MOF-based degradation of organophosphorus compounds in non-aqueous environments

2018 ◽  
Vol 6 (7) ◽  
pp. 3038-3045 ◽  
Author(s):  
Dorina F. Sava Gallis ◽  
Jacob A. Harvey ◽  
Charles J. Pearce ◽  
Morgan G. Hall ◽  
Jared B. DeCoste ◽  
...  
Keyword(s):  
Organophosphorus Compounds ◽  
Metal Organic Frameworks ◽  
Nerve Agent ◽  
Aqueous Environments ◽  
Metal Organic

Metal–organic frameworks are shown to degrade organophosphorus compounds in non-aqueous environments, highlighting appropriate simulants for the nerve agent sarin.

Synthesis of nanocrystals of Zr-based metal–organic frameworks with csq-net: significant enhancement in the degradation of a nerve agent simulant

2015 ◽  
Vol 51 (54) ◽  
pp. 10925-10928 ◽  
Author(s):  
Peng Li ◽  
Rachel C. Klet ◽  
Su-Young Moon ◽  
Timothy C. Wang ◽  
Pravas Deria ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Nerve Agent ◽  
Significant Enhancement ◽  
Metal Organic

The synthesis of nano-sized particles of NU-1000 (length from 75 nm to 1200 nm) and PCN-222/MOF-545 (length from 350 nm to 900 nm) is reported.

Cerium(IV) vs Zirconium(IV) Based Metal–Organic Frameworks for Detoxification of a Nerve Agent

2017 ◽  
Vol 29 (7) ◽  
pp. 2672-2675 ◽  
Author(s):  
Timur Islamoglu ◽  
Ahmet Atilgan ◽  
Su-Young Moon ◽  
Gregory W. Peterson ◽  
Jared B. DeCoste ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Nerve Agent ◽  
Metal Organic

Adsorptive removal of nerve-agent simulant with zirconium-based metal-organic frameworks modified by hydrophobic monocarboxylic acids

2019 ◽  
Vol 285 ◽  
pp. 61-69 ◽  
Author(s):  
Kyung Ho Cho ◽  
Sachin K. Chitale ◽  
Seung-Joo Kim ◽  
Ga-Young Cha ◽  
Do-Young Hong ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Nerve Agent ◽  
Monocarboxylic Acids ◽  
Adsorptive Removal ◽  
Metal Organic

Tuning the Lewis acidity of metal–organic frameworks for enhanced catalysis

2021 ◽  
Author(s):  
Venkata Swaroopa Datta Devulapalli ◽  
Mélissandre Richard ◽  
Tian-Yi Luo ◽  
Mattheus L. De Souza ◽  
Nathaniel L. Rosi ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Nerve Agent ◽  
Metal Salts ◽  
Lewis Acidity ◽  
Kinetics Of Hydrolysis ◽  
Nitrophenyl Phosphate ◽  
Transition Metal Salts ◽  
Metal Organic ◽  
Kinetics Of ◽  
Hydrolysis Of

The kinetics of hydrolysis of dimethyl nitrophenyl phosphate (DMNP), a simulant of the nerve agent Soman, was studied and revealed transition metal salts as catalysts.

Tailoring the Pore Size and Functionality of UiO-Type Metal–Organic Frameworks for Optimal Nerve Agent Destruction

2015 ◽  
Vol 54 (20) ◽  
pp. 9684-9686 ◽  
Author(s):  
Gregory W. Peterson ◽  
Su-Young Moon ◽  
George W. Wagner ◽  
Morgan G. Hall ◽  
Jared B. DeCoste ◽  
...  
Keyword(s):  
Pore Size ◽  
Metal Organic Frameworks ◽  
Nerve Agent ◽  
Metal Organic

scholarly journals Layer-by-Layer Integration of Zirconium Metal–Organic Frameworks onto Activated Carbon Spheres and Fabrics with Model Nerve Agent Detoxification Properties

2021 ◽  
Author(s):  
Rodrigo Gil-San-Millan ◽  
Pedro Delgado ◽  
Elena Lopez-Maya ◽  
Javier D. Martin-Romera ◽  
Elisa Barea ◽  
...  
Keyword(s):  
Activated Carbon ◽  
Metal Organic Frameworks ◽  
Nerve Agent ◽  
Layer By Layer ◽  
Carbon Spheres ◽  
Metal Organic ◽  
Activated Carbon Spheres ◽  
Zirconium Metal

Metal-Organic Frameworks

2021 ◽  
Author(s):  
Lars Öhrström ◽  
Francoise M. Amombo Noa
Keyword(s):  
Metal Organic Frameworks ◽  
Metal Organic

Substrate templated synthesis of single-phase and uniform Zr-porphyrin-based metal–organic frameworks

2020 ◽  
Vol 7 (1) ◽  
pp. 221-231
Author(s):  
Seong Won Hong ◽  
Ju Won Paik ◽  
Dongju Seo ◽  
Jae-Min Oh ◽  
Young Kyu Jeong ◽  
...  
Keyword(s):  
Chemical Bath Deposition ◽  
Single Phase ◽  
Metal Organic Frameworks ◽  
Templated Synthesis ◽  
Pore Structures ◽  
Phase Pure ◽  
Metal Organic ◽  
Cbd Method

We successfully demonstrate that the chemical bath deposition (CBD) method is a versatile method for synthesizing phase-pure and uniform MOFs by controlling their nucleation stages and pore structures.

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