Boron–nitrogen doped carbon scaffolding: organic chemistry, self-assembly and materials applications of borazine and its derivatives

2015 ◽  
Vol 51 (83) ◽  
pp. 15222-15236 ◽  
Author(s):  
Davide Bonifazi ◽  
Francesco Fasano ◽  
M. Mercedes Lorenzo-Garcia ◽  
Davide Marinelli ◽  
Hamid Oubaha ◽  
...  
Keyword(s):  
Organic Chemistry ◽  
Organic Synthesis ◽  
Self Assembly ◽  
Feature Article ◽  
Nitrogen Doped ◽  
The Past ◽  
Recent Developments ◽  
Nitrogen Doped Carbon ◽  
Boron Nitrogen

In this feature article we describe the past and recent developments in the organic synthesis and functionalisation of borazine, the isostructural inorganic analogue of benzene.

ChemInform Abstract: Boron-Nitrogen Doped Carbon Scaffolding: Organic Chemistry, Self-Assembly and Materials Applications of Borazine and Its Derivatives

ChemInform ◽  
2015 ◽  
Vol 46 (48) ◽  
pp. no-no
Author(s):  
Davide Bonifazi ◽  
Francesco Fasano ◽  
M. Mercedes Lorenzo-Garcia ◽  
Davide Marinelli ◽  
Hamid Oubaha ◽  
...  
Keyword(s):  
Organic Chemistry ◽  
Self Assembly ◽  
Nitrogen Doped ◽  
Nitrogen Doped Carbon ◽  
Boron Nitrogen

scholarly journals Recent Advances in Palladium-Catalyzed Isocyanide Insertions

Molecules ◽  
2020 ◽  
Vol 25 (21) ◽  
pp. 4906
Author(s):  
Jurriën W. Collet ◽  
Thomas R. Roose ◽  
Bram Weijers ◽  
Bert U. W. Maes ◽  
Eelco Ruijter ◽  
...  
Keyword(s):  
Organic Synthesis ◽  
Building Blocks ◽  
Insertion Reactions ◽  
Chemical Reagents ◽  
The Past ◽  
Recent Advances ◽  
Recent Developments ◽  
Palladium Catalyzed ◽  
Made In ◽  
Rapid Incorporation

Isocyanides have long been known as versatile chemical reagents in organic synthesis. Their ambivalent nature also allows them to function as a CO-substitute in palladium-catalyzed cross couplings. Over the past decades, isocyanides have emerged as practical and versatile C1 building blocks, whose inherent N-substitution allows for the rapid incorporation of nitrogeneous fragments in a wide variety of products. Recent developments in palladium catalyzed isocyanide insertion reactions have significantly expanded the scope and applicability of these imidoylative cross-couplings. This review highlights the advances made in this field over the past eight years.

Organic Synthesis

2017 ◽  
Author(s):  
Douglass F. Taber ◽  
Tristan Lambert
Keyword(s):  
Organic Synthesis ◽  
State Of The Art ◽  
Research Area ◽  
Organic Transformations ◽  
The Past ◽  
Catalytic Asymmetric Synthesis ◽  
New Methods ◽  
Recent Developments ◽  
Enantioselective Epoxidation ◽  
To Come

Organic synthesis is a vibrant and rapidly evolving field; chemists can now cyclize alkenes directly onto enones. Like the first five books in this series, Organic Synthesis: State of the Art 2013-2015 will lead readers quickly to the most important recent developments in a research area. This series offers chemists a way to stay abreast of what's new and exciting in organic synthesis. The cumulative reaction/transformation index of 2013-2015 outlines all significant new organic transformations over the past twelve years. Future volumes will continue to come out every two years. The 2013-2015 volume features the best new methods in subspecialties such as C-O, C-N and C-C ring construction, catalytic asymmetric synthesis, selective C-H functionalization, and enantioselective epoxidation. This text consolidates two years of Douglass Taber's popular weekly online column, "Organic Chemistry Highlights" as featured on the organic-chemistry.org website and also features cumulative indices of all six volumes in this series, going back twelve years.

Directed Nanoscale Self-Assembly of Natural Photosystems on Nitrogen-Doped Carbon Nanotubes for Solar-Energy Harvesting

2019 ◽  
Vol 2 (5) ◽  
pp. 2109-2115 ◽  
Author(s):  
Insu Kim ◽  
Nyeongbeen Jo ◽  
Moon Young Yang ◽  
Jeonga Kim ◽  
Hwiseok Jun ◽  
...  
Keyword(s):  
Carbon Nanotubes ◽  
Energy Harvesting ◽  
Solar Energy ◽  
Self Assembly ◽  
Nitrogen Doped ◽  
Solar Energy Harvesting ◽  
Nitrogen Doped Carbon

Self-Assembly Synthesis of Decorated Nitrogen-Doped Carbon Nanotubes with ZnO Nanoparticles: Anchoring Mechanism and the Effects of Sulfur

2014 ◽  
Vol 119 (1) ◽  
pp. 741-747 ◽  
Author(s):  
Eduardo Gracia-Espino ◽  
Florentino López-Urías ◽  
Humberto Terrones ◽  
Mauricio Terrones
Keyword(s):  
Carbon Nanotubes ◽  
Zno Nanoparticles ◽  
Self Assembly ◽  
Nitrogen Doped ◽  
Nitrogen Doped Carbon

Self-assembly of nitrogen-doped carbon dots anchored on bacterial cellulose and their application in iron ion detection

2017 ◽  
Vol 172 ◽  
pp. 93-101 ◽  
Author(s):  
Pengfei Lv ◽  
Yixin Yao ◽  
Dawei Li ◽  
Huimin Zhou ◽  
Muhammad Awais Naeem ◽  
...  
Keyword(s):  
Bacterial Cellulose ◽  
Self Assembly ◽  
Carbon Dots ◽  
Iron Ion ◽  
Ion Detection ◽  
Nitrogen Doped ◽  
Doped Carbon Dots ◽  
Nitrogen Doped Carbon

Bottom-Up Synthesis of Nitrogen-Doped Polycyclic Aromatic Hydrocarbons

Synlett ◽  
2019 ◽  
Vol 31 (03) ◽  
pp. 211-222
Author(s):  
Junzhi Liu ◽  
Xinliang Feng
Keyword(s):  
Polycyclic Aromatic Hydrocarbons ◽  
Organic Synthesis ◽  
Aromatic Hydrocarbons ◽  
Efficient Method ◽  
Dipolar Cycloaddition ◽  
Bottom Up ◽  
Nitrogen Doped ◽  
Synthesis Strategy ◽  
Polycyclic Aromatic ◽  
Boron Nitrogen

Bottom-up organic synthesis serves as an efficient method to provide atomically precise heteroatom-doped polycyclic aromatic hydrocarbons (PAHs) with not only well-defined size and edge structures but also specific concentrations and positions of the heteroatoms. We provide a plenary account of the preparation of nitrogen-doped PAHs (N-PAHs) through 1,3-dipolar cycloaddition between different dipolarophiles, as well as pyrazine-type N-doped diaza-hexa-peri-hexabenzocoronene (diaza-HBC). Additionally, we present the synthesis of a class of helical N-charged PAHs, including one charged aza[5]helicene and two charged aza[4]helicenes. Moreover, the bottom-up organic synthesis strategy is further extended to the construction of novel nitrogen-boron-nitrogen (NBN)-containing PAHs. Finally, we discuss the synthesis of four-coordinate boron chromophores containing 6,12,18-tris(alkyl amine)-5,11,17-triazatrinaphthylene derivative ligands.1 Introduction2 Nitrogen-Doped PAHs Based on Dibenzo-9a-azaphenalene (DBAP)3 Cationic Nitrogen-Doped Helical PAHs4 Nitrogen–Boron–Nitrogen-Doped PAHs5 Conclusion and Outlook

Self-assembly of hierarchical microsized hard carbon-supported Si encapsulated in nitrogen-doped carbon as anode for lithium-ion batteries

2020 ◽  
Vol 55 (26) ◽  
pp. 12373-12384 ◽  
Author(s):  
Yuansheng Liu ◽  
Huitian Liu ◽  
Wenlong Huang ◽  
Yu Yu ◽  
Xiaoqian Dai ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
Self Assembly ◽  
Lithium Ion ◽  
Hard Carbon ◽  
Nitrogen Doped ◽  
Nitrogen Doped Carbon

Triflic Anhydride (Tf2O)-Activated Transformation of Amides, Sulfoxides and Phosphorus Oxides via Nucleophilic Trapping

Synthesis ◽  
2021 ◽  
Author(s):  
Hai Huang ◽  
Jun Yong Kang
Keyword(s):  
Organic Chemistry ◽  
Organic Synthesis ◽  
Phosphorus Oxide ◽  
Synthetic Organic Chemistry ◽  
The Past ◽  
Mechanistic Pathway ◽  
Trifluoromethanesulfonic Anhydride ◽  
Wide Range ◽  
Electrophilic Activation ◽  
Nucleophilic Trapping

Trifluoromethanesulfonic anhydride (Tf2O) has found a wide range of applications in synthetic organic chemistry as a strong electrophilic activator leading to the transient generation of a triflate intermediate. This versatile triflate intermediate undergoes nucleophilic trapping with diverse nucleophiles to yield novel compounds. In this review, we describe the features and applications of triflic anhydride in organic synthesis reported in the past decade, especially in amide, sulfoxide, and phosphorus oxide chemistry through electrophilic activation. A plausible mechanistic pathway of each important reaction is also discussed.

N-Heterocyclic Carbene-Organocatalyzed Arene Formation: Application in Atroposelective Synthesis of Polysubstituted Benzenes

Synlett ◽  
2020 ◽  
Vol 31 (10) ◽  
pp. 925-932 ◽  
Author(s):  
Tingshun Zhu ◽  
Ke Xu ◽  
Ziyuan Wang
Keyword(s):  
Organic Chemistry ◽  
Recent Work ◽  
Organic Synthesis ◽  
Heterocyclic Carbenes ◽  
Powerful Method ◽  
Recent Developments ◽  
History Of ◽  
Cyclic Compounds ◽  
Near Future

In recent decades, organocatalysis by N-heterocyclic carbenes (NHCs) has emerged as a versatile and powerful method in organic synthesis. As a result of the power of NHC organocatalysis to produce cyclic compounds, polysubstituted benzenes, which are among the most important cyclic compounds in organic chemistry, can be synthesized efficiently and selectively. This article briefly summarizes the history of NHC organocatalysis, including recent developments in benzene-formation methods, and highlights our recent work in atroposelective arene formation by carbene-catalyzed formal [4+2] cyclo­additions. We expect that more NHC-catalyzed methods for the synthesis of asymmetric arenes will be developed in the near future, providing shortcuts to syntheses of sophisticated chiral functional molecules with polysubstituted benzene nuclei.

Sign in / Sign up

Export Citation Format

Share Document