X-ray structurally characterized sensors for ratiometric detection of Zn2+ and Al3+ in human breast cancer cells (MCF7): development of a binary logic gate as a molecular switch

2015 ◽  
Vol 44 (26) ◽  
pp. 11797-11804 ◽  
Author(s):  
Abhijit Ghosh ◽  
Debasis Das

A very simple molecule derived from salicylaldehyde and N-phenyl ethylenediamine (L1) functions as a dual-mode ratiometric fluorescence “turn on” sensor for Zn2+ and Al3+ at two different wavelengths.

The Analyst ◽  
2016 ◽  
Vol 141 (20) ◽  
pp. 5886-5892 ◽  
Author(s):  
Jing Wang ◽  
Chenxing Jiang ◽  
Xiaoqi Wang ◽  
Ligeng Wang ◽  
Aimin Chen ◽  
...  

A new CdTe@SiO2@CdSe nanohybrid was demonstrated for the ratiometric fluorescence detection of Cd2+via the turn-on model and “ion-imprinting” technique.


2022 ◽  
Vol 145 ◽  
pp. 112464
Author(s):  
Marina Guimarães Carvalho Machado ◽  
Maria Alice de Oliveira ◽  
Elisa Gomes Lanna ◽  
Raoni Pais Siqueira ◽  
Gwenaelle Pound-Lana ◽  
...  

2016 ◽  
Vol 45 (48) ◽  
pp. 19491-19499 ◽  
Author(s):  
Abhijit Ghosh ◽  
Sangita Adhikari ◽  
Sabyasachi Ta ◽  
Avishek Banik ◽  
Tushar Kanti Dangar ◽  
...  

X-ray structurally characterized probes to track Ag+ in in vitro endophytic bacteria at rice root tissue and human breast cancer cells (MCF7).


2011 ◽  
Vol 89 (8) ◽  
pp. 948-958 ◽  
Author(s):  
David C. Kennedy ◽  
Brian O. Patrick ◽  
Brian R. James

The cationic RuIII complexes, trans-[Ru(ma)2(L)2]CF3SO3, where Hma = maltol = 3-hydroxy-2-methyl-4-pyrone; L = imidazole (Im) (complex 2), 1(N)-methylimidazole (N-MeIm) (3), 2-methylimidazole (2-MeIm) (4), and 4-methylimidazole (4-MeIm) (5), were synthesized via the known L = EtOH (complex 1a), and characterized by elemental analysis, 1H NMR and IR spectroscopies, mass spectrometry, cyclic voltammetry, and (for 3 and 4) by X-ray crystallography. The trans-[Ru(ma)2(H2O)2]CF3SO3 complex (1b) was inadvertently isolated and characterized crystallographically, and the monomaltolato species [Ru(ma)(N-MeIm)4][CF3SO3]2 (6) was also isolated and characterized. In vitro antiproliferatory activity of complexes 2−6 against human breast cancer cells (MDA-MB-435S) was tested using an MTT assay: 4 and 5 exhibit the lowest IC50 values, ~5 and ~15 µmol/L, respectively, whereas cisplatin exhibits an IC50 value of ~35 µmol/L against this cell line.


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