Heptaphosphide cluster anions bearing group 14 element amide functionalities

2016 ◽  
Vol 45 (5) ◽  
pp. 1930-1936 ◽  
Author(s):  
Gabriela Espinoza Quintero ◽  
Isabelle Paterson-Taylor ◽  
Nicholas H. Rees ◽  
Jose M. Goicoechea
Keyword(s):  
Room Temperature ◽  
Cluster Anions ◽  
Group 14 ◽  
Dimeric Product

Reactions of the protonated heptaphosphide dianion, [HP7]2−, with one equivalent of E[N(SiMe3)2]2(E = Ge, Sn, Pb) give rise to novel derivatized cluster anions [P7EN(SiMe3)2]2−(E = Ge (1), Sn (2) and Pb (3)).1readily decomposes in solution at room temperature to afford the dimeric product [(P7Ge)2N(SiMe3)2]3−(4).

Novel and versatile room temperature ionic liquids for energy storage

2019 ◽  
Vol 12 (2) ◽  
pp. 566-571 ◽  
Author(s):  
Mega Kar ◽  
Oscar Tutusaus ◽  
Douglas R. MacFarlane ◽  
Rana Mohtadi
Keyword(s):  
Ionic Liquids ◽  
Energy Storage ◽  
Electrochemical Properties ◽  
Melting Temperature ◽  
Room Temperature ◽  
Storage Systems ◽  
Room Temperature Ionic Liquids ◽  
Cluster Anions ◽  
Boron Cluster ◽  
New Family

The first example of a family of low melting temperature ionic liquids based on the highly stable and inert closo-boron cluster anions is demonstrated. This, combined with excellent physiochemical and electrochemical properties makes this new family of ionic liquids a serious contender towards overcoming key challenges of electrolytes in energy storage systems.

scholarly journals Correction to “Dinitrogen Fixation and Reduction by Ta3N3H0,1– Cluster Anions at Room Temperature: Hydrogen-Assisted Enhancement of Reactivity”

2019 ◽  
Vol 141 (36) ◽  
pp. 14460-14460
Author(s):  
Yue Zhao ◽  
Jia-Tong Cui ◽  
Ming Wang ◽  
David Yubero Valdivielso ◽  
André Fielicke ◽  
...  
Keyword(s):  
Room Temperature ◽  
Dinitrogen Fixation ◽  
Cluster Anions

Consecutive Methane Activation Mediated by Single Metal Boride Cluster Anions NbB4−

2021 ◽  
Author(s):  
Ying Li ◽  
Ming Wang ◽  
Yongqi Ding ◽  
Chongyang Zhao ◽  
Jia-Bi Ma
Keyword(s):  
Mass Spectrometry ◽  
Gas Phase ◽  
Quantum Chemical Calculations ◽  
Quantum Chemical ◽  
Room Temperature ◽  
Methane Activation ◽  
Cluster Ions ◽  
Metal Boride ◽  
Cluster Anions ◽  
Phase Cluster

Cleavage all C−H bonds in two methane molecules by gas-phase cluster ions at room temperature is a challenging task. Herein, mass spectrometry and quantum chemical calculations have been used to...

Dinitrogen Fixation and Reduction by Ta3N3H0,1– Cluster Anions at Room Temperature: Hydrogen-Assisted Enhancement of Reactivity

2019 ◽  
Vol 141 (32) ◽  
pp. 12592-12600 ◽  
Author(s):  
Yue Zhao ◽  
Jia-Tong Cui ◽  
Ming Wang ◽  
David Yubero Valdivielso ◽  
André Fielicke ◽  
...  
Keyword(s):  
Room Temperature ◽  
Dinitrogen Fixation ◽  
Cluster Anions

Photoassisted Selective Steam and Dry Reforming of Methane to Syngas Catalyzed by Rhodium–Vanadium Bimetallic Oxide Cluster Anions at Room Temperature

2020 ◽  
Vol 132 (47) ◽  
pp. 21402-21409
Author(s):  
Yan‐Xia Zhao ◽  
Bin Yang ◽  
Hai‐Fang Li ◽  
Yan Zhang ◽  
Yuan Yang ◽  
...  
Keyword(s):  
Room Temperature ◽  
Dry Reforming ◽  
Dry Reforming Of Methane ◽  
Cluster Anions ◽  
Oxide Cluster

Neutron Powder Diffraction Refinement of the Nuclear and Magnetic Structures of HoNi2B2C at R.T., 10, 5.1 AND 2.2 K

1994 ◽  
Vol 376 ◽  
Author(s):  
Q. Huang ◽  
A. Santoro ◽  
T.E. Grigereit ◽  
J.W. Lynn ◽  
R.J. Cava ◽  
...  
Keyword(s):  
Phase Transitions ◽  
Magnetic Structure ◽  
Nuclear Structure ◽  
Powder Diffraction ◽  
Room Temperature ◽  
Neutron Powder Diffraction ◽  
Group 14 ◽  
Magnetic Structures ◽  
Temperature Lattice ◽  
Helicoidal Structure

ABSTRACTThe nuclear and magnetic structures of HoNi2B2C have been investigated by neutron powder diffraction at room temperature and at 10, 5.1 and 2.2K. The compound crystallizes with the symmetry of space group 14/mmm and has room temperature lattice parameters a=3.5170(1) and c=10.5217(3) Å. No phase transitions of the nuclear structure have been observed in the range of temperatures examined. Magnetic peaks begin to appear at about 8K. The magnetic structure is the superposition of two configurations, one in which ferromagnetic sheets of holmium spins parallel to the a-b plane are coupled antiferromagnetically along the c-axis, and another in which the ferromagnetic planes are rotated away from the antiparallel configuration to give an incommensurate helicoidal structure with a period approximately equal to twelve times the length of the c-axis. The helicoidal structure competes with superconductivity while the antiferromagnetism coexists with it.

Dinitrogen Activation and Functionalization by Heteronuclear Metal Cluster Anions FeV2C2– at Room Temperature

2020 ◽  
Vol 11 (23) ◽  
pp. 9990-9994
Author(s):  
Li-Hui Mou ◽  
Yao Li ◽  
Zi-Yu Li ◽  
Qing-Yu Liu ◽  
Yi Ren ◽  
...  
Keyword(s):  
Room Temperature ◽  
Metal Cluster ◽  
Cluster Anions
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