Chloride-promoted Pd-catalyzed direct C–H arylation for highly efficient phosphine-free synthesis of π-conjugated polymers

2015 ◽  
Vol 6 (28) ◽  
pp. 5036-5039 ◽  
Author(s):  
Shotaro Hayashi ◽  
Toshio Koizumi
Keyword(s):  
Molecular Weight ◽  
Conjugated Polymers ◽  
High Molecular Weight ◽  
Efficient Synthesis ◽  
Highly Efficient

We have successfully demonstrated a chloride-promoted Pd-catalyzed phosphine-free direct C–H arylation for highly efficient synthesis of high molecular weight π-conjugated polymers.

Polymerization of alkyl diazoacetates initiated by the amidinate/Pd system: efficient synthesis of high molecular weight poly(alkoxycarbonylmethylene)s with moderate stereoregularity

2017 ◽  
Vol 8 (27) ◽  
pp. 4030-4037 ◽  
Author(s):  
Hiroaki Shimomoto ◽  
Junya Kawamata ◽  
Hirokazu Murakami ◽  
Kazuki Yamashita ◽  
Tomomichi Itoh ◽  
...  
Keyword(s):  
Molecular Weight ◽  
High Molecular Weight ◽  
Efficient Synthesis ◽  
New System ◽  
High Molecular Weight Poly

The initiating ability of a new system, amidinate/Pd, for the polymerization of diazoacetates is described.

Efficient synthesis of narrowly dispersed amphiphilic double-brush copolymers through the polymerization reaction of macromonomer micelle emulsifiers at the oil–water interface

2016 ◽  
Vol 7 (27) ◽  
pp. 4476-4485 ◽  
Author(s):  
Heng Li ◽  
Han Miao ◽  
Yong Gao ◽  
Huaming Li ◽  
Daoyong Chen
Keyword(s):  
Molecular Weight ◽  
High Molecular Weight ◽  
Radical Polymerization ◽  
Pickering Emulsion ◽  
Polymerization Reaction ◽  
Water Interface ◽  
Efficient Synthesis ◽  
Oil Water

Narrowly dispersed amphiphilic PMA-g-PMMA/PDMA DBCs with high molecular weight were efficiently synthesized by Pickering emulsion template directed radical polymerization of macromonomer micelles.

Highly efficient synthesis of thieno[3,4-b]thiophene derivatives and (opto)electrochemical properties of new low bandgap conjugated polymers

2010 ◽  
Vol 160 (11-12) ◽  
pp. 1368-1371 ◽  
Author(s):  
Wha Sun Lee ◽  
Jin Hong Park ◽  
Myung-Jin Baek ◽  
Youn-Sik Lee ◽  
Soo-Hyoung Lee ◽  
...  
Keyword(s):  
Conjugated Polymers ◽  
Electrochemical Properties ◽  
Efficient Synthesis ◽  
Low Bandgap ◽  
Highly Efficient ◽  
Thiophene Derivatives

A silole copolymer containing a ladder-type heptacylic arene and naphthobisoxadiazole moieties for highly efficient polymer solar cells

2015 ◽  
Vol 8 (2) ◽  
pp. 552-557 ◽  
Author(s):  
Zhiyun Zhang ◽  
Francis Lin ◽  
Hsieh-Chih Chen ◽  
Hung-Chin Wu ◽  
Chin-Lung Chung ◽  
...  
Keyword(s):  
Molecular Weight ◽  
Solar Cells ◽  
High Molecular Weight ◽  
Polymer Solar Cells ◽  
Highly Efficient

We present a silole ladder-type copolymer, PSiNO, with a high molecular weight that affords a remarkable PCE of 8.37%.

Efficient Synthesis of Well-Defined, High Molecular Weight, and Processible Polyanilines under Mild Conditions via Palladium-Catalyzed Amination

2000 ◽  
Vol 122 (31) ◽  
pp. 7606-7607 ◽  
Author(s):  
Xiao-Xiang Zhang ◽  
Joseph P. Sadighi ◽  
Thomas W. Mackewitz ◽  
Stephen L. Buchwald
Keyword(s):  
Molecular Weight ◽  
High Molecular Weight ◽  
Efficient Synthesis ◽  
Mild Conditions ◽  
Palladium Catalyzed

scholarly journals Highly Efficient Synthesis of Type B Gelatin and Low Molecular Weight Chitosan Nanoparticles: Potential Applications as Bioactive Molecule Carriers and Cell-Penetrating Agents

Polymers ◽  
2021 ◽  
Vol 13 (23) ◽  
pp. 4078
Author(s):  
Cristina Gonzalez-Melo ◽  
Andres J. Garcia-Brand ◽  
Valentina Quezada ◽  
Luis H. Reyes ◽  
Carolina Muñoz-Camargo ◽  
...  
Keyword(s):  
Molecular Weight ◽  
Chitosan Nanoparticles ◽  
Synthesis Method ◽  
Low Molecular Weight ◽  
Type B ◽  
Efficient Synthesis ◽  
Gelatin Nanoparticles ◽  
Highly Efficient ◽  
Cell Penetrating ◽  
Bioactive Molecule

Gelatin and chitosan nanoparticles have been widely used in pharmaceutical, biomedical, and nanofood applications due to their high biocompatibility and biodegradability. This study proposed a highly efficient synthesis method for type B gelatin and low-molecular-weight (LMW) chitosan nanoparticles. Gelatin nanoparticles (GNPs) were synthesized by the double desolvation method and the chitosan nanoparticles (CNPs) by the ionic gelation method. The sizes of the obtained CNPs and GNPs (373 ± 71 nm and 244 ± 67 nm, respectively) and zeta potential (+36.60 ± 3.25 mV and −13.42 ± 1.16 mV, respectively) were determined via dynamic light scattering. Morphology and size were verified utilizing SEM and TEM images. Finally, their biocompatibility was tested to assure their potential applicability as bioactive molecule carriers and cell-penetrating agents.

scholarly journals Solvothermal synthesis of high molecular weight dithienogermole containing conjugated polymers

2015 ◽  
Vol 127 (6) ◽  
pp. 1053-1056
Author(s):  
FEI-BAO ZHANG ◽  
SU-FANG LV ◽  
JIANG-XIONG JIANG ◽  
YONG NI
Keyword(s):  
Molecular Weight ◽  
Conjugated Polymers ◽  
High Molecular Weight ◽  
Solvothermal Synthesis

scholarly journals Sweetening Pharmaceutical Radiochemistry by18F-Fluoroglycosylation: A Short Review

2014 ◽  
Vol 2014 ◽  
pp. 1-16 ◽  
Author(s):  
Simone Maschauer ◽  
Olaf Prante
Keyword(s):  
Molecular Weight ◽  
Nuclear Medicine ◽  
High Molecular Weight ◽  
Pet Imaging ◽  
Short Review ◽  
Imaging Studies ◽  
Highly Efficient ◽  
High Molecular Weight Proteins

At the time when the highly efficient [18F]FDG synthesis was discovered by the use of the effective precursor 1,3,4,6-tetra-O-acetyl-2-O-trifluoromethanesulfonyl-β-D-mannopyranose (mannose triflate) for nucleophilic18F-substitution, the field of PET in nuclear medicine experienced a long-term boom. Thirty years later, various strategies for chemoselective18F-labeling of biomolecules have been developed, trying to keep up with the emerging field of radiopharmaceutical sciences. Among the new radiochemical strategies, chemoselective18F-fluoroglycosylation methods aim at the sweetening of pharmaceutical radiochemistry by providing a powerful and highly valuable tool for the design of18F-glycoconjugates with suitablein vivoproperties for PET imaging studies. This paper provides a short review (reflecting the literature not older than 8 years) on the different18F-fluoroglycosylation reactions that have been applied to the development of various18F-glycoconjugate tracers, including not only peptides, but also nonpeptidic tracers and high-molecular-weight proteins.

Fast and efficient synthesis of high molecular weight poly(epsilon-caprolactone) diols by microwave-assisted polymer synthesis

2011 ◽  
Vol 121 (3) ◽  
pp. 1321-1329 ◽  
Author(s):  
Gustavo A. Gotelli ◽  
Pablo Bonelli ◽  
Gustavo A. Abraham ◽  
Alejandro Sosnik
Keyword(s):  
Molecular Weight ◽  
High Molecular Weight ◽  
Polymer Synthesis ◽  
Efficient Synthesis ◽  
Microwave Assisted ◽  
High Molecular Weight Poly
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