Polymerization of alkyl diazoacetates initiated by the amidinate/Pd system: efficient synthesis of high molecular weight poly(alkoxycarbonylmethylene)s with moderate stereoregularity

2017 ◽  
Vol 8 (27) ◽  
pp. 4030-4037 ◽  
Author(s):  
Hiroaki Shimomoto ◽  
Junya Kawamata ◽  
Hirokazu Murakami ◽  
Kazuki Yamashita ◽  
Tomomichi Itoh ◽  
...  
Keyword(s):  
Molecular Weight ◽  
High Molecular Weight ◽  
Efficient Synthesis ◽  
New System ◽  
High Molecular Weight Poly

The initiating ability of a new system, amidinate/Pd, for the polymerization of diazoacetates is described.

Fast and efficient synthesis of high molecular weight poly(epsilon-caprolactone) diols by microwave-assisted polymer synthesis

2011 ◽  
Vol 121 (3) ◽  
pp. 1321-1329 ◽  
Author(s):  
Gustavo A. Gotelli ◽  
Pablo Bonelli ◽  
Gustavo A. Abraham ◽  
Alejandro Sosnik
Keyword(s):  
Molecular Weight ◽  
High Molecular Weight ◽  
Polymer Synthesis ◽  
Efficient Synthesis ◽  
Microwave Assisted ◽  
High Molecular Weight Poly

Linear and high-molecular-weight poly-porphyrins for efficient photodynamic therapy

2021 ◽  
Author(s):  
Nan Zheng ◽  
Xiahui Li ◽  
Shangwei Huangfu ◽  
Kangkai Xia ◽  
Ruofei Yue ◽  
...  
Keyword(s):  
Molecular Weight ◽  
Photodynamic Therapy ◽  
Quantum Yield ◽  
Singlet Oxygen ◽  
High Molecular Weight ◽  
Linear Poly ◽  
High Molecular Weight Poly

A linear poly-porphyrin with high Mw and conjugated by PEG and acetazolamide was developed with enhanced singlet oxygen quantum yield, improved photo-toxicity and excellent in vivo photodynamic therapy.

Chemistry of Phenoxo Complexes. II. Synthesis of High Molecular Weight Poly(2,6-dichlorophenylene oxides)

1973 ◽  
Vol 6 (4) ◽  
pp. 498-502 ◽  
Author(s):  
B. G. Carr ◽  
J. F. Harrod ◽  
P. van Gheluwe
Keyword(s):  
Molecular Weight ◽  
High Molecular Weight ◽  
High Molecular Weight Poly

Capillary electrophoretic separation of high-molecular-weight poly(ethylene glycol)-modified proteins

2008 ◽  
Vol 373 (2) ◽  
pp. 207-212 ◽  
Author(s):  
Dong Hee Na ◽  
Eun Ji Park ◽  
Yeong Woo Jo ◽  
Kang Choon Lee
Keyword(s):  
Molecular Weight ◽  
Ethylene Glycol ◽  
High Molecular Weight ◽  
Electrophoretic Separation ◽  
Poly Ethylene Glycol ◽  
Capillary Electrophoretic ◽  
Modified Proteins ◽  
Poly Ethylene ◽  
High Molecular Weight Poly

Junction Size and Mechanical Properties of Atactic and Syndiotactic High-Molecular Weight Poly(vinyl alcohol) Hydrogels

2012 ◽  
Vol 69 (11) ◽  
pp. 623-630 ◽  
Author(s):  
Risei WADA ◽  
Hidenobu SHIMIZU ◽  
Masaru OKABE
Keyword(s):  
Mechanical Properties ◽  
Molecular Weight ◽  
High Molecular Weight ◽  
Vinyl Alcohol ◽  
Poly Vinyl Alcohol ◽  
High Molecular Weight Poly

Stereo-chemical contributions to the glass transition and liquid–liquid phase separation in high molecular weight poly(N-vinyl carbazole)

RSC Advances ◽  
2016 ◽  
Vol 6 (35) ◽  
pp. 29326-29333 ◽  
Author(s):  
Abdul G. Al Lafi ◽  
James N. Hay
Keyword(s):  
Molecular Weight ◽  
Glass Transition ◽  
Phase Separation ◽  
Liquid Phase ◽  
High Molecular Weight ◽  
Structural Properties ◽  
Thermal History ◽  
Liquid Phase Separation ◽  
High Molecular Weight Poly ◽  
Liquid Liquid Phase Separation

Thermal history and purification effects on the structural properties of PVK were investigated. Liquid–liquid phase separation is suggested to occur by separation of isotactic rich segments from a matrix which is predominantly atactic.

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