An azo-linked porous triptycene network as an absorbent for CO2 and iodine uptake

2016 ◽  
Vol 7 (3) ◽  
pp. 643-647 ◽  
Author(s):  
Qin-Qin Dang ◽  
Xiao-Min Wang ◽  
Yu-Fen Zhan ◽  
Xian-Ming Zhang
Keyword(s):  
Carbon Dioxide ◽  
Liquid Phase ◽  
Iodine Uptake ◽  
Carbon Dioxide Uptake ◽  
Porous Organic Framework ◽  
Organic Framework

An azo-linked porous organic framework (Azo-Trip) in which triptycene is incorporated as linkage, has been constructed via a facile Zn-induced reductive homocoulping reaction. The Azo-Trip exhibits selective carbon dioxide uptake and excellent iodine uptake in vapour and liquid phase.

Dynamic Zn-based metal–organic framework: stepwise adsorption, hysteretic desorption and selective carbon dioxide uptake

2013 ◽  
Vol 1 (22) ◽  
pp. 6535 ◽  
Author(s):  
Bo Liu ◽  
Yuanpu Li ◽  
Lei Hou ◽  
Guoping Yang ◽  
Yao-Yu Wang ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Metal Organic Framework ◽  
Carbon Dioxide Uptake ◽  
Metal Organic ◽  
Organic Framework

Highly efficient carbon dioxide capture with a porous organic polymer impregnated with polyethylenimine

2014 ◽  
Vol 2 (33) ◽  
pp. 13245-13249 ◽  
Author(s):  
Siyoung Sung ◽  
Myunghyun Paik Suh
Keyword(s):  
Carbon Dioxide ◽  
Carbon Dioxide Capture ◽  
Organic Polymer ◽  
Porous Organic Polymer ◽  
Highly Efficient ◽  
Porous Organic Framework ◽  
Organic Framework

A porous organic framework (PAF-5) impregnated with a polyethylenimine (PEI) displays excellent properties for post-combustion CO2 capture.

scholarly journals Tuneable CO2 binding enthalpies by redox modulation of an electroactive MOF-74 framework

2021 ◽  
Vol 2 (6) ◽  
pp. 2112-2119
Author(s):  
Patrick W. Doheny ◽  
Ravichandar Babarao ◽  
Cameron J. Kepert ◽  
Deanna M. D’Alessandro
Keyword(s):  
Carbon Dioxide ◽  
Chemical Reduction ◽  
Metal Organic Framework ◽  
Heat Of Adsorption ◽  
Redox Modulation ◽  
Carbon Dioxide Uptake ◽  
Metal Organic ◽  
Organic Framework

Chemical reduction of an electroactive metal–organic framework based on napthalenediimide modulates carbon dioxide uptake and heat of adsorption.

Highly selective carbon dioxide uptake by a microporous kgm-pillared metal–organic framework with acylamide groups

CrystEngComm ◽  
2014 ◽  
Vol 16 (25) ◽  
pp. 5520 ◽  
Author(s):  
Liting Du ◽  
Shilong Yang ◽  
Li Xu ◽  
Huihua Min ◽  
Baishu Zheng
Keyword(s):  
Carbon Dioxide ◽  
Metal Organic Framework ◽  
Carbon Dioxide Uptake ◽  
Metal Organic ◽  
Organic Framework

Application of Disk Aerators to Recarbonation of Alkaline Wastewater from Wet Gasification of Carbide

1991 ◽  
Vol 24 (7) ◽  
pp. 277-284 ◽  
Author(s):  
E. Gomólka ◽  
B. Gomólka
Keyword(s):  
Carbon Dioxide ◽  
Liquid Phase ◽  
Gas Phase ◽  
Flue Gas ◽  
Carbonic Acid ◽  
Low Cost ◽  
Flue Gases ◽  
Carbon Dioxide Content ◽  
Patent Claim ◽  
Phase Dispersion

Whenever possible, neutralization of alkaline wastewater should involve low-cost acid. It is conventional to make use of carbonic acid produced via the reaction of carbon dioxide (contained in flue gases) with water according to the following equation: Carbon dioxide content in the flue gas stream varies from 10% to 15%. The flue gas stream may either be passed to the wastewater contained in the recarbonizers, or. enter the scrubbers (which are continually sprayed with wastewater) from the bottom in oountercurrent. The reactors, in which recarbonation occurs, have the ability to expand the contact surface between gaseous and liquid phase. This can be achieved by gas phase dispersion in the liquid phase (bubbling), by liquid phase dispersion in the gas phase (spraying), or by bubbling and spraying, and mixing. These concurrent operations are carried out during motion of the disk aerator (which is a patent claim). The authors describe the functioning of the disk aerator, the composition of the wastewater produced during wet gasification of carbide, the chemistry of recarbonation and decarbonation, and the concept of applying the disk aerator so as to make the wastewater fit for reuse (after suitable neutralization) as feeding water in acetylene generators.

Construction of a Stable Crystalline Polyimide Porous Organic Framework for C 2 H 2 /C 2 H 4 and CO 2 /N 2 Separation

2019 ◽  
Vol 25 (38) ◽  
pp. 9045-9051 ◽  
Author(s):  
Lingchang Jiang ◽  
Pengyuan Wang ◽  
Meiping Li ◽  
Panpan Zhang ◽  
Jialu Li ◽  
...  
Keyword(s):  
Porous Organic Framework ◽  
Organic Framework

scholarly journals Recyclable Catalysts for Alkyne Functionalization

Molecules ◽  
2021 ◽  
Vol 26 (12) ◽  
pp. 3525
Author(s):  
Leslie Trigoura ◽  
Yalan Xing ◽  
Bhanu P. S. Chauhan
Keyword(s):  
Supported Catalysts ◽  
Metal Organic Framework ◽  
Metal Nanoparticle ◽  
Homogeneous Catalyst ◽  
Catalyst Recycling ◽  
Catalytic Systems ◽  
Recyclable Catalysts ◽  
Metal Organic ◽  
Porous Organic Framework ◽  
Organic Framework

In this review, we present an assessment of recent advances in alkyne functionalization reactions, classified according to different classes of recyclable catalysts. In this work, we have incorporated and reviewed the activity and selectivity of recyclable catalytic systems such as polysiloxane-encapsulated novel metal nanoparticle-based catalysts, silica–copper-supported nanocatalysts, graphitic carbon-supported nanocatalysts, metal organic framework (MOF) catalysts, porous organic framework (POP) catalysts, bio-material-supported catalysts, and metal/solvent free recyclable catalysts. In addition, several alkyne functionalization reactions have been elucidated to demonstrate the success and efficiency of recyclable catalysts. In addition, this review also provides the fundamental knowledge required for utilization of green catalysts, which can combine the advantageous features of both homogeneous (catalyst modulation) and heterogeneous (catalyst recycling) catalysis.

scholarly journals Selective capture of carbon dioxide from hydrocarbons using a metal-organic framework

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Omid T. Qazvini ◽  
Ravichandar Babarao ◽  
Shane G. Telfer
Keyword(s):  
Carbon Dioxide ◽  
Density Functional ◽  
Metal Organic Framework ◽  
Density Functional Theory Calculations ◽  
Time Lags ◽  
X Ray Crystallography ◽  
Metal Organic ◽  
Adsorption Of Co ◽  
Short Time ◽  
Organic Framework

AbstractEfficient and sustainable methods for carbon dioxide capture are highly sought after. Mature technologies involve chemical reactions that absorb CO2, but they have many drawbacks. Energy-efficient alternatives may be realised by porous physisorbents with void spaces that are complementary in size and electrostatic potential to molecular CO2. Here, we present a robust, recyclable and inexpensive adsorbent termed MUF-16. This metal-organic framework captures CO2 with a high affinity in its one-dimensional channels, as determined by adsorption isotherms, X-ray crystallography and density-functional theory calculations. Its low affinity for other competing gases delivers high selectivity for the adsorption of CO2 over methane, acetylene, ethylene, ethane, propylene and propane. For equimolar mixtures of CO2/CH4 and CO2/C2H2, the selectivity is 6690 and 510, respectively. Breakthrough gas separations under dynamic conditions benefit from short time lags in the elution of the weakly-adsorbed component to deliver high-purity hydrocarbon products, including pure methane and acetylene.

Sign in / Sign up

Export Citation Format

Share Document