Axial ligand modified high valent tin(iv) porphyrins: synthesis, structure, photophysical studies and photodynamic antimicrobial activities on Candida albicans

RSC Advances ◽  
2015 ◽  
Vol 5 (75) ◽  
pp. 61103-61117 ◽  
Author(s):  
Rahul Soman ◽  
Darpan Raghav ◽  
Subramaniam Sujatha ◽  
Krishnan Rathinasamy ◽  
Chellaiah Arunkumar
Keyword(s):  
Candida Albicans ◽  
Dft Calculations ◽  
Single Crystal ◽  
Fluorescence Imaging ◽  
Structure Analysis ◽  
Antimicrobial Activities ◽  
Axial Ligand ◽  
X Ray ◽  
Photophysical Studies ◽  
High Valent

Photophysical studies, fluorescence imaging, single crystal X-ray structure analysis and DFT calculations revealed that compounds2and3show enhanced phototoxicity towardsCandida albicanscompared to compound1.

Synthesis, spectroscopic and single crystal X-ray studies on three new mononuclear Ni(II) pincer type complexes: DFT calculations and their antimicrobial activities

2017 ◽  
Vol 1141 ◽  
pp. 428-435 ◽  
Author(s):  
Samaresh Layek ◽  
Bhumika Agrahari ◽  
Abhrajyoti Tarafdar ◽  
Chanda Kumari ◽  
Anuradha ◽  
...  
Keyword(s):  
Dft Calculations ◽  
Single Crystal ◽  
Antimicrobial Activities ◽  
X Ray

Antimicrobial activities of self-assembled copper(ii), nickel(ii), and cobalt(iii) complexes combined with crystallographic, spectroscopic, DFT calculations and Hirshfeld surfaces analyses

2019 ◽  
Vol 43 (31) ◽  
pp. 12417-12430 ◽  
Author(s):  
Lan-Qin Chai ◽  
Ling Zhou ◽  
Hong-Bin Zhang ◽  
Kuan-Hao Mao ◽  
Hong-Song Zhang
Keyword(s):  
Dft Calculations ◽  
Single Crystal ◽  
Antimicrobial Activities ◽  
Hirshfeld Surface ◽  
Metal Salts ◽  
Spectroscopic Methods ◽  
Dft Studies ◽  
X Ray ◽  
X Ray Crystallography ◽  
Hirshfeld Surfaces

Three 2-D and 3-D Cu(ii), Ni(ii), and Co(iii) complexes were obtained by reaction of HL1 with different metal salts. The complexes were characterized by single-crystal X-ray crystallography and spectroscopic methods, as well as Hirshfeld surface analysis and DFT studies.

How the Magnetic Field Impacts the Chiroptical Activities of Helical Copper Enantiomers

2021 ◽  
Author(s):  
jialu wu ◽  
Bo Li ◽  
Hong Wang ◽  
Ying Zhen Lai ◽  
Yue Ye ◽  
...  
Keyword(s):  
Magnetic Field ◽  
Solid State ◽  
Thermogravimetric Analysis ◽  
Single Crystal ◽  
Structure Analysis ◽  
Chiral Ligands ◽  
X Ray ◽  
The Magnetic Field

A pair of enantiomers {[Cu(L-pro)(L-tyr)]·2H2O}n (L-1) and {[Cu(D-pro)(D-tyr)]·2H2O}n (D-1) based on the chiral ligands L/D-proline and L/D-tyrosine were synthesized and investigated by single-crystal X-ray structure analysis, IR, thermogravimetric analysis, solid-state...

scholarly journals Arene Ruthenium Metalla-Assemblies with Anthracene Moieties for PDT Applications

Inorganics ◽  
2018 ◽  
Vol 6 (3) ◽  
pp. 97 ◽  
Author(s):  
Marie Gaschard ◽  
Farzaneh Nehzat ◽  
Thomas Cheminel ◽  
Bruno Therrien
Keyword(s):  
Molecular Structure ◽  
Single Crystal ◽  
General Formula ◽  
Structure Analysis ◽  
White Light ◽  
Light Irradiation ◽  
Synthesis And Characterization ◽  
X Ray

The synthesis and characterization of three metalla-rectangles of the general formula [Ru4(η6-p-cymene)4(μ4-clip)2(μ2-Lanthr)2][CF3SO3]4 (Lanthr: 9,10-bis(3,3’-ethynylpyridyl) anthracene; clip = oxa: oxalato; dobq: 2,5-dioxido-1,4-benzoquinonato; donq: 5,8-dioxido-1,4-naphthoquinonato) are presented. The molecular structure of the metalla-rectangle [Ru4(η6-p-cymene)4(μ4-oxa)2(μ2-Lanthr)2]4+ has been confirmed by the single-crystal X-ray structure analysis of [Ru4(η6-p-cymene)4(μ4-oxa)2(μ2-Lanthr)2][CF3SO3]4 · 4 acetone (A2 · 4 acetone), thus showing the anthracene moieties to be available for reaction with oxygen. While the formation of the endoperoxide form of Lanthr was observed in solution upon white light irradiation, the same reaction does not occur when Lanthr is part of the metalla-assemblies.

scholarly journals Syntheses, Characterization, Crystal Structures and Antimicrobial Activity of Schiff Base Copper(II) Complexes Derived from 2-Bromo-6-((2-(isopropylamino) ethylimino)methyl)phenol

2021 ◽  
Vol 68 (4) ◽  
pp. 1008-1015
Author(s):  
Yong Yuan ◽  
Xi-Kun Lu ◽  
Gao-Qi Zhou ◽  
Xiao-Yang Qiu
Keyword(s):  
Antimicrobial Activity ◽  
Schiff Base ◽  
Single Crystal ◽  
Elemental Analysis ◽  
Structure Determination ◽  
Antimicrobial Activities ◽  
X Ray ◽  
Zwitterionic Form ◽  
Square Planar ◽  
Vis Spectroscopy

Three new copper(II) complexes, [Cu(LH)2]Br2 (1), [Cu(LH)2]NCS2 (2), and [Cu(LH)2](NO3)2 (3), where LH is the zwitterionic form of 2-bromo-6-((2-(isopropylamino)ethylimino)methyl)phenol (HL), were synthesized and characterized by elemental analysis, IR and UV-vis spectroscopy. The structures of the complexes were further confirmed by single crystal X-ray structure determination. All compounds are mononuclear copper(II) complexes. The Cu atoms in the complexes are coordinated by two imino N and two phenolate O atoms from two LH ligands, forming square planar coordination. The compounds were assayed for their antimicrobial activities.

Sign in / Sign up

Export Citation Format

Share Document