scholarly journals Separating bulk from grain boundary Li ion conductivity in the sol–gel prepared solid electrolyte Li1.5Al0.5Ti1.5(PO4)3

2015 ◽  
Vol 3 (42) ◽  
pp. 21343-21350 ◽  
Author(s):  
Stefan Breuer ◽  
Denise Prutsch ◽  
Qianli Ma ◽  
Viktor Epp ◽  
Florian Preishuber-Pflügl ◽  
...  
Keyword(s):  
Impedance Spectroscopy ◽  
Grain Boundary ◽  
Ion Transport ◽  
Solid Electrolyte ◽  
Transport Properties ◽  
Low Temperatures ◽  
Sol Gel ◽  
Ion Conductivity ◽  
Li Ion ◽  
Ceramic Electrolytes

Impedance spectroscopy measurements down to very low temperatures allowed for resolving bulk ion transport properties in highly conducting ceramic electrolytes.

scholarly journals Garnet to hydrogarnet: effect of post synthesis treatment on cation substituted LLZO solid electrolyte and its effect on Li ion conductivity

RSC Advances ◽  
2021 ◽  
Vol 11 (48) ◽  
pp. 30283-30294
Author(s):  
Charlotte Fritsch ◽  
Tatiana Zinkevich ◽  
Sylvio Indris ◽  
Martin Etter ◽  
Volodymyr Baran ◽  
...  
Keyword(s):  
Impedance Spectroscopy ◽  
Solid Electrolyte ◽  
Strong Dependence ◽  
Ion Conductivity ◽  
Sample Treatment ◽  
Li Ion ◽  
Post Synthesis

Investigation of commercial Li7La3Zr2O12 (LLZO) with various substituents. Although impedance spectroscopy suggests something else: the ion conductivity does not show a strong dependence on the substituting cation, but rather on the sample treatment.

Grain Boundary Contributions to Li-Ion Transport in the Solid Electrolyte Li7La3Zr2O12 (LLZO)

2017 ◽  
Vol 29 (22) ◽  
pp. 9639-9647 ◽  
Author(s):  
Seungho Yu ◽  
Donald J. Siegel
Keyword(s):  
Grain Boundary ◽  
Ion Transport ◽  
Solid Electrolyte ◽  
Li Ion

scholarly journals Upscaling of LATP synthesis: Stoichiometric screening of phase purity and microstructure to ionic conductivity maps

Ionics ◽  
2021 ◽  
Vol 27 (5) ◽  
pp. 2017-2025
Author(s):  
Nikolas Schiffmann ◽  
Ethel C. Bucharsky ◽  
Karl G. Schell ◽  
Charlotte A. Fritsch ◽  
Michael Knapp ◽  
...  
Keyword(s):  
Ionic Conductivity ◽  
Sol Gel ◽  
Ion Conductivity ◽  
Process Window ◽  
Lithium Aluminum ◽  
Potential Candidate ◽  
Secondary Phases ◽  
X Ray Diffraction ◽  
Battery Cell ◽  
Li Ion

AbstractLithium aluminum titanium phosphate (LATP) is known to have a high Li-ion conductivity and is therefore a potential candidate as a solid electrolyte. Via sol-gel route, it is already possible to prepare the material at laboratory scale in high purity and with a maximum Li-ion conductivity in the order of 1·10−3 s/cm at room temperature. However, for potential use in a commercial, battery-cell upscaling of the synthesis is required. As a first step towards this goal, we investigated whether the sol-gel route is tolerant against possible deviations in the concentration of the precursors. In order to establish a possible process window for sintering, the temperature interval from 800 °C to 1100 °C and holding times of 10 to 480 min were evaluated. The resulting phase compositions and crystal structures were examined by X-ray diffraction. Impedance spectroscopy was performed to determine the electrical properties. The microstructure of sintered pellets was analyzed by scanning electron microscopy and correlated to both density and ionic conductivity. It is shown that the initial concentration of the precursors strongly influences the formation of secondary phases like AlPO4 and LiTiOPO4, which in turn have an influence on ionic conductivity, densification behavior, and microstructure evolution.

Lithium ion conductivity of oriented Li0.33La0.56TiO3 solid electrolyte films prepared by a sol–gel process

2016 ◽  
Vol 284 ◽  
pp. 1-6 ◽  
Author(s):  
Takashi Teranishi ◽  
Yuki Ishii ◽  
Hidetaka Hayashi ◽  
Akira Kishimoto
Keyword(s):  
Solid Electrolyte ◽  
Sol Gel ◽  
Lithium Ion ◽  
Ion Conductivity ◽  
Sol Gel Process ◽  
Lithium Ion Conductivity

The role of Li site occupancy on the Li-ion conductivity of Ta-doped Li6.75La3Zr1.75Ta0.25O12 solid electrolyte materials with high Li concentrations

2021 ◽  
Vol 369 ◽  
pp. 115713
Author(s):  
Xingxing Zhang ◽  
Cheng Li ◽  
Weili Liu ◽  
Tae-Sik Oh ◽  
Jeffrey W. Fergus
Keyword(s):  
Solid Electrolyte ◽  
Site Occupancy ◽  
Ion Conductivity ◽  
Li Ion

scholarly journals Lithium-ion conductivity in Li6Y(BO3)3: a thermally and electrochemically robust solid electrolyte

2016 ◽  
Vol 4 (18) ◽  
pp. 6972-6979 ◽  
Author(s):  
Beatriz Lopez-Bermudez ◽  
Wolfgang G. Zeier ◽  
Shiliang Zhou ◽  
Anna J. Lehner ◽  
Jerry Hu ◽  
...  
Keyword(s):  
Energy Storage ◽  
Solid Electrolyte ◽  
Solid Electrolytes ◽  
Lithium Ion ◽  
Ion Conductivity ◽  
Ion Diffusion ◽  
New Energy ◽  
Li Ion ◽  
Lithium Ion Conductivity ◽  
Storage Technologies

The development of new frameworks for solid electrolytes exhibiting fast Li-ion diffusion is critical for enabling new energy storage technologies.

Highly Conjugated Three-Dimensional Covalent Organic Frame- works with Enhanced Li-ion Conductivity as Solid-State Electrolytes for High-Performance Lithium Metal Batteries

2022 ◽  
Author(s):  
Shi Wang ◽  
Xiang-Chun Li ◽  
Tao Cheng ◽  
Yuan-Yuan Liu ◽  
Qiange Li ◽  
...  
Keyword(s):  
Solid State ◽  
Ion Transport ◽  
High Performance ◽  
Three Dimensional ◽  
Ion Conductivity ◽  
Covalent Organic Frameworks ◽  
Lithium Metal ◽  
Lithium Metal Batteries ◽  
Li Ion ◽  
Solid State Electrolytes

Covalent organic frameworks (COFs) with well-tailored channels have the potential to efficiently transport ions yet remain to be explored. The ion transport capability is generally limited due to the lack...

scholarly journals Local Li-ion conductivity changes within Al stabilized Li7La3Zr2O12 and their relationship to three-dimensional variations of the bulk composition

2019 ◽  
Vol 7 (12) ◽  
pp. 6818-6831 ◽  
Author(s):  
Stefan Smetaczek ◽  
Andreas Wachter-Welzl ◽  
Reinhard Wagner ◽  
Daniel Rettenwander ◽  
Georg Amthauer ◽  
...  
Keyword(s):  
Impedance Spectroscopy ◽  
Chemical Analysis ◽  
Bulk Composition ◽  
Three Dimensional ◽  
Ion Conductivity ◽  
Spatially Resolved ◽  
Li Ion

Investigating conductivity variations in Al stabilized LLZO by combining microelectrode impedance spectroscopy with spatially resolved chemical analysis.

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