Modification of a disposable pencil graphite electrode with multiwalled carbon nanotubes: application to electrochemical determination of diclofenac sodium in some pharmaceutical and biological samples

2016 ◽  
Vol 8 (19) ◽  
pp. 3966-3974 ◽  
Author(s):  
Golnaz Parvizi Fard ◽  
Esmaeel Alipour ◽  
Reza Emam Ali Sabzi

A MWCNTs/PGE was developed as an electrochemical sensor and used for the determination of diclofenac sodium (DIC).

2021 ◽  
Author(s):  
Younes Bahadori ◽  
Habib Razmi

A novel electrochemical sensor based on the Cu-Al layered double hydroxide (Cu-Al LDH) by chicken feet yellow membrane (CFYM) on graphenized pencil graphite electrode (GPGE) was designed. The present modified...


Materials ◽  
2020 ◽  
Vol 13 (3) ◽  
pp. 781 ◽  
Author(s):  
Agnieszka Sasal ◽  
Katarzyna Tyszczuk-Rotko ◽  
Magdalena Wójciak ◽  
Ireneusz Sowa

A simple, sensitive and time-saving differential-pulse adsorptive stripping voltammetric (DPAdSV) procedure using a screen-printed carbon electrode modified with carboxyl functionalized multiwalled carbon nanotubes (SPCE/MWCNTs-COOH) for the determination of diclofenac (DF) is presented. The sensor was characterized using optical profilometry, SEM, and cyclic voltammetry (CV). The use of carboxyl functionalized MWCNTs as a SPCE modifier improved the electron transfer process and the active surface area of sensor. Under optimum conditions, very sensitive results were obtained with a linear range of 0.1–10.0 nmol L−1 and a limit of detection value of 0.028 nmol L−1. The SPCE/MWCNTs-COOH also exhibited satisfactory repeatability, reproducibility, and selectivity towards potential interferences. Moreover, for the first time, the electrochemical sensor allows determining the real concentrations of DF in environmental water samples without sample pretreatment steps.


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