Single lithium-ion conducting solid polymer electrolytes: advances and perspectives

2017 ◽  
Vol 46 (3) ◽  
pp. 797-815 ◽  
Author(s):  
Heng Zhang ◽  
Chunmei Li ◽  
Michal Piszcz ◽  
Estibaliz Coya ◽  
Teofilo Rojo ◽  
...  
Keyword(s):  
Growth Rate ◽  
Lithium Batteries ◽  
Polymer Electrolytes ◽  
Detrimental Effect ◽  
Lithium Ion ◽  
Transference Number ◽  
Dendrite Growth ◽  
Solid Polymer Electrolytes ◽  
Solid Polymer ◽  
Ion Conducting

Single lithium-ion conducting solid polymer electrolytes (SLIC-SPEs), with a high lithium-ion transference number, the absence of the detrimental effect of anion polarization, and low dendrite growth rate, could be an excellent choice of safe electrolyte materials for lithium batteries in the future.

Supramolecular assembly-mediated lithium ion transport in nanostructured solid electrolytes

RSC Advances ◽  
2016 ◽  
Vol 6 (44) ◽  
pp. 38223-38227 ◽  
Author(s):  
Chih-Chia Cheng ◽  
Duu-Jong Lee
Keyword(s):  
Ion Transport ◽  
Lithium Ion Batteries ◽  
Polymer Electrolytes ◽  
Solid Electrolytes ◽  
High Performance ◽  
Supramolecular Assembly ◽  
Lithium Ion ◽  
Solid Polymer Electrolytes ◽  
Solid Polymer ◽  
Ion Conducting

Supramolecular solid polymer electrolytes provide mechanical integrity and well-defined ion-conducting paths for rapid ion transport that can be applied in high-performance lithium-ion batteries.

scholarly journals Solid Polymer Electrolytes Derived from Oligomeric Poly(ethylene oxide) Chain-Grafted Crosslinked Polystyrene Microspheres

2020 ◽  
pp. 17-23
Author(s):  
Wendy Zhao ◽  
Xinyi Mei ◽  
Zheng Yue ◽  
Braja K Mandal
Keyword(s):  
Polymer Electrolytes ◽  
Lithium Ion ◽  
Solid Polymer Electrolytes ◽  
Solid Polymer ◽  
Scanning Calorimetry ◽  
Crosslinked Polystyrene ◽  
Poly Ethylene Oxide ◽  
Ion Conducting ◽  
Poly Ethylene ◽  
Surface Morphologies

A new class of lithium-ion conducting Solid Polymer Electrolytes (SPEs) has been derived from oligomeric Polyethylene Oxide (PEO)-grafted Cross-linked Polystyrene (XPS) microspheres containing one or two lithium sulfonamide moieties. The SPE containing Li:O mole ratio of 1:8 displayed excellent ionic conductivity (in excess of 10-4S/cm at 25ºC) and good electrochemical stability (4.3 volts versus Li/Li+). Thermal properties of these SPEs have also been investigated with Differential Scanning Calorimetry (DSC) and Thermogravimetric Analysis (TGA). These new SPEs possess amorphous character with a glass Transition Temperature (Tg) around 135ºC, and no significant thermal decomposition until 420ºC. Synthesis and characterization including surface morphologies of these SPEs are described.

Siloxane Diacrylate-based All-Solid Polymer Electrolytes for Lithium Batteries

2015 ◽  
Vol 2 (1) ◽  
pp. 23-27
Author(s):  
Jijeesh Nair ◽  
◽  
Matteo Destro ◽  
Claudio Gerbaldi ◽  
Federico Bella
Keyword(s):  
Lithium Batteries ◽  
Polymer Electrolytes ◽  
Solid Polymer Electrolytes ◽  
Solid Polymer

scholarly journals Biocompatible and biodegradable solid polymer electrolytes for high voltage and high temperature lithium batteries

RSC Advances ◽  
2017 ◽  
Vol 7 (40) ◽  
pp. 24856-24863 ◽  
Author(s):  
Yue Lin ◽  
Yun Cheng ◽  
Jie Li ◽  
Jan D. Miller ◽  
Jin Liu ◽  
...  
Keyword(s):  
High Temperature ◽  
Wheat Flour ◽  
High Voltage ◽  
Lithium Batteries ◽  
Polymer Electrolytes ◽  
Solid Polymer Electrolytes ◽  
Solid Polymer

Wheat flour modified solid polymer electrolytes were synthesized and used in high safety and long cycling lithium batteries.

scholarly journals Development of the PEO Based Solid Polymer Electrolytes for All-Solid State Lithium Ion Batteries

Polymers ◽  
2018 ◽  
Vol 10 (11) ◽  
pp. 1237 ◽  
Author(s):  
Yu Jiang ◽  
Xuemin Yan ◽  
Zhaofei Ma ◽  
Ping Mei ◽  
Wei Xiao ◽  
...  
Keyword(s):  
Solid State ◽  
Lithium Ion Batteries ◽  
Polymer Electrolytes ◽  
High Performance ◽  
Lithium Salt ◽  
Rapid Development ◽  
Lithium Ion ◽  
Solid Polymer Electrolytes ◽  
Solid Polymer ◽  
Potential Candidate

Solid polymer electrolytes (SPEs) have attracted considerable attention due to the rapid development of the need for more safety and powerful lithium ion batteries. The prime requirements of solid polymer electrolytes are high ion conductivity, low glass transition temperature, excellent solubility to the conductive lithium salt, and good interface stability against Li anode, which makes PEO and its derivatives potential candidate polymer matrixes. This review mainly encompasses on the synthetic development of PEO-based SPEs (PSPEs), and the potential application of the resulting PSPEs for high performance, all-solid-state lithium ion batteries.

Highly efficient solid polymer electrolytes using ion containing polymer microgels

2015 ◽  
Vol 6 (7) ◽  
pp. 1052-1055 ◽  
Author(s):  
Suting Yan ◽  
Jianda Xie ◽  
Qingshi Wu ◽  
Shiming Zhou ◽  
Anqi Qu ◽  
...  
Keyword(s):  
Ionic Conductivity ◽  
Polymer Electrolyte ◽  
Lithium Batteries ◽  
Polymer Electrolytes ◽  
Solid Polymer Electrolyte ◽  
Solid Polymer Electrolytes ◽  
High Ionic Conductivity ◽  
Solid Polymer ◽  
Highly Efficient ◽  
Potential Use

A solid polymer electrolyte fabricated using ion containing microgels manifests high ionic conductivity for potential use in lithium batteries.

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