Practical carbocatalysis by graphene oxide nanosheets in aqueous medium towards the synthesis of diversified dibenzo[1,4]diazepine scaffolds

RSC Advances ◽  
2016 ◽  
Vol 6 (91) ◽  
pp. 88904-88910 ◽  
Author(s):  
Nazia Kausar ◽  
Prasun Mukherjee ◽  
Asish R. Das

Metal free green protocol in aqueous medium. Use of GO nanosheets as exclusive heterogeneous catalyst. Almost intact catalytic activity upto the 5th run. Mild reaction conditions preserve sensitive structural moeities.

RSC Advances ◽  
2021 ◽  
Vol 11 (51) ◽  
pp. 32106-32118
Author(s):  
Puja Basak ◽  
Sourav Dey ◽  
Pranab Ghosh

Graphene oxide (GO) as a metal-free catalyst for the synthesis of 1,2,4-oxadiazoles and 2,4,6-triarylpyridines under mild reaction conditions.


RSC Advances ◽  
2021 ◽  
Vol 11 (42) ◽  
pp. 25867-25879
Author(s):  
Parisa Moradi ◽  
Maryam Hajjami

Catalytic activity of supported copper on magnetic graphene oxide was investigated as a selective and reusable nanocatalyst in the synthesis of diaryl ethers and biphenyls.


RSC Advances ◽  
2016 ◽  
Vol 6 (27) ◽  
pp. 22320-22330 ◽  
Author(s):  
Nazia Kausar ◽  
Indranil Roy ◽  
Dipankar Chattopadhyay ◽  
Asish R. Das

Graphene oxide nanosheet catalyzed strategies for construction of 2,3-dihydroquinazolinones and quinazolin-4(3H)-ones starting from anthranilamide and an aldehyde/ketone in aqueous medium at room temperature have been realized.


2016 ◽  
Vol 40 (6) ◽  
pp. 5053-5060 ◽  
Author(s):  
Shweta Kumari ◽  
Amiya Shekhar ◽  
Devendra D. Pathak

GO–TiO2 has been found to be a highly efficient and recyclable heterogeneous catalyst for the synthesis of pyrazoles and pyridines in aqueous medium at room temperature.


2019 ◽  
Vol 23 (07n08) ◽  
pp. 828-840 ◽  
Author(s):  
Lekhetho S. Mpeta ◽  
Tebello Nyokong

Alkyne-terminated Co phthalocyanine (CoPc) derivatives are linked to reduced graphene oxide nanosheets (GONS) via click chemistry and the conjugates are used for the electrocatalytic oxidation of 2-mercaptoethanol. CoPc derivatives where the alkyne group is separated from the Pc ring by an aliphatic and benzene ring (complex 3) showed the best catalytic activity (in terms of oxidation potential) in comparison to when only aliphatic chains were employed without the benzene ring (complex 2) and when there were no substituents (complex 1). The anodic oxidation of 2-mercaptoethanol on 3-GONS (linked) occurred at the least positive oxidation potential (-0.22 V vs. Ag|AgCl). 3-GONS (linked) was found to have the highest sensitivity with the lowest limit of detection of 0.08 [Formula: see text]M. When the CoPc derivative and GONS were not linked but placed sequentially on the electrode, the electrocatalytic activity (in terms of LOD) was poorer than when linked. The electrodes modified with CoPc clicked to GONS are highly promising electrochemical sensors in terms of stability, sensitivity, good catalytic activity and ease of fabrication.


RSC Advances ◽  
2015 ◽  
Vol 5 (107) ◽  
pp. 87831-87837 ◽  
Author(s):  
Tongjie Yao ◽  
Quan Zuo ◽  
Hao Wang ◽  
Jie Wu ◽  
Xiao Zhang ◽  
...  

A one-step method to prepare reduced graphene oxide/PdxAuy/polypyrrole composites with good catalytic activity was introduced. The morphologies of alloy nanostructures could turn to be spherical, coral-like and porous cluster-like.


2018 ◽  
Vol 54 (27) ◽  
pp. 3343-3346 ◽  
Author(s):  
Tingting Liu ◽  
Shuo Wang ◽  
Qiuju Zhang ◽  
Liang Chen ◽  
Weihua Hu ◽  
...  

A Pt-free catalyst of ultrasmall Ru2P nanoparticles on reduced graphene oxide nanosheets (Ru2P/RGO-20) shows remarkable HER catalytic activity under acidic and alkaline conditions, respectively, both superior to those of commercial Pt/C.


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