Decoration of CdS nanoparticle on dense and multi-edge sodium titanate nanorods to form a highly efficient and stable photoanode with great enhancement in PEC performance

This study provided preparation and application of a highly efficient photoanode having dense and efficient sodium titanate (NTO) nanorods decorated with CdS nanoparticles. The (NTO) nanorods were grown densely on...

CdS nanoparticles decorated triazine-based COFs with enhanced photocatalytic activity for highly effective degradation of emerging contaminants

Photocatalytic technique is an attractive strategy to activate persulfate for generating free radicals in the wastewater purification process. Herein, the CdS nanoparticle with unique optical property was employed to decorate...

Photosensitive Thin Films Based on Drop Cast and Langmuir-Blodgett Hydrophilic and Hydrophobic CdS Nanoparticles

Comparative photoelectrochemical studies of cadmium sulfide (CdS) nanoparticles with either hydrophilic or hydrophobic surface properties are presented. Oleylamine organic shells provided CdS nanoparticles with hydrophobic behavior, affecting the photoelectrochemical properties of such nanostructured semiconductor. Hydrophilic CdS nanoparticles were drop-cast on the electrode, whereas the hydrophobic ones were transferred in a controlled manner with Langmuir-Blodgett technique. The substantial hindrance of photopotential and photocurrent was observed for L-B CdS films as compared to the hydrophilic, uncoated nanoparticles that were drop-cast directly on the electrode surface. The electron lifetime in both hydrophilic and hydrophobic nanocrystalline CdS was determined, revealing longer carrier lifetime for oleylamine coated CdS nanoparticles, ascribed to the trapping of charge at the interface of the organic shell/CdS nanoparticle and to the dominant influence of the resistance of the organic shell against the flux of charges. The “on” transients of the photocurrent responses, observed only for the oleylamine-coated nanoparticles, were resolved, yielding the potential-dependent rate constants of the redox processes occurring at the interface.

Synthesis and Characteristics of CdS Nanoparticles in Normal (1 g) and Simulated Microgravity (SMG)

In the present investigation, the cadmium sulphide (CdS) nanoparticles are synthesized in the normal gravity i.e. 1 g (called as control) and in simulated microgravity (called as SMG). The SMG was created by using an instrument called Random Positioning Machine (RPM). Cadmium sulfide nanoparticles were synthesized by using standard chemical method under normal gravity (1 g) and simulated microgravity conditions. The synthesized CdS nanoparticles were characterized by Ultraviolet Visible spectroscopy, Fourier Transform Infrared Ray spectroscopy (FTIR), X-ray diffraction (XRD). The UV-visible absorption spectrum of CdS nanoparticle solution showed a distinct absorption peak at 472.19 nm in control and 458.26 nm in SMG. The band gap calculated from the absorption edge for microgravity sample was 2.71 eV and for control sample was 2.63 eV. The crystalline size of CdS nanoparticles synthesised in control and Micro-g was determined by XRD. Obtained results showed smaller the particle size in microgravity sample (10.78 nm) as compared to control sample (13.89 nm).