Porous hollow manganites with robust composite shells for oxidation of CO at low temperature

RSC Advances ◽  
2016 ◽  
Vol 6 (114) ◽  
pp. 113682-113688 ◽  
Author(s):  
Jung Bo Yoo ◽  
Sora Bang ◽  
Kyungtae Kim ◽  
Chengbin Li ◽  
Ji Man Kim ◽  
...  

Hollow-type manganite-coated silica microspheres were synthesized via the thermal hydrolysis of urea. The Mn2O3/SiO2_3T microspheres with robust shells exhibit best catalytic performance for CO oxidation even at temperatures below 200 °C.

Data in Brief ◽  
2021 ◽  
pp. 107323
Author(s):  
Mohamed N.A. Meshref ◽  
Seyed Mohammad Mirsoleimani Azizi ◽  
Wafa Dastyar ◽  
Rasha Maal-Bared ◽  
Bipro Ranjan Dhar

Author(s):  
AJ Dyakonov ◽  
EA Robinson

AbstractThe low-temperature catalytic oxidation of CO has been reviewed, targeting its possible application to cigarette smoke. The treatment of CO in smoke by using a filter-packed catalyst is extremely complicated by the presence of a variety of chemically active gaseous compounds, a particulate phase, the high velocity of pulsing smoke flow, and ambient temperature. The relevant mechanisms of catalysis and the catalyst preparation variables that could help to overcome these problems are considered. Possible contributors to the overall kinetics that must include variety of diffusion processes were briefly discussed. The chemisorption of O2, CO and CO2 on Pd, Pt and Au and on partially reducible supports, surface reactions and oscillations of the CO oxidation rate were analyzed. The effects of the surface structure and electronic properties of the catalyst support, preparation conditions and presence of a second transition metal on the projected CO oxidation activity of the catalysts in smoke are also discussed. The reviewed catalyst preparation approaches can solve the low-temperature catalyst activity problem. However, more work is required to stabilize this activity of an air-exposed catalyst to provide a necessary shelf life for a cigarette. The greatest challenge seems to be a particular phase - exclusive selectivity that would not contradict with the necessary fast diffusion of gases through the catalyst pores.


2014 ◽  
Vol 4 (5) ◽  
pp. 1268-1275 ◽  
Author(s):  
Jie Li ◽  
Guanzhong Lu ◽  
Guisheng Wu ◽  
Dongsen Mao ◽  
Yanglong Guo ◽  
...  

Co3O4 supported on TiO2 (anatase (A), rutile (R) and P25 (Degussa)) catalysts were prepared by a deposition–precipitation method. Co3O4/TiO2 (A) shows excellent activity for CO oxidation with 100% conversion at −43 °C.


RSC Advances ◽  
2016 ◽  
Vol 6 (71) ◽  
pp. 66553-66563 ◽  
Author(s):  
Fanyun Zhou ◽  
Xuexun Du ◽  
Jun Yu ◽  
Dongsen Mao ◽  
Guanzhong Lu

PdCl2–CuCl2/CNT was prepared by the two-step impregnation method, and the effects of the Pd and Cu loadings on its physicochemical properties and catalytic performance for low-temperature CO oxidation in the presence of H2O were investigated.


2007 ◽  
Vol 102 (1-3) ◽  
pp. 333-336 ◽  
Author(s):  
Baolin Zhu ◽  
Xiaoxiang Zhang ◽  
Shurong Wang ◽  
Shoumin Zhang ◽  
Shihua Wu ◽  
...  

2007 ◽  
Vol 116 (3-4) ◽  
pp. 136-142 ◽  
Author(s):  
Yong-Zhao Wang ◽  
Yong-Xiang Zhao ◽  
Chun-Guang Gao ◽  
Dian-Sheng Liu

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