Exceptional high selectivity of hydrogen/methane separation on a phosphonate-based MOF membrane with exclusion of methane molecules

2017 ◽  
Vol 53 (70) ◽  
pp. 9797-9800 ◽  
Author(s):  
Qipeng Yang ◽  
Liangjun Li ◽  
Weiqiang Tan ◽  
Yingjie Sun ◽  
Huanli Wang ◽  
...  

A phosphonate-based metal–organic framework membrane was constructed on a porous anodic alumina membrane (PAAM) substrate for H2/CH4 separation for the first time.

2019 ◽  
Author(s):  
Timothée Stassin ◽  
Ivo Stassen ◽  
Joao Marreiros ◽  
Alexander John Cruz ◽  
Rhea Verbeke ◽  
...  

A simple solvent- and catalyst-free method is presented for the synthesis of the mesoporous metal-organic framework (MOF) MAF-6 (RHO-Zn(eIm)2) based on the reaction of ZnO with 2-ethylimidazole vapor at temperatures ≤ 100 °C. By translating this method to a chemical vapor deposition (CVD) protocol, mesoporous crystalline films could be deposited for the first time entirely from the vapor phase. A combination of PALS and Kr physisorption measurements confirmed the porosity of these MOF-CVD films and the size of the MAF-6 supercages (diam. ~2 nm), in close agreement with powder data and calculations. MAF-6 powders and films were further characterized by XRD, TGA, SEM, FTIR, PDF and EXAFS. The exceptional uptake capacity of the mesoporous MAF-6 in comparison to the microporous ZIF-8 is demonstrated by vapor-phase loading of a molecule larger than the ZIF-8 windows.


2021 ◽  
Vol 9 (7) ◽  
pp. 1811-1820
Author(s):  
Shuang Yan ◽  
Bin Luo ◽  
Jia He ◽  
Fang Lan ◽  
Yao Wu

Novel bimetallic metal–organic framework nanocomposites were fabricated by a facile yet efficient method. The as-prepared nanomaterial exhibited high sensitivity and high selectivity toward phosphopeptides and good reusability of five cycles for enriching phosphopeptides.


2021 ◽  
Vol 1147 ◽  
pp. 144-154
Author(s):  
Yao-Yao Zhang ◽  
Wang Xu ◽  
Jian-Fang Cao ◽  
Yang Shu ◽  
Jian-Hua Wang

2007 ◽  
Vol 56 (11) ◽  
pp. 6712
Author(s):  
Huang Li-Qing ◽  
Pan Hua-Qiang ◽  
Wang Jun ◽  
Tong Hui-Min ◽  
Zhu Ke ◽  
...  

2010 ◽  
Vol 10 (5) ◽  
pp. 3380-3384 ◽  
Author(s):  
Mohamed Shaban ◽  
Hany Hamdy ◽  
Fayez Shahin ◽  
Joonmo Park ◽  
Sang-Wan Ryu

2019 ◽  
Vol 10 (18) ◽  
pp. 2263-2272 ◽  
Author(s):  
Huaizhi Liu ◽  
Hao Peng ◽  
Yumeng Xin ◽  
Jiuyang Zhang

We reported for the first time using metal–organic framework (MOF) nanoparticles as effective nanofillers to significantly enhance the mechanical performance of hydrogels. The MOF hydrogels have been developed for drug delivery materials with high loading capacity and much extended drug releasing profiles.


2020 ◽  
Vol 49 (17) ◽  
pp. 5618-5624
Author(s):  
Rui Zhang ◽  
Ju-Hua Huang ◽  
De-Xian Meng ◽  
Fa-Yuan Ge ◽  
Li-Fei Wang ◽  
...  

Three MOF isomers including framework-catenation and framework-topological isomers were synthesized for adsorbing carbon dioxide with high selectivity.


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