Chemically reprogrammable metal organic frameworks (MOFs) based on Diels–Alder chemistry

2017 ◽  
Vol 53 (83) ◽  
pp. 11461-11464 ◽  
Author(s):  
Sana Nayab ◽  
Vanessa Trouillet ◽  
Hartmut Gliemann ◽  
Silvana Hurrle ◽  
Peter G. Weidler ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Diels Alder ◽  
New Class ◽  
Metal Organic

We pioneer a new class of reprogrammable MOFs able to switch their interlattice chemistry via a facile Diels–Alder based cycloreversion process.

scholarly journals Proton transfer in hydrogen-bonded degenerate systems of water and ammonia in metal–organic frameworks

2019 ◽  
Vol 10 (1) ◽  
pp. 16-33 ◽  
Author(s):  
Dae-Woon Lim ◽  
Masaaki Sadakiyo ◽  
Hiroshi Kitagawa
Keyword(s):  
Proton Transfer ◽  
Metal Organic Frameworks ◽  
Proton Conductors ◽  
Degenerate System ◽  
New Class ◽  
System P ◽  
Metal Organic ◽  
Crystalline Metal ◽  
Hydrogen Bonded

Porous crystalline metal–organic frameworks (MOFs) are emerging as a new class of proton conductors through the hydrogen-bonded degenerate system.

Ag+-sensitized lanthanide luminescence in Ln3+ post-functionalized metal–organic frameworks and Ag+ sensing

2015 ◽  
Vol 3 (9) ◽  
pp. 4788-4792 ◽  
Author(s):  
Ji-Na Hao ◽  
Bing Yan
Keyword(s):  
Energy Transfer ◽  
Metal Organic Frameworks ◽  
Intramolecular Energy Transfer ◽  
Lanthanide Luminescence ◽  
New Class ◽  
Metal Organic ◽  
Nir Luminescence ◽  
Co Doped

A new class of lanthanide luminescent MOFs was constructed by encapsulating Ln3+ into the pores of MIL-121 (Ln3+@MIL-121). Ag+ was found to be able to greatly enhance the weak visible or NIR luminescence of Ln3+@MIL-121 since it can induce more efficient intramolecular energy transfer from the ligand to Ln3+ in Ag–Ln co-doped MOFs.

scholarly journals Enantioselective Diels–Alder reaction in the confined space of homochiral metal–organic frameworks

RSC Advances ◽  
2016 ◽  
Vol 6 (112) ◽  
pp. 111436-111439 ◽  
Author(s):  
Koichi Tanaka ◽  
Shohei Nagase ◽  
Taku Anami ◽  
Michał Wierzbicki ◽  
Zofia Urbanczyk-Lipkowska
Keyword(s):  
Heterogeneous Catalyst ◽  
Metal Organic Frameworks ◽  
Alder Reaction ◽  
Diels Alder ◽  
Confined Space ◽  
Diels Alder Reaction ◽  
Metal Organic

A novel homochiral porous MOF synthesized using (R)-2,2′-dihydroxy-1,1′-binaphthyl-4,4′-dibenzoic acid was shown to be an effective heterogeneous catalyst for asymmetric Diels–Alder reaction between isoprene and N-ethyl maleimide.

Laser-induced synthesis of ZIF-67: a facile approach for the fabrication of crystalline MOFs with tailored size and geometry

2019 ◽  
Vol 3 (7) ◽  
pp. 1302-1309 ◽  
Author(s):  
Erick L. Ribeiro ◽  
Seyyed Ali Davari ◽  
Sheng Hu ◽  
Dibyendu Mukherjee ◽  
Bamin Khomami
Keyword(s):  
Porous Materials ◽  
Metal Organic Frameworks ◽  
New Class ◽  
Metal Organic

Metal organic frameworks (MOFs) are fast emerging as a new class of crystalline hybrid porous materials originating from inorganic (metal) nodes connected by organic linkers.

Reversible Diels–Alder and Michael Addition Reactions Enable the Facile Postsynthetic Modification of Metal–Organic Frameworks

2021 ◽  
Vol 60 (7) ◽  
pp. 4397-4409
Author(s):  
Sana Nayab ◽  
Vanessa Trouillet ◽  
Hartmut Gliemann ◽  
Peter G. Weidler ◽  
Iqra Azeem ◽  
...  
Keyword(s):  
Michael Addition ◽  
Metal Organic Frameworks ◽  
Diels Alder ◽  
Addition Reactions ◽  
Postsynthetic Modification ◽  
Metal Organic
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