The atmospheric oxidation of CH3OOH by the OH radical: the effect of water vapor

2017 ◽  
Vol 19 (19) ◽  
pp. 12331-12342 ◽  
Author(s):  
Josep M. Anglada ◽  
Ramon Crehuet ◽  
Marilia Martins-Costa ◽  
Joseph S. Francisco ◽  
Manuel Ruiz-López

The relative humidity can enhance the atmospheric oxidation of CH3OOH by OH into CH3O2 + H2O up to 19% whereas the formation of H2CO + OH + H2O is enhanced up to 5% only under the same conditions.

1995 ◽  
Vol 412 ◽  
Author(s):  
Gregory E. Gdowski ◽  
John C. Estill

AbstractAISI 1020 carbon steel was exposed to air at various relative humidities at 65°C. A “critical relative humidity” (CRH) of 75–85% was determined. The CRH is the transitional relative humidity where oxidation/corrosion changes from dry oxidation to aqueous film electrochemical corrosion. Short term testing suggests that aqueous film electrochemical corrosion results in the formation of an inner oxide of Fe3O4, and an outer oxide of a powdery Fe2O3 and/or Fe2O3·xH2O.


2005 ◽  
Vol 22 (1) ◽  
pp. 139-146 ◽  
Author(s):  
Alexander Donchev ◽  
Harald Fietzek ◽  
Vladislav Kolarik ◽  
Daniel Renusch ◽  
Michael Schütze

2021 ◽  
Vol 13 (11) ◽  
pp. 2179
Author(s):  
Pedro Mateus ◽  
Virgílio B. Mendes ◽  
Sandra M. Plecha

The neutral atmospheric delay is one of the major error sources in Space Geodesy techniques such as Global Navigation Satellite Systems (GNSS), and its modeling for high accuracy applications can be challenging. Improving the modeling of the atmospheric delays (hydrostatic and non-hydrostatic) also leads to a more accurate and precise precipitable water vapor estimation (PWV), mostly in real-time applications, where models play an important role, since numerical weather prediction models cannot be used for real-time processing or forecasting. This study developed an improved version of the Hourly Global Pressure and Temperature (HGPT) model, the HGPT2. It is based on 20 years of ERA5 reanalysis data at full spatial (0.25° × 0.25°) and temporal resolution (1-h). Apart from surface air temperature, surface pressure, zenith hydrostatic delay, and weighted mean temperature, the updated model also provides information regarding the relative humidity, zenith non-hydrostatic delay, and precipitable water vapor. The HGPT2 is based on the time-segmentation concept and uses the annual, semi-annual, and quarterly periodicities to calculate the relative humidity anywhere on the Earth’s surface. Data from 282 moisture sensors located close to GNSS stations during 1 year (2020) were used to assess the model coefficients. The HGPT2 meteorological parameters were used to process 35 GNSS sites belonging to the International GNSS Service (IGS) using the GAMIT/GLOBK software package. Results show a decreased root-mean-square error (RMSE) and bias values relative to the most used zenith delay models, with a significant impact on the height component. The HGPT2 was developed to be applied in the most diverse areas that can significantly benefit from an ERA5 full-resolution model.


Author(s):  
Feng-Yang Bai ◽  
Ming-Shuai Deng ◽  
Mei-Yan Chen ◽  
Lian Kong ◽  
Shuang Ni ◽  
...  

The transport and formation of fluorinated compounds are greatly significant due to their possible environmental risks. In this work, the ·OH-mediated degradation of CF3CF2CF2CH2OH and CF3CHFCF2CH2OH in the existence of...


1934 ◽  
Vol 26 (1) ◽  
pp. 71-72 ◽  
Author(s):  
G. W. Jones ◽  
Henry. Seaman
Keyword(s):  

1999 ◽  
Vol 48 (2) ◽  
pp. 65-76 ◽  
Author(s):  
K. El harfi ◽  
A. Mokhlisse ◽  
M.Ben Chanâa

2016 ◽  
Vol 18 (26) ◽  
pp. 17414-17427 ◽  
Author(s):  
Tianlei Zhang ◽  
Chen Yang ◽  
Xukai Feng ◽  
Jiaxin Kang ◽  
Liang Song ◽  
...  

Catalyst X (X = H2O, (H2O)2and (H2O)3) is incorporated into the channel of H2S +3O2formation and the catalytic effect of water, water dimers and water trimers is mainly taken from the contribution of a single water vapor molecule.


2011 ◽  
Vol 344 (1-2) ◽  
pp. 111-121 ◽  
Author(s):  
Zeinhom M. El-Bahy ◽  
Ahmed I. Hanafy ◽  
Mohamed M. Ibrahim ◽  
Masakazu Anpo

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