Phase diversity in an adsorption model of an additive binary gas mixture for all sets of lateral interactions

2018 ◽  
Vol 20 (15) ◽  
pp. 10359-10368 ◽  
Author(s):  
V. F. Fefelov ◽  
A. V. Myshlyavtsev ◽  
M. D. Myshlyavtseva
Keyword(s):  
Phase Behavior ◽  
Square Lattice ◽  
Complete Analysis ◽  
Gas Mixture ◽  
Lateral Interactions ◽  
Adsorption Model ◽  
Adsorbed Molecules ◽  
Phase Diversity ◽  
Binary Gas Mixture ◽  
Different Types

Complete analysis of phase behavior of an adsorption model of a binary gas mixture on a square lattice was carried out for all possible sets of lateral interactions between nearest adsorbed molecules of the same type and no interaction between adsorbed molecules of different types.

Adsorption of organics on thermally treated solids obtained from colloidal silica

1987 ◽  
Vol 52 (3) ◽  
pp. 572-581 ◽  
Author(s):  
Miroslav M. Kopečni ◽  
Slobodan K. Milonjic ◽  
Wladyslaw Rudzinski ◽  
Jacek Jagiello
Keyword(s):  
Gas Chromatography ◽  
Thermodynamic Parameters ◽  
Adsorption Isotherms ◽  
Colloidal Silica ◽  
Adsorption Properties ◽  
Thermal Pretreatment ◽  
Lateral Interactions ◽  
Adsorbed Molecules ◽  
Temperature Range ◽  
Thermally Treated

Adsorption isotherms of three adsorbates on the solid beads obtained from colloidal silica were determined by means of gas chromatography at low surface coverages, when lateral interactions between the adsorbed molecules are negligible. The influence of thermal pretreatment on the adsorption properties of the solids was investigated in the temperature range from 343 to 423 K, while the solids were heated between 523 K and 1 223 K. The thermodynamic parameters of adsorption have been determined and used to discuss the adsorbate-adsorbent interactions.

scholarly journals Influence of Casting Solvents on CO2/CH4 Separation Using Polysulfone Membranes

Membranes ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 286
Author(s):  
Roba M. Almuhtaseb ◽  
Ahmed Awadallah-F ◽  
Shaheen A. Al-Muhtaseb ◽  
Majeda Khraisheh
Keyword(s):  
High Efficiency ◽  
In Situ Synthesis ◽  
Separation Process ◽  
Polymeric Membranes ◽  
Gas Mixture ◽  
Manufacturing Cost ◽  
Binary Gas Mixture ◽  
Maximum Permeability ◽  
Polysulfone Membranes

Polysulfone membranes exhibit resistance to high temperature with low manufacturing cost and high efficiency in the separation process. The composition of gases is an important step that estimates the efficiency of separation in membranes. As membrane types are currently becoming in demand for CO2/CH4 segregation, polysulfone will be an advantageous alternative to have in further studies. Therefore, research is undertaken in this study to evaluate two solvents: chloroform (CF) and tetrahydrofuran (THF). These solvents are tested for casting polymeric membranes from polysulfone (PSF) to separate every single component from a binary gas mixture of CO2/CH4. In addition, the effect of gas pressure was conducted from 1 to 10 bar on the behavior of the permeability and selectivity. The results refer to the fact that the maximum permeability of CO2 and CH4 for THF is 62.32 and 2.06 barrer at 1 and 2 bars, respectively. Further, the maximum permeability of CF is 57.59 and 2.12 barrer at 1 and 2 bars, respectively. The outcome selectivity values are 48 and 36 for THF and CF at 1 bar, accordingly. Furthermore, the study declares that with the increase in pressure, the permeability and selectivity values drop for CF and THF. The performance for polysulfone (PSF) membrane that is manufactured with THF is superior to that of CF relative to the Robeson upper bound. Therefore, through the results, it can be deduced that the solvent during in-situ synthesis has a significant influence on the gas separation of a binary mixture of CO2/CH4.

scholarly journals Effects of Polydispersity on the Phase Behavior of Additive Hard Spheres in Solution

Molecules ◽  
2021 ◽  
Vol 26 (6) ◽  
pp. 1543
Author(s):  
Luka Sturtewagen ◽  
Erik van der Linden
Keyword(s):  
Phase Behavior ◽  
Critical Point ◽  
Volume Fraction ◽  
Hard Spheres ◽  
Second Virial Coefficient ◽  
Two Phase ◽  
Different Types ◽  
Asymmetric Partitioning ◽  
Average Size ◽  
Liquid Liquid Phase Separation

The ability to separate enzymes, nucleic acids, cells, and viruses is an important asset in life sciences. This can be realised by using their spontaneous asymmetric partitioning over two macromolecular aqueous phases in equilibrium with one another. Such phases can already form while mixing two different types of macromolecules in water. We investigate the effect of polydispersity of the macromolecules on the two-phase formation. We study theoretically the phase behavior of a model polydisperse system: an asymmetric binary mixture of hard spheres, of which the smaller component is monodisperse and the larger component is polydisperse. The interactions are modelled in terms of the second virial coefficient and are assumed to be additive hard sphere interactions. The polydisperse component is subdivided into sub-components and has an average size ten times the size of the monodisperse component. We calculate the theoretical liquid–liquid phase separation boundary (the binodal), the critical point, and the spinodal. We vary the distribution of the polydisperse component in terms of skewness, modality, polydispersity, and number of sub-components. We compare the phase behavior of the polydisperse mixtures with their concomittant monodisperse mixtures. We find that the largest species in the larger (polydisperse) component causes the largest shift in the position of the phase boundary, critical point, and spinodal compared to the binary monodisperse binary mixtures. The polydisperse component also shows fractionation. The smaller species of the polydisperse component favor the phase enriched in the smaller component. This phase also has a higher-volume fraction compared to the monodisperse mixture.

Phase behavior of linear heterogeneous trimers on a square lattice

2011 ◽  
Vol 135 (19) ◽  
pp. 194702 ◽  
Author(s):  
W. Rżysko ◽  
M. Borówko
Keyword(s):  
Phase Behavior ◽  
Square Lattice

scholarly journals Simulation of a two-dimensional binary gas mixture outflow into vacuum through a thin slit on the basis of direct solution of the Boltzmann kinetic equation

2021 ◽  
Vol 2056 (1) ◽  
pp. 012007
Author(s):  
S S Sitnikov ◽  
F G Tcheremissine ◽  
T A Sazykina
Keyword(s):  
Kinetic Equation ◽  
Boltzmann Kinetic Equation ◽  
Gas Mixture ◽  
Two Dimensional ◽  
Direct Solution ◽  
Steady State Regime ◽  
Collision Integrals ◽  
Flow Formation ◽  
Binary Gas Mixture ◽  
State Regime

Abstract Two-dimensional binary gas mixture outflow from a vessel into vacuum through a thin slit is studied on the basis of direct solution of the Boltzmann kinetic equation. For evaluation of collision integrals in the Boltzmann equation a conservative projection method is used. Numerical simulation of a two-dimensional argon-neon gas mixture outflow from a vessel into vacuum was performed. Graphs of mixture components flow rate dependence on time during the flow formation, as well as fields of molecular density and temperature for steady-state regime, were obtained.

scholarly journals ANALYSIS OF STUDENT FORMULA CAR FOR OPTIMUM SAFETY AND PERFORMANCE

2020 ◽  
pp. 137-142
Author(s):  
Rabi Pathak
Keyword(s):  
Boundary Conditions ◽  
Weight Reduction ◽  
Structural Performance ◽  
Complete Analysis ◽  
Loading Conditions ◽  
Different Types ◽  
And Performance ◽  
Reliability Performance ◽  
Ansys Workbench

The Formula Student competitions are held everyyear. This paper is the result of the analysis done on the sample car design that can be presented in the Formula Student competition. The purpose of the paper is to provide a final summary on chassis analysis and structural performance. It also talks about all the important analysis that is to be done on a Formula Student car to make it safe and perform well on the track. The design has been made such that it focusses on maximum adjustability, reliability, performance, safety, weight reduction and ease of manufacturing. The analysis was done to make sure the objectives of design are fulfilled. After going through many papers, documents, blogs and videos we found that many people get confused about the loading conditions and boundary conditions for different types of tests so this paper prioritizes to make people understand about those conditions as well as about the major tests required to perform complete analysis of Formula Student cars. The weight of the chassis was calculated as 36 kg approximately according to the data obtained from design modeler of Ansys workbench as well as Solidworks. The design sustained all the loading conditions and passed all the tests. Thus, one of the objective of this paper is to help other universities and passionate students to successfully design and analyze their cars that can pass all necessary tests included in the paper. KEYWORDS—Formula Student; FEA; Boundary Conditions; Loading Conditions; Ansys; Solidworks

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