Melamine tunable effect in a lenalidomide-based supramolecular self-assembly system via hydrogen bonding

2017 ◽  
Vol 41 (16) ◽  
pp. 7924-7931 ◽  
Author(s):  
Aiping Gao ◽  
Yiran Li ◽  
Haiting Lv ◽  
Dan Liu ◽  
Na Zhao ◽  
...  

In this study, melamine could tune the self-assembly structures, rheological behaviour, and surface wettability via intermolecular hydrogen bonding between gelator 1 and melamine.

2018 ◽  
Vol 74 (8) ◽  
pp. 1151-1154
Author(s):  
Pushpendra Singh ◽  
Harkesh B. Singh ◽  
Ray J. Butcher

In the title compound, [HgCl2(C16H28N2Se)], the primary geometry around the Se and Hg atoms is distorted trigonal–pyramidal and distorted square-pyramidal, respectively. The distortion of the molecular geometry in the complex is caused by the steric demands of the ligands attached to the Se atom. The Hg atom is coordinated through two chloride anions, an N atom and an Se atom, making up an unusual HgNSeCl2 coordination sphere with an additional long Hg...N interaction. Intermolecular C—H...Cl interactions are the only identified intermolecular hydrogen-bonding interactions that seem to be responsible for the self assembly. These relatively weak C—H...Cl hydrogen bonds possess the required linearity and donor–acceptor distances. They act as molecular associative forces that result in a supramolecular assembly along the b-axis direction in the solid state of the title compound.


Author(s):  
Ganghuo Pan ◽  
Jie Leng ◽  
Liye Deng ◽  
Liwen Xing ◽  
Rui Feng

Author(s):  
Alejandro Rodríguez ◽  
Alexander Grushin ◽  
James A. Reggia

Drawing inspiration from social interactions in nature, swarm intelligence has presented a promising approach to the design of complex systems consisting of numerous, simple parts, to solve a wide variety of problems. Swarm intelligence systems involve highly parallel computations across space, based heavily on the emergence of global behavior through local interactions of components. This has a disadvantage as the desired behavior of a system becomes hard to predict or design. Here we describe how to provide greater control over swarm intelligence systems, and potentially more useful goal-oriented behavior, by introducing hierarchical controllers in the components. This allows each particle-like controller to extend its reactive behavior in a more goal-oriented style, while keeping the locality of the interactions. We present three systems designed using this approach: a competitive foraging system, a system for the collective transport and distribution of goods, and a self-assembly system capable of creating complex 3D structures. Our results show that it is possible to guide the self-organization process at different levels of the designated task, suggesting that self-organizing behavior may be extensible to support problem solving in various contexts.


2019 ◽  
Vol 21 (21) ◽  
pp. 11242-11258
Author(s):  
Valery Andrushchenko ◽  
Walter Pohle

IR spectroscopy paired with calculations reveals that structurally similar amphiphiles ODA and DOG form very different supramolecular assemblies.


2017 ◽  
Vol 53 (84) ◽  
pp. 11552-11555 ◽  
Author(s):  
Jiangjun Chen ◽  
Zhongxin Zhang ◽  
Chengming Wang ◽  
Zhao Gao ◽  
Zongchun Gao ◽  
...  

Organogold(i)-based fibers and gels have been successfully constructed, which involve Au⋯Au interactions in the self-assembled structures.


2008 ◽  
Vol 120 (6) ◽  
pp. 1079-1083 ◽  
Author(s):  
Junchen Wu ◽  
Tao Yi ◽  
Tianmin Shu ◽  
Mengxiao Yu ◽  
Zhiguo Zhou ◽  
...  

2006 ◽  
Vol 25 (22) ◽  
pp. 5276-5285 ◽  
Author(s):  
Seung Uk Son ◽  
Jeffrey A. Reingold ◽  
Gene B. Carpenter ◽  
Paul T. Czech ◽  
Dwight A. Sweigart

2010 ◽  
Vol 82 (4) ◽  
pp. 917-929 ◽  
Author(s):  
Stefan Mohnani ◽  
Anna Llanes-Pallas ◽  
Davide Bonifazi

The controlled engineering of functional architectures composed of π-systems with unusual opto-electronic properties is currently being investigated intensively from both fundamental research and technological application viewpoints. In particular, the exploitation of the supramolecular approach for the facile construction of multidimensional architectures, featuring cavities capable of hosting functional molecules, could be used in several applications, such as nanomedicine, molecular-based memory storage devices, and sensors. This paper highlights our recent strategies to use hydrogen-bonding interactions to prepare nanostructured functional architectures via the self-assembly of organic molecular modules studied at different interfaces.


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