scholarly journals High surface coverage of a self-assembled monolayer by in situ synthesis of palladium nanodeposits

Nanoscale ◽  
2017 ◽  
Vol 9 (35) ◽  
pp. 13281-13290 ◽  
Author(s):  
Lucía Herrer ◽  
Victor Sebastian ◽  
Santiago Martín ◽  
Alejandro González-Orive ◽  
Francesc Pérez-Murano ◽  
...  
Keyword(s):  
Surface Coverage ◽  
High Surface ◽  
In Situ Synthesis ◽  
Self Assembled Monolayer ◽  
Confined Growth ◽  
Growth Method ◽  
Self Assembled

Nascent metal|monolayer|metal devices have been fabricated by depositing palladium, by growing palladium nanodeposits through a CO-confined growth method.

In Situ Synthesis of a Novel Quinone Imine Self-Assembled Monolayer and Consideration of Its Reactivity with L-Arginine

2012 ◽  
Vol 24 (6) ◽  
pp. 1362-1373 ◽  
Author(s):  
Ali Hamzehloei ◽  
Mir Fazlollah Mousavi ◽  
S. Zahra Bathaie
Keyword(s):  
Quinone Imine ◽  
In Situ Synthesis ◽  
Self Assembled Monolayer ◽  
Self Assembled

Spectral and cyclic voltammetric characterization of self-assembled monolayers on gold of pyrene end-labeled oligonucleotide duplexes

1999 ◽  
Vol 77 (5-6) ◽  
pp. 1077-1084 ◽  
Author(s):  
R Scott Reese ◽  
Marye Anne Fox
Keyword(s):  
Gold Surface ◽  
Self Assembled Monolayers ◽  
Self Assembled Monolayer ◽  
Surface Emission ◽  
Assembled Monolayers ◽  
Oligonucleotide Duplex ◽  
Self Assembled ◽  
Duplex Formation

Self-assembled monolayers of sulfur-terminated oligonucleotide duplexes were formed on flat gold surfaces, either by exposure of a self-assembled monolayer bearing one oligonucleotide strand to the complementary strand or by preformation of a oligonucleotide duplex that was then deposited on a fresh gold surface. Virtually identical spectral behavior was observed whether the duplex was produced before deposition or by in situ complementary association. With a duplex bearing an appropriate pyrene end-label, the resulting thin film was photoresponsive. Surface emission measurements show no evidence for pyrene aggregation on the modified surfaces. The polarity of the photocurrent, reflecting photoinduced electron transfer initiated by photoexcitation of pyrene, is opposite that expected from the oligonucleotide-mediated reduction of the appended pyrene excited state.Key words: oligonucleotide, self-assembled monolayer, duplex formation, photoelectrochemistry, surface emission.

Innenrücktitelbild: In Situ Synthesis of Self-Assembled Gold Nanoparticles on Glass or Silicon Substrates through Reactive Inkjet Printing (Angew. Chem. 2/2014)

2013 ◽  
Vol 126 (2) ◽  
pp. 611-611
Author(s):  
Mutalifu Abulikemu ◽  
Eman Husni Da'as ◽  
Hanna Haverinen ◽  
Dongkyu Cha ◽  
Mohammad Azad Malik ◽  
...  
Keyword(s):  
Gold Nanoparticles ◽  
Inkjet Printing ◽  
In Situ Synthesis ◽  
Silicon Substrates ◽  
Self Assembled

Performances of Sexithiophene Based Thin-Film Transistor Using Self-Assembled Monolayers

1997 ◽  
Vol 488 ◽  
Author(s):  
J. Collet ◽  
O. Tharaud ◽  
C. Legrand ◽  
A. Chapoton ◽  
D. Vuillaume
Keyword(s):  
Thin Film ◽  
Threshold Voltage ◽  
High Performance ◽  
Film Formation ◽  
Substrate Surface ◽  
High Surface ◽  
Thin Film Transistor ◽  
Subthreshold Slope ◽  
Self Assembled Monolayer ◽  
Self Assembled

AbstractHigh performance thin-film transistors (TFT) made of conducting oligomers are obtained when the organic films are well ordered at a molecular level. Highly ordered films are obtained provided that oligomers have a sufficient mobility on the substrate surface during film formation. One possible way to fulfill such a condition is to evaporate oligomers on heated substrates [1,2]. In this work, we suggest that a high surface mobility is obtained by a chemical functionalization of the silicon dioxide surface, and the corresponding improvements of the TFT performances are evidenced. A self-assembled monolayer of octadecyltrichlorosilane (OTS) was deposited on the SiO2 by chemisorption from solution before the evaporation of sexithiophene film. Room temperature current-voltage measurements indicate that the presence of the OTS monolayer improves TFT performances : threshold voltage is decreased, subthreshold slope is decreased, a high current ratio Ion/Ioff is obtained for a reduced gate voltage excursion, the fieldeffect mobility is slightly increased. We have also fabricated and characterized a nanometer scale organic FET (gate length = 50 nm) made of 6T films and only with a self-assembled monolayer as the insulating film between the degenerated silicon substrate (gate) and the conducting channel (no thick SiO2, we call it « oxide-free » organic FET). Performances of this nanometer size organic FETs are the following : subthreshold slope of 0.35V/dec, threshold voltage of −1.3V, effective mobility of 2×10−4 cm2/V.s.

Effect of Chemisorptions on Wetting Property in TiO Nanosheet Film

2012 ◽  
Vol 601 ◽  
pp. 16-20
Author(s):  
Yin Ping Ye ◽  
Wen Du ◽  
Hong Xuan Li ◽  
Li Ji ◽  
Jian Min Chen ◽  
...  
Keyword(s):  
Magnetron Sputtering ◽  
Hydrothermal Method ◽  
Xps Analysis ◽  
Self Assembled Monolayer ◽  
Wetting Property ◽  
Self Assembled

TiO nanosheet films were fabricated by magnetron sputtering and followed with the direct in situ hydrothermal method. Without UV irriadiation, the TiO nanosheet surface showed a wetting property of superhydrophilicity. However, after chemisorptions using a self-assembled monolayer of n-CF3(CF2)7CH2CH2Si(OC2H5)3, the wetting property of the film can be changed from superhydrophilicity to superhydrophobicity. Based on the FESEM, XRD, XPS analysis, the mechanism of the wetting bahavior was proposed.

THE ELECTROCHEMICAL STUDIES ON A SELF-ASSEMBLED VIOLOGEN MONOLAYER USING QUARTZ CRYSTAL MICROBALANCE

2002 ◽  
Vol 01 (05n06) ◽  
pp. 593-596 ◽  
Author(s):  
J. Y. OCK ◽  
H. K. SHIN ◽  
Y. S. KWON ◽  
S. H. SONG ◽  
S. M. CHANG ◽  
...  
Keyword(s):  
Self Assembly ◽  
Quartz Crystal ◽  
Surface Coverage ◽  
Gold Surface ◽  
Frequency Change ◽  
Self Assembled Monolayer ◽  
Solution Interface ◽  
Reversible Redox ◽  
Mass Detector ◽  
Self Assembled

The electrochemical behavior of viologen self-assembled monolayer has been investigated with QCM, which has been known as ng order mass detector. The self-assembly process of viologen was monitored using resonant frequency (ΔF) and resonant resistance (R). The QCM measurements indicated a mass adsorption for viologen assembling on the gold surface with a frequency change of about 300, 135 Hz and its surface coverage (Γ) was calculated to be 5.02 × 10-9 and 1.64 × 10-9 mol/cm2. A reversible redox process was also observed and analyzed with an ionic interaction at the viologen/solution interface using ΔF.

scholarly journals A solvothermal strategy: one-step in situ synthesis of self-assembled 3D graphene-based composites with enhanced lithium storage capacity

2014 ◽  
Vol 2 (24) ◽  
pp. 9200-9207 ◽  
Author(s):  
Jingjing Ma ◽  
Jiulin Wang ◽  
Yu-Shi He ◽  
Xiao-Zhen Liao ◽  
Jun Chen ◽  
...  
Keyword(s):  
Storage Capacity ◽  
Three Dimensional ◽  
In Situ Synthesis ◽  
Li Ion Batteries ◽  
Lithium Storage ◽  
3D Graphene ◽  
One Step ◽  
Li Ion ◽  
Self Assembled

A facile and controllable solvothermal strategy has been developed to synthesize three-dimensional graphene-based monoliths for Li-ion batteries.

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