Encapsulating surface-clean metal nanoparticles inside metal–organic frameworks for enhanced catalysis using a novel γ-ray radiation approach

2018 ◽  
Vol 5 (1) ◽  
pp. 29-38 ◽  
Author(s):  
Zhen Zhang ◽  
Xiaoling Cui ◽  
Wei Yuan ◽  
Qihao Yang ◽  
Huarong Liu ◽  
...  

A facile, efficient and universal γ-radiation strategy has been developed to incorporate surface-clean metal nanoparticles into metal–organic frameworks exhibiting remarkable catalytic activity and stability.


Nanoscale ◽  
2018 ◽  
Vol 10 (35) ◽  
pp. 16425-16430 ◽  
Author(s):  
Yongde Tong ◽  
Guangxin Xue ◽  
Hui Wang ◽  
Mei Liu ◽  
Jin Wang ◽  
...  

Interfacial coupling between ZIFs and noble metal NPs plays a significant role in enhancing catalytic efficiency.



2017 ◽  
Vol 5 (10) ◽  
pp. 4835-4841 ◽  
Author(s):  
Pradip Pachfule ◽  
Xinchun Yang ◽  
Qi-Long Zhu ◽  
Nobuko Tsumori ◽  
Takeyuki Uchida ◽  
...  

High-temperature pyrolysis of Ru nanoparticle-encapsulated MOF (Ru@HKUST-1) afforded ultrafine Cu/Ru nanoparticle-embedded porous carbon composites (Cu/Ru@C), which show high catalytic activity for ammonia borane hydrolysis.





Nanoscale ◽  
2017 ◽  
Vol 9 (43) ◽  
pp. 16645-16651 ◽  
Author(s):  
Guangchao Zheng ◽  
Zhuwen Chen ◽  
Kadir Sentosun ◽  
Ignacio Pérez-Juste ◽  
Sara Bals ◽  
...  

Shape control in metal–organic frameworks still remains a challenge.



2021 ◽  
Author(s):  
Zhanke Wang ◽  
Lei Ge ◽  
Guangxu Zhang ◽  
Rongrong Gao ◽  
Hao Wang ◽  
...  

A novel dissolution-crystallization strategy was developed to synthesize urchin-like superstructure metal-organic frameworks (MOFs) with self-assembled 1D nanorods. The superstructure MOFs not only inherit the high activity of nano-sized MOFs but...



2019 ◽  
Vol 48 (37) ◽  
pp. 13953-13959 ◽  
Author(s):  
Zakary Lionet ◽  
Shun Nishijima ◽  
Tae-Ho Kim ◽  
Yu Horiuchi ◽  
Soo Wohn Lee ◽  
...  

Pyrolysis of metal–organic frameworks (MOFs) to produce metal nanoparticles embedded inside a porous carbon matrix (M@PC) has drawn a lot of attention in recent years.



CrystEngComm ◽  
2017 ◽  
Vol 19 (29) ◽  
pp. 4082-4091 ◽  
Author(s):  
Marek B. Majewski ◽  
Ashlee J. Howarth ◽  
Peng Li ◽  
Michael R. Wasielewski ◽  
Joseph T. Hupp ◽  
...  

Various methods for encapsulating enzymes in metal–organic frameworks are discussed and the catalytic activity of biocomposites prepared using these methods is highlighted.



ChemInform ◽  
2012 ◽  
Vol 43 (43) ◽  
pp. no-no
Author(s):  
Amarajothi Dhakshinamoorthy ◽  
Hermenegildo Garcia


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