An in situ study on the solid state decomposition of ammonia borane: unmitigated by-product suppression by a naturally abundant layered clay mineral

2018 ◽  
Vol 5 (2) ◽  
pp. 301-309 ◽  
Author(s):  
Binayak Roy ◽  
Joydev Manna ◽  
Urbi Pal ◽  
Animesh Hajari ◽  
Ankita Bishnoi ◽  
...  
Keyword(s):  
Thermal Decomposition ◽  
Cost Effectiveness ◽  
Solid State ◽  
Clay Mineral ◽  
Ammonia Borane ◽  
In Situ Study ◽  
Solid State Decomposition ◽  
Layered Clay

Borazine is a by-product often encountered in the thermal decomposition of ammonia borane, which leads to an inescapable hindrance towards sustainability and cost effectiveness.

Thermal decomposition of layered Co-Al hydrotalcite An in situ study

2003 ◽  
pp. 631-638
Author(s):  
J. Pérez-Ramírez ◽  
G. Mul ◽  
J.B. Taboada ◽  
F. Kapteijn ◽  
J.A. Moulijn
Keyword(s):  
Thermal Decomposition ◽  
In Situ Study

In-situ study on thermal decomposition of 1,3-disilabutane to silicon carbide on Si(100) surface

2012 ◽  
Vol 258 (6) ◽  
pp. 2201-2205
Author(s):  
Hae-geun Jee ◽  
Sang-Hun Nam ◽  
Jin-Hyo Boo ◽  
Seong Kyu Kim ◽  
Soon-Bo Lee
Keyword(s):  
Thermal Decomposition ◽  
Silicon Carbide ◽  
In Situ Study

The Effects of Chemical Additives on the Induction Phase in Solid-State Thermal Decomposition of Ammonia Borane

2008 ◽  
Vol 20 (16) ◽  
pp. 5332-5336 ◽  
Author(s):  
David J. Heldebrant ◽  
Abhi Karkamkar ◽  
Nancy J. Hess ◽  
Mark Bowden ◽  
Scot Rassat ◽  
...  
Keyword(s):  
Thermal Decomposition ◽  
Solid State ◽  
Ammonia Borane ◽  
Induction Phase ◽  
Chemical Additives

Thermal decomposition in the solid state

1975 ◽  
Vol 28 (6) ◽  
pp. 1169 ◽  
Author(s):  
W Ng
Keyword(s):  
Thermal Decomposition ◽  
Kinetic Equation ◽  
Solid State ◽  
Conventional Method ◽  
Differential Form ◽  
Kinetic Equations ◽  
Decomposition Kinetics ◽  
Solid State Decomposition ◽  
Decomposition Time ◽  
Decomposition Curve

The foundation of solid state decomposition kinetics is based on the well known theory of nucleation and nucleus growth put forward by Jacobs and Tompkins. It has now been shown that all the kinetic equations thus derived can be represented by a general differential form: ������������������������� dα/dt = kα1-p(1-α)1-q in which α, t and k are respectively the fractional decomposition, time and rate constant; while p and q are parameters lying between zero and unity inclusively. A method has been suggested to find p and q experimentally, thereby enabling one to find the appropriate kinetic form for the chemical decomposition. The conventional method involves the testing of various existing equations to the decomposition data. Different equations are found to fit over different ranges of the decomposition curve so that it is difficult to decide which is the correct kinetic equation for a particular reaction. The present approach however eliminates this complication.

An x-ray cell for in situ study of solid-state transformations

1988 ◽  
Vol 21 (5) ◽  
pp. 495-496 ◽  
Author(s):  
M S W Vong ◽  
P A Sermon ◽  
V A Self ◽  
K Grant ◽  
A J Blackburn
Keyword(s):  
Solid State ◽  
X Ray ◽  
In Situ Study ◽  
Ray Cell

In Situ Multinuclear NMR Spectroscopic Studies of the Thermal Decomposition of Ammonia Borane in Solution

2008 ◽  
Vol 120 (39) ◽  
pp. 7603-7606 ◽  
Author(s):  
Wendy J. Shaw ◽  
John C. Linehan ◽  
Nathaniel K. Szymczak ◽  
David J. Heldebrant ◽  
Clem Yonker ◽  
...  
Keyword(s):  
Thermal Decomposition ◽  
Ammonia Borane ◽  
Spectroscopic Studies ◽  
Multinuclear Nmr

In Situ Multinuclear NMR Spectroscopic Studies of the Thermal Decomposition of Ammonia Borane in Solution

2008 ◽  
Vol 47 (39) ◽  
pp. 7493-7496 ◽  
Author(s):  
Wendy J. Shaw ◽  
John C. Linehan ◽  
Nathaniel K. Szymczak ◽  
David J. Heldebrant ◽  
Clem Yonker ◽  
...  
Keyword(s):  
Thermal Decomposition ◽  
Ammonia Borane ◽  
Spectroscopic Studies ◽  
Multinuclear Nmr
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