Layered Clay–Graphene Oxide Nanohybrids for the Reinforcement and Fire-Retardant Properties of Polyurea Matrix

Nanostructures are more and more evolved through extensive research on their functionalities; thus, the aim of this study was to obtain layered clay–graphene oxide nanohybrids with application as reinforcing agents in polyurea nanocomposites with enhanced thermal–mechanical and fire-retardant properties. Montmorillonite (MMT) was combined with graphene oxide (GO) and amine functionalized graphene oxide (GOD) through a new cation exchange method; the complex nanostructures were analyzed through FTIR and XPS to assess ionic interactions between clay layers and GO sheets by C1s deconvolution and specific C sp3, respective/ly, C-O secondary peaks appearance. The thermal decomposition of nanohybrids showed a great influence of MMT layers in TGA, while the XRD patterns highlighted mutual MMT and GO sheets crystalline-structure disruption by the d (002) shift 2θ = 6.29° to lower values. Furthermore, the nanohybrids were embedded in the polyurea matrix, and the thermo-mechanical analysis gave information about the stiffness of MMT–GO nanocomposites, while GOD insertion within the MMT layers resulted in a 30 °C improvement in the Tg of hard domains, as shown in the DSC study. The micro CT analysis show good dispersion of inorganic structures within the polyurea, while the SEM fracture images revealed smooth surfaces. Cone calorimetry was used to evaluate fire-retardant properties through limiting the oxygen index, and MMT–GOD based nanocomposites showed a 35.4% value.

X-ray Photoelectron Spectroscopic Study of Some Organic and Inorganic Modified Clay Minerals

Layered clay systems intercalated with inorganic and organic compounds were analyzed to highlight how XPS can provide information on the different environments surrounding a particular atom as well as provide discernments on the size, coordination, and structural and oxidative transformations of the intercalating/pillaring compounds. XPS data on the intercalation of urea and K-acetate in low- and high-defect kaolinite revealed the interaction of the intercalating group NH2 with the siloxane functional groups in the interlayer surface. The intercalation of HDTMA in Mt demonstrated the use of XPS in monitoring the change in conformation assumed by alkylammonium intercalating compounds in Mt with increasing CEC. Studies on the pillaring of Mt by Al13 and Ga13 by XPS allowed determination of the coordination of the pillaring compound within the Mt layer. Lastly, the intercalation of hexacyanoferrate in hydrotalcite demonstrated the capability of XPS in following changes in the oxidation state of the iron compound. These were gleaned from interpretation of the shifts in binding energies and presence of multiplet splitting in the XPS of the component elements of the minerals or the intercalating compounds.

Geotechnical ULS design issues of bridge shallow foundations

Some important issues referring to the Ultimate Limit States of geotechnical design of bridge shallow foundations are discussed using results of 2D and 3D FE analyses, as follows: (a) The effects of highly eccentric and inclined loadings on the bearing capacity of footings on cohesionless soils, (b) the effects of soil inhomogeneity in the special case of 2-layered clay, (c) the scour effects in case of abutment and piers in riverbed, from the geotechnical point of view.

Modified Layered Silicas as Catalysts for Conversion of Nitrogen Pollutants in Flue Gases—A Review

This paper is focused on the recent achievements in the studies of modified layered zeolites and cationic layered clay minerals. These materials are very promising catalysts in green chemistry processes, such as selective catalytic reduction of NOx with ammonia (NH3-SCR) and selective catalytic oxidation of ammonia to dinitrogen (NH3-SCO). Special attention is paid to the roles of the micro- and mesoporous structures of the catalytic materials, the type and location of deposited transition metals, as well as surface acidity in the design of effective catalysts for the NH3-SCR and NH3-SCO processes. The majority of the presented analysis is based on the authors’ research.

Bearing Capacity Factor of Circular Footings on Two-layered Clay Soils

Geotechnical engineers often deal with layered foundation soils. In this case, the soil bearing capacity assessment using the conventional bearing capacity theory based on the upper layer properties introduces significant inaccuracies if the top layer thickness is comparable to the rigid footing width placed on the soil surface. Under undrained conditions the cohesion increases almost linearly with depth. A few theoretical studies have been proposed in the literature in order to incorporate the cohesion variation with depth in the computation of the ultimate bearing capacity of the strip and circular footings. Rigorous solutions to the problem of circular footings resting on layered clays with linear increase of cohesion do not appear to exist. In this paper, numerical computations using FLAC code are carried out to assess the vertical bearing capacity beneath rough rigid circular footing resting on two-layered clays of both homogeneous and linearly increasing shear strength profiles. The bearing capacity calculation results which depend on the top layer thickness, the two-layered clays strength ratio and the cohesion increase rates with depth are presented in both tables and graphs, and compared with previously published results available in the literature. The critical depth for circular footing is found significantly less than for strip footing. Doi: 10.28991/cej-2021-03091689 Full Text: PDF