scholarly journals Single-phase white-emitting phosphors Ba3Ce(1−x−y)(PO4)3:xTb3+,yMn2+ and Ba3Ce(1−x−z)(PO4)3:xTb3+,zSm3+: structure, luminescence, energy transfer and thermal stability

RSC Advances ◽  
2017 ◽  
Vol 7 (32) ◽  
pp. 19584-19592 ◽  
Author(s):  
Shuchao Xu ◽  
Zhijun Wang ◽  
Panlai Li ◽  
Ting Li ◽  
Qiongyu Bai ◽  
...  

A series of Ba3Ce(1−x−y)(PO4)3:xTb3+,yMn2+ and Ba3Ce(1−x−z)(PO4)3:xTb3+,zSm3+ phosphors were synthesized by a high temperature solid-state reaction.

2013 ◽  
Vol 683 ◽  
pp. 199-202 ◽  
Author(s):  
Jia Yue Sun ◽  
Dian Peng Cui ◽  
Bing Xue ◽  
Guang Chao Sun ◽  
Hai Yan Du

A series of single-phase Sr5(PO4)3F: Eu2+, Tb3+, Na+ phosphors have been synthesized by high temperature solid-state reaction. The photoluminescence excitation and emission spectra, concentration effect and energy transfer from Eu2+ to Tb3+ are investigated in detail. The work shows that there is an effective energy transfer from Eu2+ to Tb3+, where Eu2+ reveals an intense excitation band from 280 nm to 400 nm, matching well with the emission of n-UV chips, and Tb3+ emits an intense green emitting light.


RSC Advances ◽  
2019 ◽  
Vol 9 (52) ◽  
pp. 30406-30418 ◽  
Author(s):  
Yun Chen ◽  
Wenge Ding ◽  
Panlai Li ◽  
Xue Li ◽  
Qi Bao ◽  
...  

A series of Ce3+/Tb3+, Tb3+/Mn2+ and Ce3+/Tb3+/Mn2+ doped Ba3Y(PO4)3 were synthesized by the high temperature solid state method.


2021 ◽  
Author(s):  
Jing Yan ◽  
Chunyan Jiang ◽  
Yulun Xian ◽  
Jianbang Zhou ◽  
Hong Li ◽  
...  

A series of Tb3+- and Eu3+-doped Ca8ZnLu(PO4)7 (CZLP:Tb3+ and CZLP:Eu3+) as well as Ca8ZnTb(PO4)7:Eu3+ (CZTP:Eu3+) phosphors have been prepared via the traditional high-temperature solid-state reaction. X-ray powder diffraction (XRD) patterns...


RSC Advances ◽  
2017 ◽  
Vol 7 (25) ◽  
pp. 14974-14980 ◽  
Author(s):  
J. Llanos ◽  
D. Espinoza ◽  
R. Castillo

Inorganic phosphors based on monoclinic Y2WO6 doped with Eu3+ ions were prepared via conventional solid-state reactions at high temperature.


2012 ◽  
Vol 182-183 ◽  
pp. 122-125
Author(s):  
Li Li Wang ◽  
Xiu Feng Wang ◽  
Cheng Long Yu ◽  
Hong Tao Jiang

Hydroxyapatite (HA) was synthesized in presence of 20wt% m-ZrO2by solid state reaction between tricalcium phosphate(TCP) and Ca(OH)2at 1000 °C for 2h. Similarily, Fluorine hydroxyapatite(FA) was synthesized using tricalcium phosphate and calcium fluoride as raw materials at 1000 °Cfor 3h. The as-prepared HA was mixed with 10%,25%,45%,55%,70wt% FA and the mixture was sintered at 1000°C-1400°C for 2h. The main phase and bulk density was measured. The results show that when the relative amount of FA to HA increased, the decomposition of the composite is decreased gradually because of the formation of thermally stable FHA solid solutions. Low temperature would effect the exchange of ionic between FA and HA,while high temperature would impact synthesis of composites, because high temperature would lead to dissolution of HA ,which has to react with FA. Increase the content of HA would be advantage for synthesis FHA-ZrO2composite.


2015 ◽  
Vol 3 (35) ◽  
pp. 9112-9121 ◽  
Author(s):  
Shuchao Xu ◽  
Panlai Li ◽  
Zhijun Wang ◽  
Ting Li ◽  
Qiongyu Bai ◽  
...  

A series of LiBaBO3:RE (RE = Eu2+/Tb3+/Eu3+) phosphors have been synthesized using the high-temperature solid-state reaction method.


RSC Advances ◽  
2017 ◽  
Vol 7 (25) ◽  
pp. 15222-15227 ◽  
Author(s):  
Baoxing Wang ◽  
Qiang Ren ◽  
Ou Hai ◽  
Xiulan Wu

The Ba2P2O7:Tb3+, Eu3+ phosphors were synthesized by a high temperature solid-state reaction method in air atmosphere and their crystal structures, lifetime, luminescence properties, and energy transfer mechanism were investigated in detail.


2014 ◽  
Vol 633-634 ◽  
pp. 306-309 ◽  
Author(s):  
Jia Yue Sun ◽  
Liu Han ◽  
Qiu Mei Di ◽  
Qi Guang Xu

Novel Na3YSi2O7: Sm3+, Eu3+phosphors for white light-emitting diodes were prepared by high-temperature solid-state reaction. The photoluminescence excitation and emission spectra, energy transfer from Eu2+to Tb3+are investigated in detail. The current research suggests that Na3YSi2O7: Sm3+, Eu3+phosphor is a potential candidate for application in Phosphor-converted LEDs.


1992 ◽  
Vol 280 ◽  
Author(s):  
Y. W. Kim ◽  
I. K. Kim ◽  
N. I. Lee ◽  
J. W. Ko ◽  
S. T. Ahn ◽  
...  

ABSTRACTThe effect of the crystallographic orientation of underlying poly-Si film on the thermal stability of the TiSi2 film was studied. Different preferred orientations of the poly-Si film were obtained by annealing poly-Si or amorphous Si films at various temperatures. The TiSi2 film was formed by the solid-state reaction of the Ti film sputtered on the poly-Si film. The thermal stability of the TiSi2 film was evaluated by changes in the sheet resistance and microstructural evolution during furnace anneals. The TiSi2 film on poly-Si with the <110> preferred orientation shows more stable conductivity during high temperature anneals than with the <111> orientation. The surface energy of underlying poly-Si is expected to influence the thermal stability of the TiSi2/poly-Si structure significantly. Better thermal stability of the TiSi2 film can be obtained by the higher surface energy of underlying poly-Si.


2015 ◽  
Vol 3 (44) ◽  
pp. 11618-11628 ◽  
Author(s):  
Kai Li ◽  
Mengjiao Xu ◽  
Jian Fan ◽  
Mengmeng Shang ◽  
Hongzhou Lian ◽  
...  

A series of green-yellowish-orange-emitting Eu2+,Mn2+-doped Na3LuSi2O7 (NLSO) phosphors, synthesized via the high-temperature solid state reaction process, have been investigated in detail.


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