Luminescence Properties and Energy Transfer from Eu2+ to Tb3+ in Sr5(PO4)3F Phosphor

2013 ◽  
Vol 683 ◽  
pp. 199-202 ◽  
Author(s):  
Jia Yue Sun ◽  
Dian Peng Cui ◽  
Bing Xue ◽  
Guang Chao Sun ◽  
Hai Yan Du

A series of single-phase Sr5(PO4)3F: Eu2+, Tb3+, Na+ phosphors have been synthesized by high temperature solid-state reaction. The photoluminescence excitation and emission spectra, concentration effect and energy transfer from Eu2+ to Tb3+ are investigated in detail. The work shows that there is an effective energy transfer from Eu2+ to Tb3+, where Eu2+ reveals an intense excitation band from 280 nm to 400 nm, matching well with the emission of n-UV chips, and Tb3+ emits an intense green emitting light.

2014 ◽  
Vol 633-634 ◽  
pp. 306-309 ◽  
Author(s):  
Jia Yue Sun ◽  
Liu Han ◽  
Qiu Mei Di ◽  
Qi Guang Xu

Novel Na3YSi2O7: Sm3+, Eu3+phosphors for white light-emitting diodes were prepared by high-temperature solid-state reaction. The photoluminescence excitation and emission spectra, energy transfer from Eu2+to Tb3+are investigated in detail. The current research suggests that Na3YSi2O7: Sm3+, Eu3+phosphor is a potential candidate for application in Phosphor-converted LEDs.


RSC Advances ◽  
2017 ◽  
Vol 7 (32) ◽  
pp. 19584-19592 ◽  
Author(s):  
Shuchao Xu ◽  
Zhijun Wang ◽  
Panlai Li ◽  
Ting Li ◽  
Qiongyu Bai ◽  
...  

A series of Ba3Ce(1−x−y)(PO4)3:xTb3+,yMn2+ and Ba3Ce(1−x−z)(PO4)3:xTb3+,zSm3+ phosphors were synthesized by a high temperature solid-state reaction.


2014 ◽  
Vol 700 ◽  
pp. 113-116
Author(s):  
Yu Jie Chen ◽  
Feng Lan Han ◽  
Zhao Luo

Na2BaMgP2O8phosphors were synthesized by a standard solid state reaction and their luminescent properties were investigated. The phase structure was analyzed by X-ray powder diffraction measurement. Under the excitation of 365nm, Na2BaMgP2O8:Tb3+, Eu3+phosphors show two color bands of green and red color due to5D4−7F5transition of Tb3+ions and5D0−7F2transition of Eu3+ions, respectively. The emission intensity of Tb3+deceased with the increasing concentration of Eu3+, which verified that an effective energy transfer occurred from Tb3+to Eu3+in Na2BaMgP2O8host. The present study indicated that the phosphors have a high potential application in solid state lighting.


RSC Advances ◽  
2017 ◽  
Vol 7 (25) ◽  
pp. 14974-14980 ◽  
Author(s):  
J. Llanos ◽  
D. Espinoza ◽  
R. Castillo

Inorganic phosphors based on monoclinic Y2WO6 doped with Eu3+ ions were prepared via conventional solid-state reactions at high temperature.


2013 ◽  
Vol 401-403 ◽  
pp. 796-799 ◽  
Author(s):  
Jia Yue Sun ◽  
Dian Peng Cui ◽  
Bing Xue ◽  
Guang Chao Sun

Single-phase Ba5(PO4)3Cl:Ce3+,Tb3+ (BPCl:Ce3+,Tb3+) samples have been synthesized via solid-state reaction method. The phase structure and luminescence properties are characterized using powder X-ray diffraction (XRD), photoluminescence excitation and emission spectra. Effective energy transfer occurs from Ce3+ to Tb3+ due to the observed spectral overlap between the emission band of Ce3+ and the excitation band of Tb3+. Ce3+/Tb3+-codoped Ba5(PO4)3Cl shows more intense yellowish-green light compared to that of Tb3+-doped sample under UV light excitation.


2015 ◽  
Vol 3 (35) ◽  
pp. 9112-9121 ◽  
Author(s):  
Shuchao Xu ◽  
Panlai Li ◽  
Zhijun Wang ◽  
Ting Li ◽  
Qiongyu Bai ◽  
...  

A series of LiBaBO3:RE (RE = Eu2+/Tb3+/Eu3+) phosphors have been synthesized using the high-temperature solid-state reaction method.


RSC Advances ◽  
2017 ◽  
Vol 7 (25) ◽  
pp. 15222-15227 ◽  
Author(s):  
Baoxing Wang ◽  
Qiang Ren ◽  
Ou Hai ◽  
Xiulan Wu

The Ba2P2O7:Tb3+, Eu3+ phosphors were synthesized by a high temperature solid-state reaction method in air atmosphere and their crystal structures, lifetime, luminescence properties, and energy transfer mechanism were investigated in detail.


2015 ◽  
Vol 3 (44) ◽  
pp. 11618-11628 ◽  
Author(s):  
Kai Li ◽  
Mengjiao Xu ◽  
Jian Fan ◽  
Mengmeng Shang ◽  
Hongzhou Lian ◽  
...  

A series of green-yellowish-orange-emitting Eu2+,Mn2+-doped Na3LuSi2O7 (NLSO) phosphors, synthesized via the high-temperature solid state reaction process, have been investigated in detail.


2021 ◽  
Author(s):  
yonghua wu ◽  
Fugui Yang ◽  
Fengpo Yan ◽  
Ruijuan Zuo

Abstract The Dy3+, Mn4+: NaLaMgWO6 phosphors are synthesized successfully using the technique of solid-state reaction at 1150 ℃. The XRD and SEM-EDS are measured to analyze the phase purity. The concentrations of Dy3+, Mn4+, Mg2+, Na+, La3+ and W6+ are measured by ICP. The absorption and excited spectra are presented, which indicate the 390 nm is suitable for the tunable yellow-red light excitation. Using the 390 nm LED as the excitation source, the emission spectra with different doped concentrations ratios of Dy3+to Mn4+ are obtained, which shows good tunable yellow-red emission performance.


2013 ◽  
Vol 683 ◽  
pp. 172-175 ◽  
Author(s):  
Jia Yue Sun ◽  
Yi Ning Sun ◽  
Jun Hui Zeng ◽  
Ji Cheng Zhu ◽  
Hai Yan Du

A near Infrared (NIR) quantum cutting (QC) Sr3AlO4F:Tb3+,Yb3+phosphor was synthesized by the conventional high temperature solid-state reaction. The luminescence spectra both in visible (VIS) and NIR regions and decay lifetime curves of Tb3+have been measured to prove energy transfer (ET) from Tb3+to Yb3+. Quantum efficiency (QE) related to Yb3+concentration was calculated and the highest QE was found to be 135% hen Yb3+doped concentration at 20%. The present Tb3+and Yb3+co-doped Sr3AlO4F phosphor may be a promising candidate to modify the spectral of the solar light.


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