Nanopore-induced host–guest charge transfer phenomena in a metal–organic framework
Keyword(s):
A Charge
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Using the “crystal sponge” approach, weak organic electron donor molecules were impregnated and evenly distributed in a crystal of a metal–organic framework (MOF), with the self-assembly of the donor–acceptor pairs with electron acceptor ligands. The nanopores of the MOF confined them and induced a charge transfer phenomenon, which would not occur between donor and acceptor molecules in a bulk scale.
2014 ◽
Vol 2
(10)
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pp. 3389-3398
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2018 ◽
Vol 20
(40)
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pp. 25772-25779
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2020 ◽
Vol 124
(39)
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pp. 21635-21640
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