Electrochromic tuning of transparent gold nanorods with poly[(3,4-propylenedioxy)pyrrole] shells in the near-infrared region

2017 ◽  
Vol 5 (47) ◽  
pp. 12571-12584 ◽  
Author(s):  
Jing Zhou ◽  
Ju-Won Jeon ◽  
James F. Ponder ◽  
Jeffrey A. Geldmeier ◽  
Mahmoud A. Mahmoud ◽  
...  
Keyword(s):  
Gold Nanorods ◽  
Near Infrared ◽  
Infrared Region ◽  
Absorption Bands ◽  
Nir Absorption ◽  
Near Infrared Region

An electrochemically tunable plasmonic system with narrow visible-NIR absorption bands was designed by synthesizing poly[(3,4-propylenedioxy)pyrrole] nanoshells onto a AuNR core.

Spectrophotometry of Human Hemoglobin in the near Infrared Region from 1000 to 2500 nm

1994 ◽  
Vol 2 (2) ◽  
pp. 59-65 ◽  
Author(s):  
J. Todd Kuenstner ◽  
Karl H. Norris
Keyword(s):  
Near Infrared ◽  
Infrared Region ◽  
Second Derivative ◽  
Human Hemoglobin ◽  
Absorption Bands ◽  
Near Infrared Region ◽  
Absorbance Spectra

Absorbance and first and second derivative absorbance spectra and quarter-millimolar absorptivity coefficients for hemoglobin species including oxy-, deoxy-, carboxy- and methemoglobin in the visible and in the near infrared regions from 620 nm to 2500 nm are presented. At wavelengths longer than 1500 nm, the absorbance and second derivative absorbance spectra of hemoglobin species are similar for all of the species. Absorption bands are present centred at 1690, 1740, 2056, 2170, 2290 and 2350 nm.

Chiral carbazole-based porphyrins showing absorption and circular dichroism in the near-infrared region

2020 ◽  
Vol 24 (01n03) ◽  
pp. 247-251
Author(s):  
Chihiro Maeda ◽  
Tadashi Ema
Keyword(s):  
Circular Dichroism ◽  
Near Infrared ◽  
Infrared Region ◽  
Nir Absorption ◽  
Near Infrared Region ◽  
Induced Aggregation ◽  
First Time ◽  
Circular Dichroïsm

Chiral carbazole-based porphyrins were synthesized for the first time via the incorporation of hydrobenzoin units at the thiophene moieties. They showed absorption and circular dichroism in the near-infrared (NIR) region. The NIR absorption was further red-shifted by solvent-induced aggregation.

Surface Plasmon Resonance with Electrospun Nanofibers on Gold Surface

2009 ◽  
Vol 1173 ◽  
Author(s):  
Kazuma Tsuboi ◽  
Hidetoshi Matsumoto ◽  
Mie Minagawa ◽  
Akihiko Tanioka
Keyword(s):  
Surface Plasmon ◽  
Near Infrared ◽  
Polarized Light ◽  
Electrospun Nanofibers ◽  
Gold Surface ◽  
Infrared Region ◽  
Peak Wavelength ◽  
Absorption Bands ◽  
Propagation Length ◽  
Near Infrared Region

AbstractIn this paper we report new excitation method of surface plasmon polariton (SPP) at air/gold interface with electrospun nanofibers. Nanofibers of polyvinylpirrolidone were electrospun onto the surface of a gold film. The observations by scanning electron microscopy and optical microscopy indicated that the average diameters of the nanofibers were about 300 nm and average sizes of pores were about 30-40 μm. Optical response of the nanofibers on gold surface was investigated by polarized reflection absorption spectroscopy (RAS). The RAS spectrum with p-polarized light showed two absorption bands while the spectrum with s-polarized light only one band. One is a band at about 520 nm that also found in the spectrum with s-polarized light. Another is a broad band in the near-infrared region which found only with p-polarized light. The peak intensity of the latter band increases with increase of incident angle of the polarized light and the peak wavelength of the band shifted to longer wavelength. These responses suggested that SPP at air/gold interface was excited with the scattering light from the electrospun nanofibers. We also found that the peak wavelength of the absorption band in near-infrared region changed with the increase of the amount of the nanofibers. This may be due to the fact that the sizes of the pores on gold surface became smaller than the propagation length of SPP, which resulted in scattering and interference of SPP.

Photothermal therapy of acute leukemia cells in the near-infrared region using gold nanorods CD-33 conjugates

2011 ◽  
Author(s):  
Anton Liopo ◽  
André Conjusteau ◽  
Marina Konopleva ◽  
Michael Andreeff ◽  
Alexander Oraevsky
Keyword(s):  
Acute Leukemia ◽  
Gold Nanorods ◽  
Photothermal Therapy ◽  
Near Infrared ◽  
Infrared Region ◽  
Leukemia Cells ◽  
Near Infrared Region

Near infrared spectra of some cobalt(II) compounds

1968 ◽  
Vol 21 (7) ◽  
pp. 1775
Author(s):  
DP Graddon ◽  
GM Mockler
Keyword(s):  
Absorption Band ◽  
Absorption Spectra ◽  
Metal Atom ◽  
Infrared Spectra ◽  
Near Infrared ◽  
Infrared Region ◽  
Absorption Bands ◽  
Heterocyclic Base ◽  
Near Infrared Spectra ◽  
Near Infrared Region

Absorption spectra of compounds CoX2B2 and CoX2B4 (X = Cl, Br, I, or NCS; B = a heterocyclic base) have been obtained by reflectance and in solution in the near infrared region between 1000 and 2000 mμ. The spectra are characteristic of the stereochemistry of the metal atom: octahedral compounds have a single absorption band near 1100 mμ, e < 10; tetrahedral compounds have three overlapping absorption bands near 1100,1400, and 1700 mp, 30 < < 150. Comparisons are made with previously observed spectra of octahedral and tetrahedral species of the types CoL2+6 and CoX2-4.

scholarly journals Near-infrared laser-mediated drug release and antibacterial activity of gold nanorod–sputtered titania nanotubes

2018 ◽  
Vol 9 ◽  
pp. 204173141879031 ◽  
Author(s):  
Kyoung-Suk Moon ◽  
Young-Bum Park ◽  
Ji-Myung Bae ◽  
Seunghan Oh
Keyword(s):  
Electron Microscopy ◽  
Laser Irradiation ◽  
Gold Nanorods ◽  
Near Infrared ◽  
Infrared Region ◽  
Infrared Laser ◽  
Gold Nanorod ◽  
Titania Nanotubes ◽  
Infrared Laser Irradiation ◽  
Near Infrared Region

The infection control of implants is one of the hot issues in the field of medicine and dentistry. In this study, we prepared gold nanorod–sputtered titania nanotubes on titanium surface, which is the main component of implant material, and aimed to estimate the remote-controlled tetracycline release and resulting antibacterial effects of gold nanorod–sputtered titania nanotubes using near-infrared laser irradiation. Gold nanorods prepared by ion plasma sputtering (aspect ratio = 1:3) showed optical properties like those of chemically synthesized gold nanorods, exhibiting photothermal effects in the near-infrared region, as demonstrated using field-emission scanning electron microscopy, transmission electron microscopy, and diffuse ultraviolet–visible–near-infrared spectrophotometry. In addition, a 2 wt% tetracycline/polycaprolactone mixture was found to be the most suitable experimental group to demonstrate the biological compatibilities and antibacterial activities. The results of antibacterial agar diffusion tests and near-infrared-mediated tetracycline release tests in vivo confirmed that remote-controlled tetracycline elution using near-infrared laser irradiation was highly effective. Therefore, gold nanorod–sputtered titania nanotubes would be expected to enable the continued use of the photothermal therapy of gold nanorods and extend the limited use of titania showing photocatalytic activity only within the ultraviolet-to-near-infrared region.

Harmonic and Anharmonic Oscillator Models for Pure Vibrational Infrared Spectroscopy of Diatomic Molecules

2021 ◽  
Vol 8 (1) ◽  
Author(s):  
Rohit Singh
Keyword(s):  
Infrared Spectroscopy ◽  
Harmonic Oscillator ◽  
Absorption Spectra ◽  
Near Infrared ◽  
Anharmonic Oscillator ◽  
Diatomic Molecules ◽  
Infrared Region ◽  
Molecular Vibration ◽  
Absorption Bands ◽  
Near Infrared Region

In molecular vibrational infrared spectroscopy, absorption spectra arise from molecular vibration and correspond to transitions between the vibrational energy levels associated with a given electronic state of the molecule. The vibrational transitions, which fall in the near infrared region, are induced through the interaction of the molecular electric dipole with the electric vector of the electromagnetic radiation. The near infrared region extends roughly from 1?m to ?10?^2 ?m. The article explains the pure vibrational absorption spectra of diatomic molecules such as HCl, HBr, HI, CO, … etc. In order to explain the vibrational spectra, diatomic molecules are treated as harmonic oscillator and anharmonic oscillator. In the harmonic oscillator model, we get only one absorption band at the wavenumber value? ?_osc corresponding to frequency of oscillation?_osc while in the actual experimental data, there are many absorption bands corresponding to wave numbers slightly lesser than ? ?_osc, 2? ?_osc, 3? ?_osc, ……..The occurrence of these additional bandsis attributed to the selection rule ?v=±2, ±3, ±4, ……The additional bands are having lesser intensity and are called overtone bands.

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