Boehmite nanoparticles with different functional properties for manufacturing products with specified parameters

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Taurine-Modified Boehmite Nanoparticles for GFRP Wind Turbine Rotor Blade Fatigue Life Enhancement

Advanced nanoparticle-reinforced glass fibre composites represent a promising approach to improving the service life of fatigue-loaded structures such as wind turbine rotor blades. However, processing particle-reinforced resins using advanced infusion techniques is problematic due to, for example, higher viscosity as well as filtering effects. In this work, the effects of boehmite nanoparticles on viscosity, static properties and fatigue life are investigated experimentally. Whereas rheological analysis reveals a significant increase of viscosity in the case of pristine boehmite particles, an additional taurine surface modification of the particles can effectively reduce viscosity increase. As regards mechanical properties, significant improvements of both static as well as fatigue properties are found. The addition of 15 wt.% of boehmite particles increases fatigue life by a maximum of 270% compared to the unmodified fibre-reinforced epoxy. Transmitted light-based investigation of the damage mechanisms shows delayed initiation and smaller growth rates for laminates containing boehmite particles. At the same time, the observed mechanisms and their accumulation along the relative cycle number do not change significantly. In addition, by characterising autonomous heating, the so-called Risitano fatigue limit is determined. The results reveal that with increasing particle content there is an increase in the fatigue limit.

A review of current knowledge and future trends in polymer/boehmite nanocomposites

Boehmite [bey-mahyt] is a unique aluminum oxide hydroxide nanostructure. It consists of nanosheets of octahedral aluminum ions with surface hydroxyl groups. Owing to exceptional reinforcing behavior, boehmite nanoparticles have gained immense attention as polymeric nanofillers. Essential matrices used with the boehmite based nanocomposites include poly(methyl methacrylate), polyethylene, polypropylene, polyamide, epoxy, and other polymers. In this review, all-inclusive considerations on the design, morphology, mechanical, thermal, electrical, ion conducting, flame retardancy, electrochemical, and other physical properties, and advances related to the polymer/boehmite nanocomposites are presented. The polymer/boehmite nanocomposites have been employed for the membranes (water filtration/dye removal), coatings (anti-corrosion/self-healing), Li-ion batteries, and non-flammability purposes.

Carrier Fibers for the Safe Dosage of Nanoparticles in Nanocomposites: Nanomechanical and Thermomechanical Study on Polycarbonate/Boehmite Electrospun Fibers Embedded in Epoxy Resin

The reinforcing effect of boehmite nanoparticles (BNP) in epoxy resins for fiber composite lightweight construction is related to the formation of a soft but bound interphase between filler and polymer. The interphase is able to dissipate crack propagation energy and consequently increases the fracture toughness of the epoxy resin. Usually, the nanoparticles are dispersed in the resin and then mixed with the hardener to form an applicable mixture to impregnate the fibers. If one wishes to locally increase the fracture toughness at particularly stressed positions of the fiber-reinforced polymer composites (FRPC), this could be done by spraying nanoparticles from a suspension. However, this would entail high costs for removing the nanoparticles from the ambient air. We propose that a fiber fleece containing bound nanoparticles be inserted at exposed locations. For the present proof-of-concept study, an electrospun polycarbonate nonwoven and taurine modified BNP are proposed. After fabrication of suitable PC/EP/BNP composites, the thermomechanical properties were tested by dynamic mechanical analysis (DMA). Comparatively, the local nanomechanical properties such as stiffness and elastic modulus were determined by atomic force microscopy (AFM). An additional investigation of the distribution of the nanoparticles in the epoxy matrix, which is a prerequisite for an effective nanocomposite, is carried out by scanning electron microscopy in transmission mode (TSEM). From the results it can be concluded that the concept of carrier fibers for nanoparticles is viable.

Viscosity Model for Nanoparticulate Suspensions Based on Surface Interactions

In this paper, a widely mechanistic model was developed to depict the rheological behaviour of nanoparticulate suspensions with solids contents up to 20 wt.%, based on the increase in shear stress caused by surface interaction forces among particles. The rheological behaviour is connected to drag forces arising from an altered particle movement with respect to the surrounding fluid. In order to represent this relationship and to model the viscosity, a hybrid modelling approach was followed, in which mechanistic relationships were paired with heuristic expressions. A genetic algorithm was utilized during model development, by enabling the algorithm to choose among several hard-to-assess model options. By the combination of the newly developed model with existing models for the various physical phenomena affecting viscosity, it can be applied to model the viscosity over a broad range of solids contents, shear rates, temperatures and particle sizes. Due to its mechanistic nature, the model even allows an extrapolation beyond the limits of the data points used for calibration, allowing a prediction of the viscosity in this area. Only two parameters are required for this purpose. Experimental data of an epoxy resin filled with boehmite nanoparticles were used for calibration and comparison with modelled values.

Carrier Fibers for the Safe Dosage of Nanoparticles in Nanocomposites: Nanomechanical and Thermomechanical Study on Polycarbonate/Boehmite Electrospun Fibers Embedded in Epoxy Resin

The reinforcing effect of boehmite nanoparticles (BNP) in epoxy resins for fiber composite lightweight construction is related to the formation of a soft but bound interphase between filler and polymer. The interphase is able to dissipate crack propagation energy and consequently increases the fracture toughness of the epoxy resin. Usually, the nanoparticles are dispersed in the resin and then mixed with the hardener to form an applicable mixture to impregnate the fibers. If one wishes to locally increase the fracture toughness at particularly stressed positions of the fiber-reinforced polymer composites (FRPC), this could be done by spraying nanoparticles from a suspension. However, this would entail high costs for removing the nanoparticles from the ambient air. We propose that a fiber fleece containing bound nanoparticles be inserted at exposed locations. For the present proof-of-concept study, an electrospun polycarbonate nonwoven and taurine modified BNP are proposed. After fabrication of suitable PC/EP/BNP composites, the thermomechanical properties were tested by dynamic mechanical analysis (DMTA). Comparatively, the local nano-mechanical properties such as stiffness and elastic modulus were determined by atomic force microscopy (AFM). An additional investigation of the distribution of the nanoparticles in the epoxy matrix, which is a prerequisite for an effective nanocomposite, is carried out by scanning electron microscopy in transmission mode (TSEM). From the results it can be concluded that the concept of carrier fibers for nanoparticles is viable.