Naphthalene containing amino-ether macrocycle based Cu(ii) templated [2]pseudorotaxanes and OFF/ON fluorescence switching via axle substitution

2018 ◽  
Vol 47 (38) ◽  
pp. 13408-13418 ◽  
Author(s):  
Somnath Bej ◽  
Pradyut Ghosh

A newly synthesized naphthalene containing macrocycle is employed towards the development of Cu(ii) templated [2]pseudorotaxanes. Furthermore, a fluorophoric axle threaded [2]pseudorotaxane is explored as an “OFF/ON” fluorescence switch through the axle substitution.

2015 ◽  
Vol 17 (32) ◽  
pp. 20725-20732 ◽  
Author(s):  
Sagar Satpathi ◽  
Krishna Gavvala ◽  
Partha Hazra

Conversion from iminium to alkanolamine form of Sanguinarine, a key member of benzylisoquinoline alkaloid family, is monitored in micellar environments by fluorescence switch.


2018 ◽  
Vol 6 (8) ◽  
pp. 2113-2122 ◽  
Author(s):  
Qi Yu ◽  
Xing Su ◽  
Ting Zhang ◽  
Yu-Mo Zhang ◽  
Minjie Li ◽  
...  

High-contrast fluorescence switching has been achieved in polymer films or fibers with non-invasive stimuli.


2011 ◽  
Vol 295-297 ◽  
pp. 1070-1073
Author(s):  
Hong Liang Liu ◽  
Gang Liu ◽  
Shi Qiang Cui ◽  
Wei Jun Liu

A novel photochromic diarylethene based on isoxazole moiety was synthesized and its photochromic and fluorescent properties were also investigated. This compound exhibited reversible photochromism, changing from colorless to red after irradiation with UV light both in solution and in poly-methyl methacrylate (PMMA) amorphous film. Also, it exhibited remarkable fluorescence switching in the solid state. The results showed that the diarylethene exhibited a relatively strong fluorescence switch along with the photochromism from open-ring isomer to closed-ring isomer. Using this dithienylethene 1c as optical storage was performed successfully.


2014 ◽  
Vol 886 ◽  
pp. 151-154
Author(s):  
Hong Jing Jia ◽  
Xu Gang Tang ◽  
Shou Zhi Pu

A novel unsymmetrical photochromic diarylethene 1o, which is named [1-(2-Methyl-5-pheyl-3-thienyl)-2-(2-methyl-5-(4-cyanophenyl)-3-thienyperfluorocyclopentene, was synthesized and its structure authenticated. What is more, photochromic, kinetics and fluorescence properties of the diarylethene were investigated in detail. The result indicated that this diarylethene photochromism could be controlled by UV-Vis light, changing the color from colorless to blue in hexane solution upon appropriate irradiation with 297 nm light, respectively. Its In the meantime, the kinetic experiments illustrated that the cyclization/cycloreversion process of this compound was determined to be the zeroth/first reaction. In addition, the fluorescence intensity of diarylethene decreased dramatically from open-ring isomer to closed-ring isomer. The fluorescence switching property can be potential use for optical data storage.


2020 ◽  
Vol 5 (8) ◽  
pp. 1428-1436
Author(s):  
Anu Saini ◽  
Manpreet Kaur ◽  
Mayank ◽  
Anil Kuwar ◽  
Navneet Kaur ◽  
...  

Hybrid nanoassembly, fluorescent chemosensors, selective response to ketoprofen, and nanomolar detection.


2020 ◽  
Vol 124 (52) ◽  
pp. 11017-11024
Author(s):  
Toni Haubitz ◽  
Werner Fudickar ◽  
Torsten Linker ◽  
Michael U. Kumke

Author(s):  
Massimiliano Cavallini ◽  
Ilse Manet ◽  
Marco Brucale ◽  
Laura Favaretto ◽  
Manuela Melucci ◽  
...  

Here, we applied rubbing on thiophene derivate organic semiconductor thin films to induce a reversible mechanical amorphisation. Amorphisation is associated with fluorescence switching, which is regulated by the polymorphic nature...


2018 ◽  
Vol 2 (2) ◽  
pp. 296-299 ◽  
Author(s):  
Hiroyoshi Hamada ◽  
Hayato Tsuji ◽  
Eiichi Nakamura

A new type of molecule tetrakis(benzo[b]furyl)ethene (TBFE) undergoes two-wavelength ON–OFF–ON three-stage fluorescence switching triggered by aggregation.


Sign in / Sign up

Export Citation Format

Share Document