Unprecedented catalytic performance in amine syntheses via Pd/g-C3N4 catalyst-assisted transfer hydrogenation

2018 ◽  
Vol 20 (9) ◽  
pp. 2038-2046 ◽  
Author(s):  
Xingliang Xu ◽  
Jiajun Luo ◽  
Liping Li ◽  
Dan Zhang ◽  
Yan Wang ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Formic Acid ◽  
Catalytic Performance ◽  
Nitro Compounds ◽  
Hydrogen Donor ◽  
Transfer Hydrogenation ◽  
Secondary Amines ◽  
Primary And Secondary Amines

A Pd/g-C3N4 catalyst exhibited a superb performance in the transfer hydrogenation of nitro compounds to generate their corresponding primary and secondary amines with formic acid as the hydrogen donor in aqueous solution.

scholarly journals N-Formylation of Anilines with Silica Sulfuric Acid under Solvent-Free Conditions

2013 ◽  
Vol 2013 ◽  
pp. 1-6 ◽  
Author(s):  
Davood Habibi ◽  
Payam Rahmani ◽  
Ziba Akbaripanah
Keyword(s):  
Sulfuric Acid ◽  
Formic Acid ◽  
Reaction Times ◽  
Solvent Free ◽  
Secondary Amines ◽  
Silica Sulfuric Acid ◽  
Excellent Yield ◽  
Solvent Free Conditions ◽  
Primary And Secondary Amines

N-formylation of primary and secondary amines was carried out with formic acid in the presence of silica sulfuric acid under solvent-free conditions to give the corresponding formamides in excellent yield and short reaction times.

Magnesium Aluminate Supported Cu Catalyst for Selective Transfer Hydrogenation of Biomass Derived Furfural to Furfuryl Alcohol with Formic Acid as Hydrogen Donor

2019 ◽  
Vol 4 (1) ◽  
pp. 145-151 ◽  
Author(s):  
Peddinti Nagaiah ◽  
Paleti Gidyonu ◽  
Muppala Ashokraju ◽  
Madduluri Venkata Rao ◽  
Prathap Challa ◽  
...  
Keyword(s):  
Formic Acid ◽  
Furfuryl Alcohol ◽  
Hydrogen Donor ◽  
Transfer Hydrogenation ◽  
Magnesium Aluminate ◽  
Selective Transfer ◽  
Cu Catalyst

Asymmetric Transfer Hydrogenation of Cyclic Imines in Water with a Versatile Hydrogen Donor Formic Acid/N-Methylpiperidine: Rapid Access to Highly Enantioselective Amines

2016 ◽  
Vol 1 (10) ◽  
pp. 2221-2224 ◽  
Author(s):  
Vaishali S. Shende ◽  
Savita K. Shingote ◽  
Sudhindra H. Deshpande ◽  
Ashutosh. A. Kelkar
Keyword(s):  
Formic Acid ◽  
Hydrogen Donor ◽  
Transfer Hydrogenation ◽  
Asymmetric Transfer Hydrogenation ◽  
Rapid Access

Room-temperature transfer hydrogenation and fast separation of unsaturated compounds over heterogeneous catalysts in an aqueous solution of formic acid

2014 ◽  
Vol 16 (8) ◽  
pp. 3746-3751 ◽  
Author(s):  
Ling-Hong Gong ◽  
Yi-Yu Cai ◽  
Xin-Hao Li ◽  
Ya-Nan Zhang ◽  
Juan Su ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Formic Acid ◽  
Room Temperature ◽  
Heterogeneous Catalysts ◽  
Transfer Hydrogenation ◽  
Unsaturated Compounds ◽  
Fast Separation

Transfer hydrogenation of unsaturated compounds can be conducted over Pd/CN catalysts at room temperature in an aqueous solution of formic acid.

One-pot reductive amination of aldehydes with nitroarenes using formic acid as the hydrogen donor and mesoporous graphitic carbon nitride supported AgPd alloy nanoparticles as the heterogeneous catalyst

2018 ◽  
Vol 42 (12) ◽  
pp. 10000-10006 ◽  
Author(s):  
Seda Ergen ◽  
Bilal Nişancı ◽  
Önder Metin
Keyword(s):  
Formic Acid ◽  
Heterogeneous Catalyst ◽  
Carbon Nitride ◽  
Reductive Amination ◽  
Graphitic Carbon ◽  
Hydrogen Donor ◽  
Graphitic Carbon Nitride ◽  
Secondary Amines ◽  
Alloy Nanoparticles ◽  
One Pot

A facile one-pot protocol has been developed for the synthesis of secondary amines via a tandem reductive amination of aldehydes with nitroaromatics.

Phosphine-Free Manganese Catalyst Enables Selective Transfer Hydrogenation of Nitriles to Primary and Secondary Amines Using Ammonia–Borane

ACS Catalysis ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 2786-2794
Author(s):  
Koushik Sarkar ◽  
Kuhali Das ◽  
Abhishek Kundu ◽  
Debashis Adhikari ◽  
Biplab Maji
Keyword(s):  
Ammonia Borane ◽  
Transfer Hydrogenation ◽  
Secondary Amines ◽  
Selective Transfer ◽  
Primary And Secondary Amines ◽  
Hydrogenation Of Nitriles
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