Two luminescent transition-metal–organic frameworks with a predesigned ligand as highly sensitive and selective iron(iii) sensors

2018 ◽  
Vol 42 (9) ◽  
pp. 6839-6847 ◽  
Author(s):  
Jian Zhang ◽  
Lili Zhao ◽  
Yinxia Liu ◽  
Mingyue Li ◽  
Gang Li ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Transition Metal ◽  
Metal Organic Frameworks ◽  
Luminescent Probes ◽  
Highly Sensitive ◽  
Metal Organic

The water-stable imidazole dicarboxylated-based MOFs are excellent luminescent probes for the Fe3+ ion in an aqueous solution.

scholarly journals Highly sensitive detection of nitrobenzene by a series of fluorescent 2D zinc(ii) metal–organic frameworks with a flexible triangular ligand

RSC Advances ◽  
2021 ◽  
Vol 11 (39) ◽  
pp. 23975-23984
Author(s):  
Xue Yang ◽  
Yixia Ren ◽  
Hongmei Chai ◽  
Xiufang Hou ◽  
Zhixiang Wang ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Metal Organic Frameworks ◽  
High Sensitivity ◽  
Fluorescent Sensors ◽  
Sensitive Detection ◽  
Donor Ligands ◽  
Highly Sensitive ◽  
Metal Organic ◽  
Highly Sensitive Detection

Four fluorescent 2D Zn-MOFs based on a flexible triangular ligand and linear N-donor ligands are hydrothermally prepared and used to detect nitrobenzene in aqueous solution with high sensitivity, demonstrating their potential as fluorescent sensors.

Pillared metal organic frameworks for the luminescence sensing of small molecules and metal ions in aqueous solutions

2015 ◽  
Vol 44 (4) ◽  
pp. 1754-1760 ◽  
Author(s):  
Fu-Hong Liu ◽  
Chao Qin ◽  
Yan Ding ◽  
Han Wu ◽  
Kui-Zhan Shao ◽  
...  
Keyword(s):  
Aqueous Solutions ◽  
Metal Ions ◽  
Small Molecules ◽  
Metal Organic Frameworks ◽  
Luminescent Probes ◽  
Highly Sensitive ◽  
Metal Organic

Two pillared-layer MOFs as luminescent probes with multifunctional sensitivities to detect metal ions and small molecules were reported. Our results show that the luminescence intensities of 1a and 2a are highly sensitive to Fe3+ and Cd2+ ions and small molecules such as acetone and nitrobenzene.

Selective removal of transition metal ions from aqueous solution by metal–organic frameworks

RSC Advances ◽  
2015 ◽  
Vol 5 (88) ◽  
pp. 72107-72112 ◽  
Author(s):  
Yutian Zhang ◽  
Xudong Zhao ◽  
Hongliang Huang ◽  
Zhengjie Li ◽  
Dahuan Liu ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Transition Metal ◽  
Metal Ions ◽  
Metal Organic Frameworks ◽  
Transition Metal Ions ◽  
Selective Removal ◽  
Carboxyl Groups ◽  
Separation Selectivity ◽  
Metal Organic ◽  
High Separation

Carboxyl groups in adjacent ligands in UiO-66(Zr)–2COOH exhibit specific capture performance for Cu2+, resulting in high separation selectivity for Cu2+/Ni2+.

A series of transition metal–organic frameworks: crystal structures, luminescence properties, and sensitizing for luminescent Ln(iii) ions in aqueous solution

RSC Advances ◽  
2016 ◽  
Vol 6 (73) ◽  
pp. 69007-69015 ◽  
Author(s):  
Xiang-Long Qu ◽  
Xiao-Li Zheng ◽  
Xia Li
Keyword(s):  
Aqueous Solution ◽  
Transition Metal ◽  
Crystal Structures ◽  
Metal Organic Frameworks ◽  
Luminescence Properties ◽  
Metal Organic

A series of transition metal–organic frameworks were assembled. Crystal structures, luminescence and sensitizing for Ln(iii) ions were studied.

Lanthanide metal–organic frameworks assembled from a fluorene-based ligand: selective sensing of Pb2+ and Fe3+ ions

2016 ◽  
Vol 4 (9) ◽  
pp. 1900-1905 ◽  
Author(s):  
Liang Li ◽  
Qiang Chen ◽  
Zhigang Niu ◽  
Xinhui Zhou ◽  
Tao Yang ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Fluorescence Enhancement ◽  
Metal Organic Frameworks ◽  
Neutral Network ◽  
Static Quenching ◽  
Highly Sensitive ◽  
Metal Organic ◽  
Sensitive Sensor ◽  
Lanthanide Metal

A series of fluorene-based Ln-MOFs with 3D neutral network are reported. Eu-MOF can act as the highly sensitive sensor to Pb2+ and Fe3+ ions in aqueous solution by fluorescence enhancement and quenching, respectively. The dynamic and static quenching constants of Fe3+ are obtained.

Nanoscale metal–organic frameworks as highly sensitive luminescent sensors for Fe2+ in aqueous solution and living cells

2014 ◽  
Vol 50 (69) ◽  
pp. 9969-9972 ◽  
Author(s):  
Ye Lu ◽  
Bing Yan ◽  
Jin-Liang Liu
Keyword(s):  
Aqueous Solution ◽  
Hela Cells ◽  
Metal Organic Frameworks ◽  
Living Cells ◽  
Sensitive Detection ◽  
Luminescent Sensors ◽  
Highly Sensitive ◽  
Metal Organic

We report the exploration of fluorescent nanoscale metal–organic frameworks (nMOF-253s) for highly selective and sensitive detection of Fe2+ ions in aqueous solution. Moreover, nMOF-253 of 50 nm is successfully applied in fluorescent bioimaging and intracellular Fe2+ sensing in HeLa cells.

scholarly journals Synthesis of metal–organic frameworks (MOFs) MIL-100(Fe) functionalized with thioglycolic acid and ethylenediamine for removal of eosin B dye from aqueous solution

2021 ◽  
Vol 3 (1) ◽  
Author(s):  
Adedibu C. Tella ◽  
Janet T. Bamgbose ◽  
Vincent O. Adimula ◽  
Mary Omotoso ◽  
Sunday E. Elaigwu ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Thioglycolic Acid ◽  
Metal Organic Frameworks ◽  
Thiol Group ◽  
Spectroscopic Techniques ◽  
Base Interaction ◽  
Adsorption Capacities ◽  
Melting Point Analysis ◽  
Eosin B ◽  
Metal Organic

AbstractThe interaction of eosin B dye from aqueous solution with MIL-100(Fe) and functionalized MIL-100(Fe) metal–organic frameworks (MOFs) is reported in this study. MIL-100(Fe) was prepared and functionalized with thioglycolic acid (TH) and ethylenediammine (ED) separately by incorporating the thiol (–SH) and the amine (–NH2) group of the functionalizing agents into the open metal sites of the MIL-100(Fe) to obtain the acidic (TH-MIL-100) and basic (ED-MIL-100) forms of the MOF respectively. Characterization of the MOFs was done by melting point analysis, elemental analysis, spectroscopic techniques, scanning electron microscopy (SEM), and powdered X-ray diffraction (PXRD) analysis. The adsorption experiments were carried out at different conditions such as pH, adsorbent dosage, contact time, temperature, and initial concentration of the dye to estimate the optimum conditions and the maximum adsorption capacities. Adsorption capacities were observed to increase in the order of ED-MIL-100 < MIL-100 < TH-MIL-100, while the TH-MIL-100 was the most effective in the removal process due to acid–base interaction between the acidic thiol group (–SH) and the alkaline medium of eosin B dye solution. The Langmuir Isotherm was seen to fit well to adsorption data obtained for all three adsorbent materials studied, and adsorption processes followed the pseudo-second order kinetics. This study, therefore, indicates the suitability of functionalization of MIL-100(Fe) towards improving its adsorption capacity.

3D Ln-MOFs as multi-responsive luminescent probe for efficient sensing of Fe3+, Cr2O72‒, and antibiotics in aqueous solution

CrystEngComm ◽  
2021 ◽  
Author(s):  
Yuanshan Xue ◽  
Ji Ding ◽  
Dan-Ling Sun ◽  
Weiwei Cheng ◽  
Xuanrong Chen ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Metal Organic Frameworks ◽  
Luminescent Probe ◽  
Metal Organic ◽  
Lanthanide Metal

Two families of lanthanide metal-organic frameworks (Ln-MOFs), namely {[Ln2L2(DMF)4]·xDMF·yH2O}n (Ln = Ce(1), Pr(2), Sm(3), Eu(4), Gd(5); x = 0,1; y = 0,1), and {[Ln2L2(H2O)2.5]}n (Ln = Dy(6), Ho(7)), have been...

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