Tuning the structure of bifunctional Pt/SmMn2O5 interfaces for promoted low-temperature CO oxidation activity

Nanoscale ◽  
2019 ◽  
Vol 11 (17) ◽  
pp. 8150-8159 ◽  
Author(s):  
Xiao Liu ◽  
Jiaqiang Yang ◽  
Gurong Shen ◽  
Meiqing Shen ◽  
Yunkun Zhao ◽  
...  

The role of bifunctional Pt/SmMn2O5 interfaces offered by tuning their local structure and composition in promoting low-temperature CO oxidation is investigated.

2015 ◽  
Vol 345 ◽  
pp. 319-328 ◽  
Author(s):  
V. Johánek ◽  
M. Václavů ◽  
I. Matolínová ◽  
I. Khalakhan ◽  
S. Haviar ◽  
...  

2010 ◽  
Vol 274 (1) ◽  
pp. 1-10 ◽  
Author(s):  
Lequan Liu ◽  
Feng Zhou ◽  
Liguo Wang ◽  
Xiujuan Qi ◽  
Feng Shi ◽  
...  

Nanoscale ◽  
2010 ◽  
Vol 2 (12) ◽  
pp. 2739 ◽  
Author(s):  
Jinwen Qin ◽  
Junfeng Lu ◽  
Minhua Cao ◽  
Changwen Hu

RSC Advances ◽  
2013 ◽  
Vol 3 (30) ◽  
pp. 12409 ◽  
Author(s):  
Jie Li ◽  
Guanzhong Lu ◽  
Guisheng Wu ◽  
Dongsen Mao ◽  
Yanglong Guo ◽  
...  

Science ◽  
2017 ◽  
Vol 358 (6369) ◽  
pp. 1419-1423 ◽  
Author(s):  
Lei Nie ◽  
Donghai Mei ◽  
Haifeng Xiong ◽  
Bo Peng ◽  
Zhibo Ren ◽  
...  

To improve fuel efficiency, advanced combustion engines are being designed to minimize the amount of heat wasted in the exhaust. Hence, future generations of catalysts must perform at temperatures that are 100°C lower than current exhaust-treatment catalysts. Achieving low-temperature activity, while surviving the harsh conditions encountered at high engine loads, remains a formidable challenge. In this study, we demonstrate how atomically dispersed ionic platinum (Pt2+) on ceria (CeO2), which is already thermally stable, can be activated via steam treatment (at 750°C) to simultaneously achieve the goals of low-temperature carbon monoxide (CO) oxidation activity while providing outstanding hydrothermal stability. A new type of active site is created on CeO2 in the vicinity of Pt2+, which provides the improved reactivity. These active sites are stable up to 800°C in oxidizing environments.


2012 ◽  
Vol 2 (9) ◽  
pp. 1865 ◽  
Author(s):  
Jie Li ◽  
Guanzhong Lu ◽  
Guisheng Wu ◽  
Dongsen Mao ◽  
Yanqin Wang ◽  
...  

2018 ◽  
Vol 9 (9) ◽  
pp. 2469-2473 ◽  
Author(s):  
Xiao Liu ◽  
Yuanting Tang ◽  
Meiqing Shen ◽  
Wei Li ◽  
Shengqi Chu ◽  
...  

Highly dispersed Pt sub-nanoclusters are anchored on SmMn2O5mullitesviaatomic layer deposition, and show excellent low-temperature CO oxidation activity.


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