Cluster–oxalate frameworks with extra-large channels: solvent-free synthesis, chemical stability, and proton conduction

Two new metal phosphate-oxalates (denoted SCU-26 and SCU-27) were prepared under solvent-free conditions using isonicotinic acid as a structure-directing agent. SCU-26 has a neutral layered structure showing intense blue-green luminescence...

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N-methylimidazolium containing metal phosphate-oxalates: solvent-free synthesis, crystal structure, and proton conduction

CrystEngComm ◽

10.1039/d1ce01659h ◽

2022 ◽

Author(s):

Junfeng Zhang ◽

Qing Lei ◽

Lindong Luan ◽

Hongmei Zeng ◽

Guohong Zou ◽

...

Keyword(s):

Crystal Structure ◽

Layered Structure ◽

Three Dimensional ◽

Proton Conduction ◽

Solvent Free ◽

Dimensional Structure ◽

Metal Phosphate ◽

Three Dimensional Structure ◽

Solvent Free Conditions ◽

Solvent Free Synthesis

Two N-methylimidazolium containing metal phosphate-oxalates (denoted SCU-40 and SCU-42) were prepared under solvent-free conditions. SCU-40 has a three-dimensional structure with a zeolitic crb topology, while SCU-42 has a layered structure...

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Organically templated metal phosphate-oxalates: Solvent-free synthesis, crystal structure, and proton conduction

Inorganic Chemistry Communications ◽

10.1016/j.inoche.2020.108403 ◽

2021 ◽

Vol 124 ◽

pp. 108403

Author(s):

Yue Cao ◽

Xiaoying Zhou ◽

Lindong Luan ◽

Hongmei Zeng ◽

Guohong Zou ◽

...

Keyword(s):

Crystal Structure ◽

Proton Conduction ◽

Solvent Free ◽

Metal Phosphate ◽

Solvent Free Synthesis

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Solvent-free synthesis of symmetric methylene diesters via direct reaction of aromatic carboxylates with 1,n-dihaloalkanes

RSC Advances ◽

10.1039/d1ra04814g ◽

2021 ◽

Vol 11 (46) ◽

pp. 28711-28715

Author(s):

Lin Bai ◽

Shenglong Ding ◽

Xiaofang Ma

Keyword(s):

Solvent Free ◽

Direct Reaction ◽

Highly Efficient ◽

Solvent Free Conditions ◽

Aromatic Carboxylates ◽

Solvent Free Synthesis

This work provides a highly efficient and feasible strategy for the synthesis of symmetric methylene diesters, involving the direct diesterification of various carboxylates with 1,n-dihaloalkanes under solvent-free conditions.

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Solvent-free synthesis of novel vanillidene derivatives of Meldrum's acid: biological evaluation, DNA and BSA binding study

RSC Advances ◽

10.1039/c6ra07711k ◽

2016 ◽

Vol 6 (45) ◽

pp. 39452-39459 ◽

Cited By ~ 11

Author(s):

Nenad Janković ◽

Jovana Muškinja ◽

Zoran Ratković ◽

Zorica Bugarčić ◽

Branislav Ranković ◽

...

Keyword(s):

Biological Evaluation ◽

Solvent Free ◽

Binding Study ◽

Meldrum's Acid ◽

Meldrum’S Acid ◽

Bsa Binding ◽

Solvent Free Conditions ◽

Derivatives Of ◽

Solvent Free Synthesis

A series of novel O-alkyl vanillidene derivatives containing Meldrum's acid scaffold under solvent-free conditions were synthesized.

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Solvent-free synthesis of pyrrolo [2,1-α]isoquinolines via one-pot four-component reaction

Letters in Organic Chemistry ◽

10.2174/1570178618666210805103552 ◽

2021 ◽

Vol 18 ◽

Author(s):

Ali Aminkhani ◽

Sina Sharifi

Keyword(s):

Cycloaddition Reaction ◽

Aromatic Aldehydes ◽

Solvent Free ◽

One Pot ◽

Solvent Free Conditions ◽

Solvent Free Synthesis

: An efficient four-component reaction to synthesize pyrrolo[2,1-a]isoquinolines from malononitrile, aromatic aldehydes, isoquinoline, and cyclohexyl isocyanide under solvent-free conditions is described. In a convenient, simple, and efficient one-pot procedure, the domino Knoevenagel-nucleophilic cycloaddition reaction affords excellent yields of products in less than 1 h.

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Solvent-free synthesis and properties of carboxymethyl starch fatty acid ester derivatives

Chemical Papers ◽

10.2478/s11696-008-0088-x ◽

2009 ◽

Vol 63 (1) ◽

Cited By ~ 5

Author(s):

Viera Mazíková ◽

Iva Sroková ◽

Anna Ebringerová

Keyword(s):

Fatty Acid ◽

Methyl Esters ◽

Solvent Free ◽

Water Soluble ◽

Polymeric Surfactants ◽

Acid Complex ◽

Carboxymethyl Starch ◽

Solvent Free Conditions ◽

Structural Surface ◽

Solvent Free Synthesis

AbstractWater-soluble, partially hydrophobized polysaccharides have become attractive due to their potential to act as polymeric surfactants. From carboxymethyl starch (CMS), water-soluble polymeric surfactants were prepared by esterification using two unconvential methods based on (A) a reaction with mixed anhydrides and (B) with methyl laureate (MELA) and methyl esters of the fatty acid complex of rape seed oil (MERO) under ‘solvent-free’ conditions. The obtained CMS derivatives were characterized by structural, surface-active and surfactant performance properties. Esterification using method B was successful in contrast to method A which yielded derivatives with a very low extent of esterification. Although the derivatives reduced the surface tension moderately, they exhibited remarkable emulsifying properties. The performance tests indicated good washing power and antiredeposition efficiency. The results suggest that suitable polymeric surfactants can be prepared by the unconventional esterification method B using both acylation agents. The preparations might substitute the expensive and invasive industrially applied conventional methods.

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Seed-assisted, solvent-free synthesis of a CHA-type aluminophosphate molecular sieve

RSC Advances ◽

10.1039/c5ra18148h ◽

2015 ◽

Vol 5 (116) ◽

pp. 95690-95694 ◽

Cited By ~ 8

Author(s):

Xinhong Zhao ◽

Jiangbo Zhao ◽

Xiangping Gao ◽

Yu Zhao

Keyword(s):

Molecular Sieve ◽

Solvent Free ◽

Solvent Free Conditions ◽

Solvent Free Synthesis

Triclinic AlPO4-34 with CHA topology has been successfully synthesized under seed-assisted, solvent-free conditions.

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Highly Chemoselective Solvent-Free Synthesis of 1,3,5-Triaryl-1,5-diketones: Crystallographic Investigation and Intramolecular Weak Bifurcated H Bonds Involving Aliphatic C–H Group

Synlett ◽

10.1055/s-0039-1690224 ◽

2019 ◽

Vol 30 (19) ◽

pp. 2143-2147

Author(s):

Zhongyou Yin ◽

Changkun Xiong ◽

Jianxin Guo ◽

Xiaoyun Hu ◽

Zixing Shan ◽

...

Keyword(s):

Solid State ◽

Decisive Role ◽

Solvent Free ◽

Dihedral Angles ◽

Crystallographic Investigation ◽

Structural Arrangement ◽

Bond Lengths ◽

Solvent Free Conditions ◽

Solvent Free Synthesis

Several 1,3,5-triaryl-1,5-diketones have been chemoselectively synthesized under solvent-free conditions. It was found that intramolecular weak bifurcated H-bonds interaction of aliphatic C–H group plays a decisive role in the structural arrangement of 3-(2,6-dichlorophenyl)-1,5-diphenylpentane-1,5-dione in a solid state resulting in significant impact on the corresponding bond lengths and dihedral angles.

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A One-Pot, Three-Component, Solvent-Free Synthesis of Novel 6H-Chromeno[3’,4’:5,6]Pyrido[2,3-d]Pyrimidine-Triones under Microwave Irradiation

Journal of Chemical Research ◽

10.3184/174751918x15414289771620 ◽

2018 ◽

Vol 42 (12) ◽

pp. 604-607

Author(s):

Loghman Firoozpour ◽

Hoda Yahyavi ◽

Ramona Ejtemaei ◽

Setareh Moghimi ◽

Alireza Foroumadi

Keyword(s):

Microwave Irradiation ◽

Efficient Method ◽

Barbituric Acid ◽

Reaction Times ◽

Solvent Free ◽

One Pot ◽

Solvent Free Conditions ◽

Substituted Benzaldehydes ◽

High Yields ◽

Solvent Free Synthesis

A green and efficient method for preparing novel heterocyclic systems is established through the reaction of differently substituted benzaldehydes, barbituric acid and 4-amino-2H-chromene-2-one under solvent-free conditions. This method affords 6H-chromeno[3’,4’:5,6] pyrido[2,3-d]pyrimidine-trione derivatives in high yields and short reaction times.

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