Four-metal-element quantitative analysis and pollution source discrimination in atmospheric sedimentation by laser-induced breakdown spectroscopy (LIBS) coupled with machine learning

2020 ◽  
Vol 35 (2) ◽  
pp. 403-413 ◽  
Author(s):  
Xin Zhang ◽  
Nan Li ◽  
Chunhua Yan ◽  
Jiahui Zeng ◽  
Tianlong Zhang ◽  
...  

The laser-induced breakdown spectroscopy (LIBS) technique coupled with machine learning was proposed to perform four metal elements quantitative analysis and pollution source discrimination in atmospheric sedimentation.

2021 ◽  
Author(s):  
Ashwin P. Rao ◽  
Phillip R. Jenkins ◽  
Dung M Vu ◽  
John D. Auxier ◽  
Anil K Patnaik ◽  
...  

We present the first reported quantification of trace elements in plutonium via a portable laser-induced breakdown spectroscopy (LIBS) device and demonstrate the use of chemometric analysis to enhance the handheld...


Molecules ◽  
2021 ◽  
Vol 26 (5) ◽  
pp. 1241
Author(s):  
Nikolaos Gyftokostas ◽  
Eleni Nanou ◽  
Dimitrios Stefas ◽  
Vasileios Kokkinos ◽  
Christos Bouras ◽  
...  

In the present work, the emission and the absorption spectra of numerous Greek olive oil samples and mixtures of them, obtained by two spectroscopic techniques, namely Laser-Induced Breakdown Spectroscopy (LIBS) and Absorption Spectroscopy, and aided by machine learning algorithms, were employed for the discrimination/classification of olive oils regarding their geographical origin. Both emission and absorption spectra were initially preprocessed by means of Principal Component Analysis (PCA) and were subsequently used for the construction of predictive models, employing Linear Discriminant Analysis (LDA) and Support Vector Machines (SVM). All data analysis methodologies were validated by both “k-fold” cross-validation and external validation methods. In all cases, very high classification accuracies were found, up to 100%. The present results demonstrate the advantages of machine learning implementation for improving the capabilities of these spectroscopic techniques as tools for efficient olive oil quality monitoring and control.


Author(s):  
Kateřina Kiss ◽  
Anna Šindelářová ◽  
Lukáš Krbal ◽  
Václav Stejskal ◽  
Kristýna Mrázová ◽  
...  

Nowadays, laser-based techniques play a significant role in medicine, mainly in the ophthalmology, dermatology, and surgical fields.


Author(s):  
Raquel C Machado ◽  
Diego Victor Babos ◽  
Daniel Fernandes Andrade ◽  
Edenir Rodrigues Pereira-Filho

Quantitative analysis requires several efforts to obtain an adequate calibration method to overcome matrix effects employing direct solid analysis by laser-induced breakdown spectroscopy (LIBS). To this end, in this study,...


Author(s):  
Fu Chang ◽  
Jianhong Yang ◽  
Huili Lu ◽  
Haixia Li

It is significant to improve the repeatability of quantitative analysis of laser-induced breakdown spectroscopy (LIBS) in one-shot measurement where the skill of averaging is not valid because multiple measurements are...


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