Flame-retardant and smoke-suppressing wood obtained by the in situ growth of a hydrotalcite-like compound on the inner surfaces of vessels

2019 ◽  
Vol 43 (41) ◽  
pp. 16359-16366 ◽  
Author(s):  
Shuai Lv ◽  
Xianggui Kong ◽  
Liren Wang ◽  
Fazhi Zhang ◽  
Xiaodong Lei

MgAl-CO32−-LDH was directly grown on the inner surfaces of wood vessels via a one-step hydrothermal process, which greatly enhanced the flame retardant and smoke suppression properties of the wood.

2019 ◽  
Vol 2019 ◽  
pp. 1-12 ◽  
Author(s):  
Xiaoling Yao ◽  
Chungui Du ◽  
Yating Hua ◽  
Jingjing Zhang ◽  
Rui Peng ◽  
...  

In recent years, bamboo has been widely used for building materials and household goods. However, bamboo is flammable, so a flame-retardant treatment for bamboo is urgently needed. In this work, nano MgAl-layered double hydroxide (MgAl-LDH) coated on bamboo, which was called MgAl-LB, was synthesized by an in situ one-step method. To determine the optimal in situ time, the effects of different reaction times on LDH growth on the bamboo surface and the flame retardancy of the MgAl-LBs were investigated. The SEM observations show that LDH growth on the surface of bamboo was basically saturated when the in situ reaction time was 24 h. Abrasion experiments show that MgAl-LDH coating has good abrasion resistance. The fire performance of the MgAl-LBs was evaluated by cone calorimeter tests, which indicated that the THR and TSP of the MgAl-LBs were significantly lower than those of untreated bamboo. Taking into account the energy consumption problem, determining the reaction time of 24 h is the optimal reaction time. Compared with untreated bamboo, the THR and TSP of MgAl-LB prepared at 24 h decreased by 33.3% and 88.9%, respectively.


2020 ◽  
Vol 861 ◽  
pp. 113939 ◽  
Author(s):  
Yanan Zhang ◽  
Yu Zhang ◽  
Lei Li ◽  
Junlei Chen ◽  
Peizhi Li ◽  
...  

Small ◽  
2017 ◽  
Vol 13 (18) ◽  
pp. 1604161 ◽  
Author(s):  
Cheng-Zong Yuan ◽  
Zhong-Ti Sun ◽  
Yi-Fan Jiang ◽  
Zheng-Kun Yang ◽  
Nan Jiang ◽  
...  

2014 ◽  
Vol 602-603 ◽  
pp. 221-225
Author(s):  
Meng Ying Liu ◽  
Ya Li Li ◽  
Sheng Xiang Qu ◽  
Shuai Shuai Han ◽  
Si Hui Wang

Carbon nanofiber (CNF) and silicon carbonitride (SiCN) ceramic nanocomposites (SiCN/CNF) are fabricated by in-situ growth of CNFs in SiCN ceramics during ceramic transformation of polymeric precursors of polysilazanes (PSZ). Metal catalyst precursors are mixed into the polysilazane liquid forming metal particles from decomposition under heating during the pyrolysis. At certain temperatures, ethylene was introduced as a carbon source to induce the growth of CNFs over the metal particles in the ceramic body followed by heating to higher temperatures to complete the pyrolysis. In this way, bulk nanocomposites of SiCN/CNF are obtained as crack-free bodies although some pores are left in the sample. Scanning electron microscopy (SEM) analysis performed on the cross-section of nanocomposites revealed the distribution of needle-like nanofibers of diameter ~ 200 nm and exposed length of ~ 2 μm. The CNFs exhibited the unique multiscale nanostructure in micron hollow tubes with branched nanofiber walls. Energy dispersive X-ray spectrometer (EDX) detected carbon as the major element from the nanofibers confirming the formation of carbon nanofibers. Moreover, clusters of nanoparticles are formed on the ceramic surface from carbon depositions. The in-situ growth of CNFs in SiCN ceramics provides a one-step process potentially to be developed for fabrication of structural and functional SiCN/CNF nanocomposites.


2021 ◽  
Vol 31.2 (149) ◽  
pp. 119-125

In-situ nanocomposites of reduced graphene oxide (rGO) and niken oxide (NiO) nanowire were prepared by direct introducing homemade graphene oxide (GO) into precursor solution of NiO with different weight contents of GO (0.0, 0.5, and 1.0 wt.%) before carrying out the one-step hydrothermal process. Homemade GO was synthesized from graphene nanoflakes via Hummer method. Crystal structure and crystallinity of nanocomposites were analyzed using X-ray diffraction method. Scanning electron microscopy was used to study the morphology of nanocomposites. The absorbability of nanocomposites was evaluated through the absorption experiment with two organic dyes: methyl orange and congo red. The results show that compositing with GO does not affect the crystal structure of NiO but it causes the break of NiO nanorod into shorter nanorods, the increase of microstrain in NiO nanorods, and the increase of the absorption efficiency of nanocomposite with both methyl orange and congo red. The results are contribution to the study on hybrid/nanocomposite materials of carbon-based materials and metal oxide semiconductor nanostructures.


RSC Advances ◽  
2015 ◽  
Vol 5 (89) ◽  
pp. 73126-73132 ◽  
Author(s):  
Liang Shi ◽  
Bohua Dong ◽  
Rongjie Gao ◽  
Ge Su ◽  
Wei Liu ◽  
...  

Superparamagnetic hierarchical Fe3O4@titanate microspheres synthesized via a hydrothermal process exhibit rapid adsorption behavior and can be used as recyclable adsorbents.


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